Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
General Information
Revision date
2012-05-05
Product name
Aropack 403 comp.A
CAS No.
9016-87-9
1.2.1 Relevant identified uses
Industrial
Icons in SDS
Company Information
company name
POZZI-AROSIO srl
e-mail address of the competent person responsible for the Safety Data Sheet
d.luise@pozziarosio.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
2.1 Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof: Properties: Carcinogenic category 3 Xn Harmful Xi Irritant
R-phrase(s)
R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. EC regulation criteria 1272/2008 (CLP) Warning, Acute Tox. 4, Harmful if inhaled. Warning, Skin Irrit. 2, Causes skin irritation. Warning, Eye Irrit. 2, Causes serious eye irritation. Danger, Resp. Sens. 1, May cause allergy or asthma symptoms or breathing difficulties if inhaled. Warning, Skin Sens. 1, May cause an allergic skin reaction. Warning, Carc. 2, Suspected of causing cancer. Warning, STOT SE 3, May cause respiratory irritation. Warning, STOT RE 2, May cause damage to organs through prolonged or repeated exposure.
Adverse physicochemical, human health and environmental effects
No other hazards
Hazard pictograms
Danger
Hazard statements
H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P285 In case of inadequate ventilation wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions
None
Contains
DIPHENYLMETHANEDIISOCYANATE, ISOMERS AND HOMOLOGUES (MDI)
2.3 Other hazards
The substance / mixture contains NO PBT / vPvB in accordance with Regulation (EC) 1907/2006, Annex XIII. The use of this chemical leads to the requirement of "Risk Assessment" by the employer in accordance with the provisions of Decree n. 81 of April 9, 2008. Workers exposed to this chemical agent must undergo health surveillance if the results of risk assessment show that, depending on the type and amount of chemical agent and the method and frequency of exposure to this agent, there is only a risk "irrelevant" to the health and "low" for the safety of workers and the measures provided for in the same Decree. are sufficient to reduce the risk.