PR420 PartA

Hazard statements (CLP)

H226, H315, H317, H319, H331, H334, H335, H351, H373

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXICITY (SINGLE EXPOSURE) (Respiratory tract SPECIFIC TARGET ORGAN irritation) - Category 3 (REPEATED EXPOSURE) - Category 2 SPECIFIC TARGET ORGAN TOXICITY consisting of ingredient(s) of unknown toxicity: 4% (Oral), 62. Percentage of the mixture 5% (Dermal)

Hazard pictograms

A A

Signal word

Danger

Hazard statements

Flammable liquid and vapor. Toxic if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Prevention

safety precautions have : Obtain special instructions before use. Do not handle until all and understood. Wear protective gloves. Wear eye or face protection. been read clothing. Wear respiratory protection. Keep away from heat, hot Wear protective surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion- electrical, ventilating, lighting and all material-handling equipment. Use only non- proof precautionary measures against static discharge. Keep container sparking tools. Take tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.

Response

H Get medical attention if you feel unwell. IF exposed or concerned: Get medical IF INHALED: If breathing is difficult, remove person to fresh air and keep attention. comfortable for breathing, Call a POISON CENTER or physician. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN (or hair): immediately all contaminated clothing. Rinse skin with water or shower. IF ON Take off SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs Get medical attention. IF IN EYES Rinse cautiously for several minutes. Remove contact lenses, if present and easy to do. with water Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Moisture-sensitive material. Repeated exposure to high vapor concentrations may and nervous system cause irritation of the respiratory system and permanent brain Inhalation of vapor/aerosol concentrations above the recommended exposure damage. limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Emits toxic fumes when heated.

2.3 Other hazards

None known.