Spray & Gloss

Poorboy’s World UK

Revision date : 2015-12-18

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GHS07
Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

General Information

Revision date

2015-12-18

Product name

Spray & Gloss

1.2.1 Relevant identified uses

Spray-on vehicle detail spray Non-Recommended /

Emergency telephone

General: 01924 469920 UK Sales

Icons in SDS

GHS07

Company Information

company name

Poorboy’s World UK

GHS Information

Signal word

Warning

Section 2

SECTION 2: Hazards identification

GHS Classification Identification GHS

2.1 Classification of the substance or mixture

Classification for for mixture: mixture: Serious eye damage/eye irritation - Category 1

Hazard pictograms

SSiiggnnaall W Woorrddss:: Warning HHaazzaarrdd SSttaatteem meennttss:: Causes serious eye irritation. PPrreeccaauuttiioonnaarryy SSttaatteem meennttss:: PPrreevveennttiioonn Wear protective gloves/protective clothing/eye protection/face protection. Wash skin thouroughly after handling. RReessppoonnssee IF IN EYES: Remove contact lenses, if present and easy to do. Continue rinsing. IF IN EYES: Rinse cautiously with water for several minutes. IF EYE IRRITATION PERSISTS: Get medical advice/attention. Version: 1 Page 1 of 7 Date Created 12/18/2015 SSeeccttiioonn 33.. CCoom mppoossiittiioonn // IInnffoorrm maattiioonn oonn IInnggrreeddiieennttss Identifiers Ingredients Percentage

Classifications

160875-66-1 Poly(oxy-1,2-ethanediyl), alpha- 1% to 5% Eye 1 , Skin 2, Acute tox 4, auatic acute3, (propylheptyl) acuatic chronic 3 57-55-6 Propylene glycol Eye 2B, STOT SE3 noarcotic, STOT Rep 2 1% to 5% (kidney, spleen, blood) Section 4. First-Aid First-Aid Measures Measures FFiirrsstt--AAiidd EEyyeess Continue rinsing. Hold eyelids open to ensure adequate flushing. Remove the contact lenses if worn and easy to do that. Wash eyes with plenty of water. FFiirrsstt--AAiidd:: SSkkiinn If redness or other symptoms occur, seek medical advice / attention. FFiirrsstt--AAiidd:: IInnggeessttiioonn DO NOT INDUCE VOMITING. If the exposed person is drowsy or unconscious, do not give anything by mouth. Rinse the mouth with water. FFiirrsstt--AAiidd:: IInnhhaallaattiioonn Remove person to fresh air and keep at rest in a position comfortable for breathing. If after inhalation you feel unwell, seek medical advice. FFiirrsstt--AAiidd:: OOtthheerr GGeenneerraall aaddvviiccee In all cases if in doubt or when symptoms persist, seek medical advice Section 5. Fire-Fighting Fire-Fighting Measures Measures SSuuiittaabbllee EExxttiinngguuiisshhiinngg M Meeddiiaa TThhee ssuuggggeesstteedd aapppprroopprriiaattee m meeddiiaa Carbon dioxide. Foam. Powder BC. Water spray UUnnssuuiittaabbllee EExxttiinngguuiisshhiinngg M Meeddiiaa IInnaapppprroopprriiaattee m meeddiiaa Straight streams of water PPrrootteeccttiivvee M Meeaassuurreess ffoorr FFiirree--FFiigghhttiinngg Wear full protective clothing. Wear self-contained breathing apparatus. SSppeecciiaall PPrrootteeccttiivvee AAccttiioonnss ffoorr FFiirree--FFiigghhtteerrss Explosive when mixed with combustible material. Dike area to prevent runoff and contamination of water sources. Do not allow run-off from fire fighting to enter drains or water courses. CCoom mbbuussttiioonn PPrroodduuccttss Carbon dioxide (CO₂). Carbon monoxide (CO). Oxides of nitrogen (NOₓ). SSeeccttiioonn 66.. AAcccciiddeennttaall RReelleeaassee M Meeaassuurreess Personal Personal Precautions, Precautions, Protective Protective Equipment Equipment and and Emergency Emergency Procedures Procedures Avoid breathing gas / mist / dust / fume / vapor /spray / particles. Ventilate spill area. Environmental Environmental Precautions

Precautionary statements

Do not discharge into drains or any body of water (rivers, streams, ponds, lakes, etc). Dike area to prevent runoff and contamination of water sources. Dispose the material in accordance with the government regulation. Clean-up Clean-up Procedures Procedures Absorb with earth, sand, or other non-combustible material. If possible, the spilled liquid should be transferred to a waste container. Date Created 12/18/2015 Version: 1 Page 2 of 7 Large Large spills: spills: If possible, dike the area to prevent spreading. Section 7. Handling Handling and and Storage Precautions for for Safe Safe Handling Handling Ensure there is sufficient ventilation of the area. Handle in accordance with all current regulations and standards. Handle in accordance with good industrial hygiene and safety practice. Conditions Conditions for for Safe Safe Storage

