~ 12092TF

Hazard statements (CLP)

H315, H319, H336, H341, H350, H351, H360, H411, H412

Code

Statements

H315

Causes skin irritation

Classification system

NFPA Rating - NFPA ratings (scale 0 - 4) Health = 2 Fire=0 Reactivity = 0

HMIS® ratings

(scale 0 - 4) HEALTH Health = *2 FIRE [0] Fire=0 [0] Reactivity =0 - Chemical characterization: Mixtures - Description: Mixture of the substances listed below with nonhazardous additions.

Hazardous Ingredients

79-01-6 Acetylene Trichloride (Trichloroethylene ) 70-90% Muta. 2, H341; Carc. 1B, H350; Repr. 1A, H360; @ Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H336; Aquatic Chronic 3, H412 127-18-4 tetrachloroethylene 15-35% @ Carc. 2, H351; @Aquatic Chronic 2, H411 -SVHC 79-01-6 | Acetylene Trichloride (Trichloroethylene ) (Contd. of page 2) - Description of first aid measures - General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. - After inhalation: In case of unconsciousness, place patient securely on side position for transportation. - After skin contact: Immediately wash with water and soap and rinse thoroughly. - After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. - After swallowing: Immediately call a doctor. - Most important symptoms and effects, both acute and delayed No further relevant information available. - Indication of any immediate medical attention and special treatment needed No further relevant information available. - Extinguishing media - Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. - Special hazards arising from the substance or mixture No further relevant information available. - Advice for firefighters - Protective equipment: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. - Personal precautions, protective equipment and emergency procedures Not required. - Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. - Methods and material for containment and cleaning up: Absorb with liquid-binding material (ie. sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. Dispose of the collected material according to regulations. - Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. - Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. - Information about protection against explosions and fires: Keep protective respiratory device available. - Conditions for safe storage, including any incompatibilities

Storage

- Requirements to be met by storerooms and receptacles: No special requirements. - Information about storage in one common storage facility: Not required. (Contd. of page 3) - Further information about storage conditions: Keep receptacle tightly sealed. - Specific end use(s) No further relevant information available. - Additional information about design of technical systems: No further data; see section 7. - Control parameters - Components with occupational exposure limits: 79-01-6 Acetylene Trichloride (Trichloroethylene ) PEL Long-term value: 100 ppm Ceiling limit value: 200; 300* ppm *5-min peak in any 2 hrs REL See Pocket Guide Apps. A and C TLV | Short-term value: 135 mg/m?, 25 ppm Long-term value: 54 mg/m?, 10 ppm BEI 127-18-4 tetrachloroethylene PEL Long-term value: 100 ppm Ceiling limit value: 200; 300* ppm *5-min peak in any 3 hrs REL Minimize workplace exp. concs.;Pocket Guide App. A TLV | Short-term value: 685 mg/m?, 100 ppm Long-term value: 170 mg/m?, 25 ppm BEI - Ingredients with biological limit values: 79-01-6 Acetylene Trichloride (Trichloroethylene ) BEI 15 mg/L urine end of shift at end of workweek Trichloroacetic acid (nonspecific) 0.5 mg/L blood end of shift at end of workweek Trichloroethanol without hydrolysis (nonspecific) blood end of shift at end of workweek Trichloroethylene (semi-quantitative) end-exhaled air end of shift at end of workweek Trichloroethylene (semi-quantitative) (Contd. of page 4) 127-18-4 tetrachloroethylene BEI 3 ppm end-exhaled air prior to shift Tetrachloroethylene 0.5mg/L blood prior to shift Tetrachloroethylene

Additional information

The lists that were valid during the creation were used as basis - Exposure controls - Personal protective equipment: - General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. - Breathing equipment: Not required. - Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Select glove material based on penetration times, rates of diffusion and degradation. - Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. - Penetration time of glove material The exact break-through time has to be determined and observed by the manufacturer of the protective gloves. - Eye protection: Tightly sealed goggles - Information on basic physical and chemical properties - General Information - Appearance: Form: Liquid Color: Clear - Odor: Characteristic - Odor threshold: Not determined. - pH-value: Not determined. (Contd. of page 5) - Change in condition Melting point/Melting range: Not determined. Boiling point/Boiling range: 87 °C (189 °F) - Flash point: Not applicable. - Flammability (solid, gaseous): Not applicable. - Ignition temperature: 410 °C (770 °F) - Decomposition temperature: Not determined. - Auto igniting: Product is not selfigniting. - Danger of explosion: Product does not present an explosion hazard. - Explosion limits: Lower: 7.9 Vol % Upper: 90.0 Vol % - Vapor pressure @ 20 °C (68 °F): 77 hPa (58 mm Hg) - Density @ 20 °C (68 °F): 1.493 glcm? (12.459 Ibs/gal) - Relative density Not determined. - Vapour density Not determined. - Evaporation rate Not determined. - Solubility in / Miscibility with Water: Not miscible or difficult to mix. - Partition coefficient (n-octanol/water): Not determined. - Viscosity: Dynamic: Not determined. Kinematic: Not determined. - Solvent content: Organic solvents: 100.0 % VOC content: 80.0 %

