HS-5504

Hazard statements (CLP)

H225, H301, H302, H311, H312, H314, H317, H331, H332, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA Acute Toxicity: Oral, Category 3 Acute Toxicity: Skin, Category 3 Skin Corrosion/Irritation, Category 1B Skin Sensitization, Category 1 Acute Toxicity: Inhalation, Category 3 Carcinogenicity, Category 2 Acute Toxicity: Oral, Category 4 Acute Toxicity: Skin, Category 4 Acute Toxicity: Inhalation, Category 4 Flammable Liquids, Category 2 Specific Target Organ Toxicity (single exposure), Category 1

Signal word

Danger

Hazard statements

H301 - Toxic if swallowed. H311 - Toxic in contact with skin. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H331 - Toxic if inhaled. H351 - Suspected of causing cancer . H302 - Harmful if swallowed. H312 - Harmful in contact with skin. H332 - Harmful if inhaled. H225 - Highly flammable liquid and vapor.

Precautionary statements

P264 - Wash hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P361+364 - Take off immediately all contaminated clothing and wash it before reuse. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P362+364 - Take off contaminated clothing and wash it before reuse. P271 - Use only outdoors or in a well-ventilated area. P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P281 - Use personal protective equipment as required. P233 - Keep container tightly closed. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/.../ equipment. P243 - Take precautionary measures against static discharge. P242 - Use only non-sparking tools.

Response

P301+310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P330 - Rinse mouth. P312 - Call a POISON CENTER/doctor/... if you feel unwell. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363 - Wash contaminated clothing before reuse. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P333+313 - If skin irritation or rash occurs, seek medical advice/attention. P308+313 - IF exposed or concerned: Get medical attention/advice.

Storage

P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place. P403+235 - Store in cool/well-ventilated place. OSHA Regulatory Status: This material is classified as hazardous under OSHA regulations.

Potential health effects

Though a single exposure may cause no effect, daily exposures may result in the (Acute and Chronic): accumulation of a harmful amount. Prolonged or repeated skin contact may cause dermatitis. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Harmful if inhaled. Skin: Harmful if absorbed through skin. Causes skin burns. Inhalation is the most common route of occupational exposure. Skin Contact: Causes burns. Skin Absorption: Readily absorbed through skin. Toxic if absorbed through skin. May cause skin irritation. Causes moderate skin irritation. May be absorbed through the skin in harmful amounts. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Eye Contact: Causes eye burns. May cause eye irritation. May cause painful sensitization to light. Methanol is a mild to moderate eye irritant. Inhalation, ingestion or skin absorption of methanol can cause significant disturbances in vision, including blindness. Ingestion: Toxic if swallowed. Ingestion can cause immediate burning pain in the mouth, throat, abdomen; severe swelling of the larynx and skeletal paralysis affecting the ability to breathe, circulatory shock and convulsions. May cause allergic respiratory and skin reactions. May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Harmful if swallowed. Causes eye burns. May be fatal or cause blindness if swallowed.

Aspiration hazard

Cannot be made non-poisonous. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause cardiopulmonary system effects.