Storage

Protect against external exposure such as frost. Suitable Suitable Packaging Packaging Always keep in containers made of the same materials as the supply container. Store in original container / packaging. Section 8. Exposure Exposure Controls Controls / / Personal Personal Protection Protection Control Control Parameters Parameters / / Limits Limits for for Product Product Not established for the product or its ingredients. Control Control Parameters Parameters / / Limits Limits for for Component Component Propylene glycol PNEC Wastewater 20000 mg/l. Treatment PNEC Seawater 572 mg/l. Sediment PNEC Freshwater 572 mg/l. Sediment DNEL/DMEL General 10 mg/m³, Local effects. Population Inhalation Chronic DNEL/DMEL Worker 186 mg/m³, Systemic effect. Inhalation Chronic 10 mg/m³ (Total Dust), Local effect. PNEC Seawater 26 mg/l. PNEC Freshwater 206 mg/kg. PNEC Soil 50 mg/kg. ACGIH 50 ppm, Ceiling. Poly(oxy-1,2-ethanediyl), alpha-(propylheptyl) DNEL/DMEL General 50 mg/m³, Systemic effect. Population Inhalation Chronic Engineering Engineering Measures Measures Provide adequate general and local exhaust ventilation. Respiratory Respiratory Protection Protection No special respiratory protection specified for the product. Eye/Face Eye/Face Protection Protection Wear safety goggles. Skin Skin and and Body Body Protection Protection Date Created 12/18/2015 Version: 1 Page 3 of 7 No special skin or body protection specified for the product. Hand Hand Protection Protection Wear appropriate chemical resistant gloves. Preventative skin protection (barrier creams / ointments) is recommended. Section 9. Physical Physical and and Chemical Chemical Properties Properties Basic Basic physical physical and and chemical chemical properties properties Information Information PPhhyyssiiccaall SSttaattee liquid AAppppeeaarraannccee Dark Green Color OOddoorr Lemon Fragrance OOddoorr tthhrreesshhoolldd Not available ppHH 7 to 8.5 M Meellttiinngg ppooiinntt Not available BBooiilliinngg ppooiinntt 100°C / 212°F FFllaasshh PPooiinntt Not available EEvvaappoorraattiioonn rraattee ww//rr//tt eetthheerr Not available EEvvaappoorraattiioonn rraattee ww//rr//tt bbuuttyyll Not available aacceettaattee FFllaam mm maabbiilliittyy Not available FFllaam mm maabbiilliittyy lliim miitt Not available VVaappoorr pprreessssuurree 31.69 hPa VVaappoorr ddeennssiittyy Not available RReellaattiivvee ddeennssiittyy ww//rr//tt wwaatteerr 0.98 to 1.02 at 25 °C RReellaattiivvee ddeennssiittyy ww//rr//tt aaiirr Not available RReellaattiivvee ddeennssiittyy ww//rr//tt ootthheerr Not available ssuubbssttaannccee SSoolluubbiilliittyy Not available SSoolluubbiilliittyy iinn ootthheerr ssoollvveennttss Not available PPaarrttiittiioonn ccooeeffffiicciieenntt Not available AAuuttoo--iiggnniittiioonn tteem mppeerraattuurree Not available DDeeccoom mppoossiittiioonn tteem mppeerraattuurree Not available VViissccoossiittyy Not available FFrreeeezziinngg ppooiinntt Not available DDeennssiittyy 1.001 g/ml Section 10. Chemical Chemical Stability Stability & & Reactivity Reactivity Information Information Stability/Reactivity Chemical Chemical stability: stability: This product is stable under ambient condition. Possibility Possibility of of Hazardous Hazardous Reactions Reactions Dangerous reactions are not expected if the technical instructions in storage of chemicals are met. Conditions Conditions to to Avoid Avoid Avoid strong shocks. Version: 1 Page 4 of 7 Date Created 12/18/2015 Hazardous Hazardous Products Products of of Decomposition Decomposition No decomposition hazardous products are specified. Section 11. Toxicological Toxicological Information Information Toxicological Toxicological Information Information for for Product Product No component of this product present at levels greater than or equal to 0.1% is identified as a probable, possible, or confirmed human carcinogen by IARC, OSHA, or the NTP. This product does not contain any reportable health hazards in the US or Europe. Toxicological Toxicological Information Information for for Component Component Propylene glycol LD LD 50 50 Oral Oral 22 g/kg, Mouse. 20 g/kg, Rat. 18500 mg/kg, Rabbit. LD LD 50 50 Dermal Dermal 20800 mg/kg, Rabbit. Poly(oxy-1,2-ethanediyl), alpha-(propylheptyl) LD LD 50 50 Oral Oral 500 mg/kg. Irritation/Corrosion Irritation/Corrosion Information Information for for Product Product Eyes: Eyes: Causes serious eye damage. Section 12. Ecological Ecological Information Information Ecotoxicity Ecotoxicity Values Values for for Product Product Ecotoxicity: Ecotoxicity: This product is not classified as an eco toxin by any regulations in the US or the Europe. Ecotoxicity Ecotoxicity Values Values for for Component Component Poly(oxy-1,2-ethanediyl), alpha-(propylheptyl) LC LC 50 50 Fish: Fish: 10-100 mg/l(96h). EC EC 50 50 Crustacea: Crustacea: 10-100 mg/l(48h), Daphnia magna. Propylene glycol LC LC 50 50 Fish: Fish: 40613 mg/l(96h), Oncorhynchus mykiss. EC EC 50 50 Algae: Algae: 19000 mg/l, Scenedesmus subspicatus(96h). EC EC 50 50 Crustacean: Crustacean: >4000 mg/l(48h), Daphnia magna. Section 13. Disposal Disposal Considerations Considerations Waste Waste Disposal Disposal Regulation(s) Regulation(s) / / Operation Operation Disposal, treatment, or recycling of industrial waste must comply with applicable regulations to preserve the environment. Whenever possible, reuse containers. To do this, rinse container with water and reuse water for another iteration or treat effluent as product residue as indicated in above. Section 14. Transportation Transportation Information Information Other This product is not regulated for transport. Section 15. Regulatory Regulatory Information Information Safety, Safety, Health Health and and Environmental

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