PRIMER 4

Hazard statements (CLP)

H225, H303+H313, H315, H317, H318, H332, H334, H336, H351, H361, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the FLAMMABLE LIQUIDS - Category 2 substance or mixture ACUTE TOXICITY (oral) - Category 5 ACUTE TOXICITY (dermal) - Category 5 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (respiratory system) - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 6.1% Oral), 10.3% (Dermal), 6.1% (Inhalation)

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor. H332 - Harmful if inhaled. H303 + H313 - May be harmful if swallowed or in contact with skin. H318 - Causes serious eye damage. H315 - Causes skin irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 - May cause an allergic skin reaction. H361 - Suspected of damaging the unborn child. H351 - Suspected of causing cancer. H336 - May cause drowsiness or dizziness. H373 - May cause damage to organs through prolonged or repeated exposure. (respiratory system)

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves. Wear protective clothing. Wear eye or face protection. P284 - Wear respiratory protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P264 - Wash hands thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P314 - Get medical attention if you feel unwell. P308 + P313 - IF exposed or concerned Get medical attention. P304 + P340 + P312 - IF INHALED Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or physician. P301 + P312 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P333 + P313 - If skin irritation or rash occurs: Get medical attention. P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.

Storage

P405 - Store locked up.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Prolonged or repeated contact may dry skin and cause irritation. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Repeated exposure may lead to permanent respiratory disability. Moisture-sensitive material. Emits toxic fumes when heated.

Supplemental label elements

Photosensitive agents In case of accidental eye contact, avoid concurrent exposure to elements (First aid the sun or other sources of UV light which may increase the sensitivity of the eyes. In measures): case of accidental skin contact, avoid concurrent exposure to the sun or other sources of UV light which may increase the sensitivity of skin. See toxicological information (Section 11)

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 2 substance or mixture ACUTE TOXICITY (oral) - Category 5 ACUTE TOXICITY (dermal) - Category 5 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (respiratory system) - Category 2 Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 6.1% (Oral), 10.3% (Dermal), 6.1% (Inhalation)