PR1590 BLACK Part B

Hazard statements (CLP)

H302+H312, H315, H317, H319, H331, H334, H335, H350

Code

Statements

H302+H312

Harmful if swallowed or in contact with skin

SECTION 2: Hazards identification

Classification of the substance or mixture ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Signal word

Danger

Hazard statements

H302 + H312 - Harmful if swallowed or in contact with skin. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H331 - Toxic if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H350 - May cause cancer.

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P340, P311 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P301 + P312, P330 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. Rinse mouth. P302 + P312, P352 - IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P362 + P364 - Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice or attention.

Storage

P405 - Store locked up. P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Repeated exposure may lead to permanent respiratory disability. Moisture-sensitive material. Emits toxic fumes when heated. See toxicological information (Section 11)

2.1 Classification of the substance or mixture

ACUTE TOXICITY (oral) - Category 4 substance or mixture ACUTE TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Category 3 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3