ISOCYANATE PREPOLYMER

Hazard statements (CLP)

H313, H315, H317, H319, H332, H334, H351, H373

Code

Statements

H313

May be harmful in contact with skin

SECTION 2: Hazards identification

Classification of the substance or mixture ACUTE TOXICITY (dermal) - Category 5 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys, liver, respiratory system) - Category 2

Ingredient(s) with unknown acute toxicity

74.2% (Oral), 93.6% (Dermal), 80.2% (Inhalation)

Signal word

Danger

Hazard statements

H332 - Harmful if inhaled. H313 - May be harmful in contact with skin. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. (kidneys, liver, respiratory system)

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves. Wear protective clothing. Wear eye or face protection. P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P264 - Wash hands thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P314 - Get medical attention if you feel unwell. P308 + P313 - IF exposed or concerned Get medical attention. P304 + P340 + P312 - IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or physician. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P333 + P313 - If skin irritation or rash occurs: Get medical attention. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention.

Storage

P405 - Store locked up.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Repeated exposure may lead to permanent respiratory disability. Moisture-sensitive material. Emits toxic fumes when heated. See toxicological information (Section 11)

2.1 Classification of the substance or mixture

ACUTE TOXICITY (dermal) - Category 5 substance or mixture ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (kidneys, liver, respiratory system) - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 74.2% (Oral), 93.6% (Dermal), 80.2% (Inhalation)