DURETHANE HARDENER (4286)

Hazard statements (CLP)

H316, H317, H332, H334, H335, H351, H373

Code

Statements

H316

Causes mild skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 3 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Signal word

Danger

Hazard statements

H316 - Causes mild skin irritation. H317 - May cause an allergic skin reaction. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. (hearing organs)

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P340, P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P362 + P364 - Take off contaminated clothing and wash it before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention.

Storage

P405 - Store locked up. P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Prolonged or repeated contact may dry skin and cause irritation. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Repeated exposure may lead to permanent respiratory disability. Moisture-sensitive material. Emits toxic fumes when heated. See toxicological information (Section 11)

2.1 Classification of the substance or mixture

ACUTE TOXICITY (inhalation) - Category 4 substance or mixture SKIN IRRITATION - Category 3 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2