RoofSkin (Part B)

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

CLP CLASSIFICATION

Eye Irrit. 2 H319; Acute Tox. 4 H332; Carc. 2 H351; Resp

Most important adverse effects

Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure

Hazard statements

H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H373: May cause damage to organs through prolonged or repeated exposure

Hazard pictograms

GHS07 Exclamation mark GHS08 Health hazard 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Carbon dioxide. Foam Dry Powder 5.2. Special hazards arising from the substance or mixture Exposure hazards: Burning produces noxious and toxic fumes. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Evacuate personnel to safe areas. Wear suitable protective equipment. 6.2. Environmental precautions Environmental precautions: Should not be released into the environment Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Transfer to a suitable container. Absorb into dry earth or sand. 6.4. Reference to other sections Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. 7.3. Specific end use(s) Section 8: Exposure controls/personal protection 8.1. Control parameters

Hazardous Ingredients

DIPHENYLMETHANE DIISOCYANATE (ISOMERS AND HOMOLOGUES) Workplace Exposure Limits Respirable Dust State 8 hour TWA 15min. STEL 8 hour TWA 15 min. STEL UK 0.02 mg/m3 0.07 mg/m3 - DIPHENYLMETHANE-4,4'-DI-ISOCYANATE UK 0.02 mg/m3 0.07 mg/m3 DNEL/PNEC Values: DNEL / PNEC No data available 8.2. Exposure controls Engineering measures: Ensure there is exhaust ventilation of the area. Hand protection: Butyl gloves. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles. Skin protection: Impermeable protective clothing. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Liquid Colour: Dark brown Odour: Characteristic odour Flash point°C: 200-250oc

Further information

No data available Section 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. 10.4. Conditions to avoid Conditions to avoid: Heat. Flames. Materials to avoid: Water. Alcohols. Strong oxidising agents. Amines. Strong acids. Strong bases. 10.5. Incompatible materials 10.6. Hazardous decomposition products Section 11: Toxicological information 11.1. Information on toxicological effects Hazardous ingredients: DIPHENYLMETHANE DIISOCYANATE (ISOMERS AND HOMOLOGUES) ORL RAT LD50 49 gm/kg SKN RBT LD50 >9400 mg/kg DIPHENYLMETHANE-4,4'-DI-ISOCYANATE ORL MUS LD50 2200 mg/kg ORL RAT LD50 9200 mg/kg Relevant hazards for product: Hazard Route Basis Acute toxicity (ac. tox. 4) INH Hazardous: calculated Skin corrosion/irritation DRM Hazardous: calculated Serious eye OPT Hazardous: calculated damage/irritation Respiratory/skin sensitisation INH DRM Hazardous: calculated Carcinogenicity -- Hazardous: calculated STOT-single exposure INH Hazardous: calculated STOT-repeated exposure - Hazardous: calculated Symptoms / routes of exposure Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: No data available.