CHOCOLATO

SECTION 2: Hazards identification

EMERGENCY OVERVIEW This mixture has not been evaluated as a whole for health effects. Information provided on health effects of this product is based on the individual components. However, some vapors or contaminants may be released upon heating and the end-user (fabricator) must take the necessary precautions (mechanical ventilation, respiratory protection, etc.) to protect employees from exposure. See sections 8 and 11 for special precautions. Do not use this pigment in polymers at temperatures over 200°C (392°F). Decomposition of diarylide pigments in polymers at temperatures over 200°C (392°F) may produce trace amounts of monoazo dyes, which in turn can decompose to produce aromatic amines. The amount and type of degradation products formed depend on the dwell time, formulation and processing conditions as well as temperature. As conditions become more severe, as when temperatures move into the 240-300°C (464-572°F) range, trace quantities of 3,3'-dichlorobenzidine can be generated. 3,3'-dichlorobenzidine is classified as a suspect carcinogen by NTP and IARC, is classified as Acute Toxicity category 4 and Carcinogen Category 1B according to 1272/2008EC (CLP), and is regulated by OSHA as a suspect carcinogen. In order to avoid the generation of and exposure to 3,3'-dichlorobenzidine, do not use diarylide pigments in polymers when temperatures exceed 200°C (392°F). Handle with care. Organic dusts have the potential to be explosive with static spark or flame initiation.

Principle Routes of Exposure

Inhalation, Skin contact, Ingestion Acute exposure Inhalation : Inhalation of airborne droplets may cause irritation of the respiratory tract. Ingestion : May be harmful if swallowed. Eyes : May cause eye and skin irritation. Skin : Experience shows no unusual dermatitis hazard from routine handling. Chronic exposure : Refer to Section 11 for Toxicological Information.

Medical Conditions Generally Aggravated by Exposure

None known.