Note: Ingredients listed on restricted chemical lists
EC/CAS
822-06-0
Name of the chemical
Hexamethylene diisocyanate
Concentration
<1.0
General Information
Revision date
2016-04-26
Product name
GRAFFITI RESISTANT HARDENER
Manufacturer Name
PPG Industries, Inc
Emergency telephone
1-800-647-6050
Icons in SDS
Company Information
company name
PPG Industries, Inc
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Ingredient(s) with unknown acute toxicity
13.7%
Signal word
Danger
Hazard statements
Flammable liquid and vapor. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.
Prevention
Wear protective gloves. Wear eye or face protection. Wear respiratory protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Contaminated work clothing must not be allowed out of the workplace.
Response
Get medical attention if you feel unwell. IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention.
Storage
Store locked up. Store in a well-ventilated place. Keep cool.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Supplemental label elements
Moisture-sensitive material. Repeated exposure to high vapor concentrations may elements cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
2.3 Other hazards
Prolonged or repeated contact may dry skin and cause irritation.