Phenol-formaldehyde resol molding compound

Hazard statements (CLP)

H315, H317, H318, H341, H350

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture

Health hazards

Serious Eye Damage/ Eye Irritation, Category 1 Skin Irritation, Category 2 Skin Sensitization, Category 1 Germ Cell Mutagenicity, Category 2 Carcinogenicity, Category 1B Corrosion Exclamation mark

Physical hazards

Combustible Dust

Signal word

DANGER

Hazard statements

H318: Causes serious eye damage. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H341: Suspected of causing genetic defects. H350: May cause cancer. H: May form combustible dust concentrations in air.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P261: Avoid breathing dust. P264: Wash hands and forearms thoroughly after handling. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response

P302+P352 IF ON SKIN Wash with plenty of water and soap P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/ attention P310: Immediately call a doctor if eyes have come in contact with this material. P321 Specific treatment Wash affected areas immediately with plenty of water and soap P333+P313 If skin irritation or rash occurs Get medical advice/attention P362+P364: Take off contaminated clothing and wash it before reuse.

Storage

P405: Store locked up.

Disposal

P501: Dispose of contents and empty containers in accordance with local, regional and federal regulations.

2.3 Other hazards

AS SOLD the product is a plastic molding compound A plastic resin (phenol- formaldehyde polymer) intimately mixed and compounded with one or more of a variety of organic and/or inorganic filling materials. When fully “cured” or reacted, the plastic resin is insoluble, infusible and binds the well- dispersed, embedded filling materials. Some particles of molding compound may be present in a size that constitutes a respirable dust. This respirable dust may contain one or more of the following materials: carbon black, coal dust, fibrous glass, graphite, mineral fillers that may contain small amounts of crystalline silica, wood flour and/or other organic fibers. Chronic inhalation of each of the above has been associated with fibrotic lung disease and may increase the risk of lung cancer, especially among smokers. AS USED during polymerization (e.g., curing of the product during normal processing) or decomposition, small amounts phenol and formaldehyde (as well as water vapor, carbon monoxide and carbon dioxide) may be evolved. Grinding or machining of cured molded material may create a dust that poses a respiratory hazard if inhaled (see above). Comments: Refer to Section 5 for additional information on combustible dust hazards and Section 11 for detailed information on health effects and symptoms.

2.1 Classification of the substance or mixture

Health hazards: Serious Eye Damage/ Eye Irritation, Category 1 Skin Irritation, Category 2 Skin Sensitization, Category 1 Germ Cell Mutagenicity, Category 2 Carcinogenicity, Category 1B Physical hazards: Combustible Dust