307 TILE ADHESIVE PART B

Hazard statements (CLP)

H302, H313, H317, H335

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

GHS Classification Classification of the substance or mixture

Hazard statements

H302: Harmful is swallowed H313: May be harmful in contact with skin H317: May cause an allergic skin reaction H335: May cause respiratory irritation HMIS-ratings (scale 0 - 4) CHEMICAL NAME HEALTH 3 FLAMMABILITY 1 H315 Causes skin irritation H315 Causes skin irritation H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P260: Do not breathe dust/fume/gas/mist/vapours/spray. Page 1 of 5 www.polygem.com Section 2 - HAZARDS IDENTIFICATION (continued) P264: Wash hands thoroughly after handling P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection.

Response

P337+P313 If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use appropriate media for extinction P302+P353 IF ON SKIN Wash with plenty of soap and water for extinction P391: Collect spillage P403+P235: Store in well ventilated place. Keep cool. P501: Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. P261 Avoid breathing mist/vapors/spray P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves, clothing, and eye/face protection. P302 + P352 IF ON SKIN: wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical attention. P337+P313 If eye irritation persists: Get medical attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Physical hazards

0 PERSONAL PROTECTION F 0 PERSONAL PROTECTION F Page 1 of 4 www.polygem.com Section 2 - HAZARDS IDENTIFICATION (CONTINUED) See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal protective equipment recommendations.

2.3 Other hazards

None Known

HMIS® ratings

HEALTH-3, FLAMMABILITY-1, REACTIVITY-0 See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal protective equipment recommendations. CHEMICAL NAME HEALTH 2 FLAMMABILITY 1

Potential health effects

Eye contact: Mild or moderate irritation, possible minor temporary cornea injury. Skin contact: May cause skin irritation on prolonged or repeated exposure. Skin absorption: Not considered toxic. Inhalation: May cause nasal irritation, central nervous system depression or lung injury. Chronic effects of over exposure: None Page 2 of 5 www.polygem.com Section 4: First Aid Measures EMERGENCY & FIRST AID PROCEDURES: Eyes: Flush with plenty of water and get medical attention. Keep eye lids apart. Wash within 1 minute of contact for maximum results. Skin: Promptly wipe clean with paper or cloths and wash with soap and water. Remove contaminated clothing before reuse. Attention should be paid to hair, nose and eyes. Inhalation: In case of exposure to high concentration of vapor or mist, remove person to fresh air. Ingestion: If large amounts are swallowed, induce vomiting. Seek medical attention. May cause burns to mouth and throat. Eye contact: Mild or moderate irritation, possible minor temporary cornea injury. Skin contact: May cause skin irritation on prolonged or repeated exposure. Skin absorption: Not considered toxic. Inhalation: May cause nasal irritation, central nervous system depression or lung injury. Chronic effects of over exposure: None

Principle Routes of Exposure

Inhalation, Ingestion, skin and eye contact. Carcinogenity: This product does not contain 0.1% or more of any substance which is listed as a carcinogen

Storage

Store in a cool, dry place. Page 3 of 5 www.polygem.com Section 8: Exposure Control/Personal Protection Respiratory Protection: If vapor or mist is generated and the occupational exposure limit is exceeded, use appropriate NIOSH/MSHA approved self-contained breathing equipment or a full face respirator. Respirators should be selected by and used following requirements found in OSHA's respirator standards (29 CFR 1910134). Not required for properly ventilation area. Ventilation: Local exhaust and general ventilation is recommended. Hand Protection: Nitrile Rubbers gloves. Eye Protection: Wear safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exits for eye contact with splashing or spraying liquid, or airborne material; Have an eye wash station available. Skin and Body Protection: Avoid skin contact by wearing chemically resistant gloves and long sleeved shirt. An apron may be appropriate if splashing can occur. Section 9: Physical and Chemical Properties Physical state: Gel Color: Gray Odor: Amine Odor Weight by gallon: 14 lbs Solids (% by weight) 100 V.O.C. 0 g/L Boiling range: 335 F Melting point: N/E Density: 1.04 Percent volatile: N/D Vapor density (air=1): Not Volatile Vapor pressure (mm Hg): N/E Evaporation rate: N/A Water miscibility: <0.1% Section 10: Stability and Reactivity Stability: Stable Incompatibility: Strong oxiders, epoxy resin, and amine mixtures especially when hot. Hazardous polymerization: Will not occur. Hazardous decomposition products: Oxides of Carbon and Phenolics under burning conditions Conditions to avoid: Heat and warm storage Not applicable

TOXICOLOGICAL INFORMATION

Chemical Name LD50/LC50 Modified Polyamidoamine Not established

ECOLOGICAL INFORMATION

Overview: No ecological information available. Page 4 of 5 www.polygem.com

Disposal

Considerations To the best of our knowledge, this product does not meet the definition of hazardous waste under U.S. EPA Hazardous Waste Regulations 40 CFR 261. Disposal via incineration at an approved facility is recommended. Consult state, local or provincial authorities for more restrictive requirements. Section 14: Transport Information Consult Bill of Lading for transportation information DOT: Not Regulated IATA: Not Regulated Section 15: Regulatory Information P501 Dispose of contents and containers in accordance with local, regional and international regulations. Precautionary statements are listed according to the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) – Annex III

UN Number

n/a

Further information

This information is furnished without warranty, representation inducement or license of any kind, except that is accurate to the best of Polygem Inc. knowledge, or obtained from sources believed by Polygem Inc. to be accurate and Polygem Inc. does not assure any legal responsibility for use reliance upon the same. Customers are encouraged to conduct their own tests. Before using any product, please read its label. Revision Date: 05/2015 Page 5 of 5 www.polygem.com SAFETY DATA SHEET Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: #307 TILE ADHESIVE PART A Company: POLYGEM INC. PO Box 609 West Chicago, Illinois 60185 Telephone: 630-231-5600 630-231-5604 (Fax Line) Emergency Telephone Number: 1-800-535-5053 USA 01-352-323-3444 International

Classification according to GHS

Skin irritation: Category 2, H315 Skin Sensitization Category 1 H317 Eye irritation: Category 2, H319

Signal word

See SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for personal protective

2.1 Classification of the substance or mixture

Classification according to the Regulation (EC) No. 1272/2008 Acute Dermal Toxicity Category 4 Acute Oral Toxicity Category 4 Skin Sensitization Category 1 Skin Corrosion/Irritation Category 1B Chronic Aquatic Toxicity Category 2 Classification according to the Regulation Directive 199/45/EC: [Xn] Harmful, [C] Corrosive, [N] Dangerous to the Environment Information Concerning particular hazards for human and environment: Product Description: This product is grey heavy paste with a sweet amine odor Health Hazards: Corrosive, Severe eye irritant; Respiratory Irritant, may cause skin sensitization. Flamability Hazards: This product is flammable above it's fashpoint of 380F (195 C) Reactivity Hazards: None known. Environmental Hazards: The environmental effects of this product have not been investigated; however it is not expected to cause significant adverse effects. Emergency Considerations: Emergency responders must wear proper personal protective equipment (and have appropriate fire suppresion equipment) suitable for the situation to which they are responding. Classification system: This classification is according to the latest editions of the EU-lists, and extended by company and literature data.