Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
General Information
Revision date
2016-04-24
Product name
PR 868 Part A
CAS No.
9016-87-9
Manufacturer Name
PPG Aerospace PRC-DeSoto
Emergency telephone
(412) 434-4515 (U.S.
Icons in SDS
Company Information
company name
PPG Aerospace PRC-DeSoto
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
29 CFR 1910.1200) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
2.1 Classification of the substance or mixture
ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Ingredient(s) with unknown acute toxicity
53.6%
Signal word
Danger
Hazard statements
Harmful if inhaled. Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Wear respiratory protection. Use only outdoors or in a well- ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace.
Response
Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. If experiencing respiratory symptoms: Call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs Get medical attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
Store locked up.
Disposal
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Supplemental label elements
Moisture-sensitive material. Skin contact to isocyanate monomer may lead to allergic elements lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Repeated exposure may lead to permanent respiratory disability. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Emits toxic fumes when heated.
2.3 Other hazards
None known.