YELLOW ACRYLIC LACQUER

Hazard statements (CLP)

H225, H315, H319, H336, H351, H361, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Health Hazards Not Otherwise Classified - Category 1 This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8)

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Prolonged or repeated contact may dry skin and cause irritation.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling.

Response

IF exposed or concerned Get medical advice or attention. IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Photosensitive agents : In case of accidental eye contact, avoid direct exposure to the sun or other sources of UV light as severe irritation including burns may result. These reactions can be delayed – get medical attention if pain, irritation or blistering occurs after contact. In case of accidental skin contact, avoid direct exposure to the sun or other sources of UV light as severe irritation including burns may result. These reactions can be delayed – get medical attention if pain, irritation, rash or blistering occurs after contact.

Storage

Store locked up. Store in a well-ventilated place. Keep container tightly closed.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated. Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 19.1% (oral), 58.1% (dermal), 22% (inhalation) CAS number/other identifiers Ingredient name toluene Synonyms % (w/w) CAS number Benzene, methyl-; Methylbenzene; Toluol; 15 - 40 108-88-3 Phenyl methane; Methyl benzol; toluene, pure; toluene, crude; t-butylchloride dimethylsilane, solution in toluene; preparation consisting of: — 80 % or more but not more than 90 % by weight of (S)-hydroxy-3-phenoxy- benzeneacetonitrile (CAS RN 61826-76-4) and — 10 % or more but not more than 20 % by weight of toluene (CAS RN108-88-3); preparation containing: — 74 % or more but not more than 90 % by weight of (S)-α-hydroxy-3-phenoxy- 26 % by weight of toluene (CAS RN 108-88-3); methacide titanium dioxide Titanium oxide; Titanium oxide (TiO2); CI 10 - 30* 13463-67-7 77891; Titanium peroxide; Rutile; C.I. Pigment White 6; titanium dioxide, other than those of heading 3206 11 00; C.I. 77891; E 171; titanium(IV) oxide, other than those of heading 3206 11 00 butanone ethyl methyl ketone; 2-Butanone; Methyl 7 - 13* 78-93-3 ethyl ketone; MEK; 2-Butanone (Methyl ethyl ketone); Methyl acetone; butane- 2-one; mixture consisting of: — 64 % or more, but not more than 74 % by weight of amorphous silica (CAS RN 7631-86-9) — 25 % or more, but not more than 35 % by weight of butanone (CAS RN 78-93-3) and — not more than 1 % by weight of 3- (2,3-epoxypropoxy)propyltrimethoxysilane (CAS RN 2530-83-8); preparation, containing: — cyanic acid, C,C’-( (1-methylethylidene)di-4,1-phenylene) ester, homopolymer (CAS RN 25722-66-1), — 1,3-bis(4-cyanophenyl) propane (CAS RN 1156-51-0), — in a solution of butanone (CAS RN 78-93-3) with a content of less than 50 % by weight; butan-2-one; Methyl ethyl ketone (MEK) (I, T) 2-methoxy-1-methylethyl acetate 2-Propanol, 1-methoxy-, 2-acetate; 3 - 7* 108-65-6 Propylene glycol monomethyl ether acetate; 2-Propanol, 1-methoxy-, acetate; 1-Methoxy-2-propanol, acetate; 2-Acetoxy-1-methoxypropane; Propylene glycol methyl ether acetate; 1-Methoxypropyl-2-acetate; 1-Methoxy- 2-propanol acetate; light stabiliser

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 2 substance or mixture SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Health Hazards Not Otherwise Classified - Category 1 Section 2. Hazard identification This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).