Further information

No further relevant information available. - Reactivity No further relevant information available. - Chemical stability Stable under normal conditions. - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. - Possibility of hazardous reactions No dangerous reactions known. - Conditions to avoid No further relevant information available. - Incompatible materials: No further relevant information available. - Hazardous decomposition products: No dangerous decomposition products known. - Information on toxicological effects - Acute toxicity: - LD/LC50 values that are relevant for classification: 79-01-6 Acetylene Trichloride (Trichloroethylene ) Oral LD50 2402 mg/kg (mouse) (Contd. of page 6) Dermal LD50 8450 mg/kg (mouse) 127-18-4 tetrachloroethylene Oral LD50 2629 mg/kg (rat) - Primary irritant effect: - on the skin: Irritant to skin and mucous membranes. - on the eye: Irritating effect. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic. - Carcinogenic categories - IARC (International Agency for Research on Cancer) 79-01-6 Acetylene Trichloride (Trichloroethylene ) 2A 127-18-4 tetrachloroethylene 2A - NTP (National Toxicology Program) 79-01-6 Acetylene Trichloride (Trichloroethylene ) R 127-18-4 tetrachloroethylene R - OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed. - Toxicity - Aquatic toxicity: Toxic to aquatic life - Persistence and degradability No further relevant information available. - Bioaccumulative potential No further relevant information available. - Mobility in soil No further relevant information available. - Ecotoxical effects

Remarks

Harmful to fish - Additional ecological information: - General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Harmful to aquatic organisms

PBT Substances

Not applicable

vPvB Substances

Not applicable

Other hazards

No further relevant information available - Waste treatment methods - Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. of page 7) - Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations.

UN Number

- DOT, ADR, IMDG, IATA UN3287 - UN proper shipping name -DOT Toxic liquid, inorganic, n.o.s. -ADR UN3287 Toxic liquid, inorganic, n.o.s. - IMDG TOXIC LIQUID, INORGANIC, N.O.S. (TETRACHLOROETHYLENE), MARINE POLLUTANT - IATA TOXIC LIQUID, INORGANIC, N.O.S. - Transport hazard class(es) -DOT 6.1 Toxic substances 6.1 6.1 Toxic substances 6.1 - Class 6.1 Toxic substances - Label 6.1 - Packing group - DOT, ADR, IMDG, IATA

Environmental hazards

- Marine pollutant: Yes Symbol (fish and tree) - Special marking (ADR): Symbol (fish and tree) - Special precautions for user Warning: Toxic substances (Contd. of page 8) - EMS Number: F-AS-A - Segregation groups Liquid halogenated hydrocarbons - Transport in bulk according to Annex Il of MARPOL73/78 and the IBC Code Not applicable. - Transport/Additional information: -DOT - Quantity limitations On passenger aircraft/rail: 60L On cargo aircraft only: 220L -ADR - Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml - UN "Model Regulation™: UN3287, Toxic liquid, inorganic, n.o.s., 6.1, lll - Safety, health and environmental regulations/legislation specific for the substance or mixture - Sara - Section 355 (extremely hazardous substances): None of the ingredients are listed. - Section 313 (Specific toxic chemical listings): All ingredients are listed. - TSCA (Toxic Substances Control Act): All ingredients are listed. - Proposition 65 - Chemicals known to cause cancer: All ingredients are listed. - Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. - Chemicals known to cause reproductive toxicity for males: 79-01-6 | Acetylene Trichloride (Trichloroethylene ) - Chemicals known to cause developmental toxicity: 79-01-6 | Acetylene Trichloride (Trichloroethylene ) - Carcinogenic categories - EPA (Environmental Protection Agency) 79-01-6 Acetylene Trichloride (Trichloroethylene ) CaH 127-18-4 tetrachloroethylene L - TLV (Threshold Limit Value established by ACGIH) 79-01-6 Acetylene Trichloride (Trichloroethylene ) A2 127-18-4 tetrachloroethylene A3 - NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. - GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. of page 9) - Hazard pictograms % GHS07 GHS08 - Signal word Danger - Hazard-determining components of labeling: Acetylene Trichloride (Trichloroethylene ) tetrachloroethylene - Hazard statements Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. - Precautionary statements Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Avoid release to the environment. Wash thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). Take off contaminated clothing and wash before reuse. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of water. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations. - National regulations: The product is subject to be labeled according with the prevailing version of the regulations on hazardous substances. - State Right to Know 79-01-6 Acetylene Trichloride (Trichloroethylene ) 70-90% < Muta. 2, H341; Carc. 1B, H350; Repr. 1A, H360; @Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H336; Aquatic Chronic 3, H412 127-18-4 tetrachloroethylene 15-35% @ Carc. 2, H351; @Aquatic Chronic 2, H411 All ingredients are listed. (Contd. of page 10) - Information about limitation of use: Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases.