RS 600 -­‐ A Component

SECTION 2: Hazards identification

Ch m al harac r zat on · D s r pt on: M ur of he subs anc s s d be ow w h nonhazardous addi ons. Dangerous ompon n s: r 25068-­‐38-­‐6 a on produ : b sph no -­‐A-­‐( p hlorhydr n) po r s n (numb r av rage mol u ar w gh = 700) 75-­‐100% 1317-­‐65-­‐3 2. L m s one 10% · Addi onal nformat on: For he wording of he s on 16. · d r s phras s r r o s · Hazard des r pt on: May aus and s n rr at on. Prolonged ontac may aus s ns zat on. · Informat on per ain ng o par u ar dangers for man and n ronm n : The produc has o be abe d due o nt rnat onal ac now dged al ulat on proc dur s us ng he at s al d rs ons. · C ass f at on s s m: Th ass a on was mad a ord ng o h a s di ons of n rna onal subs an s s s, and pand d upon rom ompany and ratur data. · NFPA rat ngs (s al 0 -­‐ 4) 1 H r = 1 1 al h = 1 F R ac = 0 · HMIS-­‐rat ngs (s al 0 -­‐ 4) H al h = 1 F r = 1 3. R ac = 0 · Af r nhalat on: Suppl r sh air and o be sur al or a doc or. 4. In as of uncons ousness plac pat nt s abl n s de pos on or ranspor at on. nam : RS 600 – A Component 8. Exposure controls and personal protection · Page 2/6 03/21/2014 Af Imm r skin on ac : diat wash w h wat r and soap and r ns horoughl . I s n rr at on ont nues, onsul a doc or. · Af r on ac : R ns opened or s ral m nut s under running wat r. Then onsul a doc or. · Af r swal ow ng: Se mm diat m di al adv . Trade Se m di al r atm nt. Fire fighting measures · · Su abl xt ngu sh ng agen s: CO2, nguishing powder or wat r spray. F ght arger r s w h wat r spray or al ohol r s s ant oam. · Prot qu pm n : B aus r may produc herma de ompos on produ s, w ar a s -­‐ on a n d br athing apparatus (SCBA) w h a u ac pi 5. operat d n pr ssur -­‐demand or pos -­‐pr ssur mode. Date: Accidental release measures · P rson-­‐r at d saf pr au ons: W ar prot quipm nt. K p unprot d persons away. · M asur s for n ronm n al prot on: Inform r spe author s n as of s page nto wat r ours or s wage s s m. · M asur s for an ng/ ol ng: Absorb w h quid-­‐binding mat r al (sand, diatom , ac d binders, uni rsal binders, sawdus ). Ensur adequat at on. nt 6. 7. Handling and storage · Handl ng: Informat on for saf handl ng: W ar appropr at personal pro oth ng o pr n and s n on ac . A oid br a hing apors or m s s of his produc . Us w h adequat nt at on. Do not ak nt rnal . · Informat on abou prot on agains xplos ons and f r s: No spe al m asur s r quir d. · S orage: · R qu r m n s o be m by s or rooms and r ptac s: Stor n a ool dr ocat on. · Informat on abou s orage n on ommon s orage fac : Stor away rom ncompat bl mat r als. s al d. · Fur h r nformat on abou s orage ondi ons: K p r ptac ght · · Addi onal nformat on abou des gn of hn al s s Addi onal nformat on: The s s hat w r al d dur ng he r at on w r ms: No ur her data; s us d as bas s. m 7. Compon n s w h m 1317-­‐65-­‐3 L m s on alu s hat r qu r mon or ng at h workplac : PEL 5** mg/m ) · REL 10*; TLV 15*; 10 *Total mg/m 5** mg/m dus **R spirabl rac on *Total dus **R spirabl rac on ( nam : RS 600 – A Component Page 3/6 03/21/2014 10. Stability and reactivity 9. · P rsonal prot qu pm n : · G n ral prot and h gi n m asur s: K p away rom oods uf s, be rages and d. Imm diat r mov al soi d and ontam nat d othing. Wash hands be or br aks and at he nd of wor . A oid ontac w h he s and s n. · Br ath ng qu pm n : In as o br posur or ow po u on us r sp ra or r d . In as o n ns or ong r posur us r spirator prot de hat s ndependent of r ulat ng air. · Prot on of hands: Prot glov s The glov mat r al has o be mperm abl and r s s ant o he produc he subs anc he pr parat on. Trade · E prot on: W ar appropr at prot on o pr nt ontac . Date: Physical and chemical properties G n ral Informat on Form: Color: Odor: L C quid ar M d · Change n ondi on M ng poin M ng range: Unde rm ned. Boi ng poin Boi ng range: Unde rm ned. · F ash poin : > 93°C (> 199°F) · Au o gn ng: Produc s not s gni ng. · Danger of xplos on: Produc does not pr s nt an plos on hazard. · D ns at 20°C (68°F): 1.200 g/ m · Solubi n M s bi w h Wat r: Not m s bl or di ul o m . · Sol n on n : Organ sol n s: 0.0 % · Sol ds on n : 100.0 % Compounds: Not de rm ned · Volat Organ · Th rmal de ompos on ondi ons o be avoided: No de ompos on us d ac ording o spe at ons. · Dangerous r ac ons R ac s w h ac ds, al al s and ox diz ng agents. on: Carbon monox de and arbon diox de · · Dangerous produ s of de ompos nam : RS 600 – A Component 14. Transport information Date: 13. Page 4/6 03/21/2014 USA

TOXICOLOGICAL INFORMATION

A u oxi : · Pr mar rr an ff : · on h skin: May aus s n rr at on. · on h : Irr at ng . · S ns zat on: Sens zat on poss bl hrough s n ontac . · Addi onal oxi ologi al nformat on: Trade The produc shows he ol ow ng dangers ac ording o nt rnal approv d al ulat on m hods or pr parat ons: Irr ant 11.

ECOLOGICAL INFORMATION

E otoxi al ff s: · R mark: Tox or sh · G n ral not s: Wat r hazard ass 1 (Se -­‐ass ssm nt): s ght hazardous or wat r A so poisonous or sh and plank on n wat r bodi s. organisms Tox or aquat 12. Disposal considerations · Produ : · R omm ndat on: Mus not be dispos d of as normal garbage. Do not al ow produc o r ach s wage s s m. I s he generator s r spons bi o de rm ne he was m s appl abl de ni ons of hazardous was . Stat and ocal r gulat ons may d r rom d ra disposal r gu at ons. D spos of was mat r al a ording o o al, s at , d ra , and prov nc al nv ronm ntal r gulat ons. R omm ndat on: D sposal mus be made ac ording o F deral, Stat , and Local r gulat ons. · Un an d packagings: · · DOT r gu at ons: Not R gulat d · Hazard ass: N A · Packing group: III · R marks: Add Mar ne Pol utant o nd of proper shipping nam shipping n a bul ontainer (>119 gal ons). Not R gulat d or Transpor . · L m d Quan Exempt on: No L m d Quant mpt on appl s or his shipping ass. · U.S. Dom s Ground Sh pm n s: Sam as s d or Standard Shipm nts abov . · U.S. Dom s Ground Non-­‐Bu k (119 gal or ss per · on ain r) Sh pm n s: Sam as s d or Standard Shipm nts abov . · Land ranspor ADR RID ( ross-­‐border): ADR RID ass: N A ·

UN Number

Packaging group: III R marks: Not R gulat d or Transpor . · nam : RS 600 – A Component ·∙ Cancerogenity categories ·∙ Page 5/6 3/21/2014 USA · Mar m ranspor IMDG: · IMDG C ass: 9 · 3082 · Packaging group: III · Mar n pol u an : Y s · Propper sh pping nam : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( pox r s n) · A r ranspor ICAO-­‐TI and IATA-­‐DGR: · ICAO IATA C ass: -­‐ Trade · Packaging group: III Date: Regulations 15. Sara d. S None on 355 ( xtr m of he ngr di nt s s hazardous subs an s): Proposition 65 S on 313 (Spe f oxi h m al s ngs): Th s produ r qu r m n s of Se on 313 of T III of he Super und Am ndm nts and R author zat on A may ontain 1 or mor ox h m als subj o he r por ng (SARA) of 1986 and 40 CFR par 372. I · so, he hem als ar s d be ow. · · None Ch m als known o aus de opm n al oxi : -­‐ · d. · TSCA (Toxi Subs an of he ngr di nts s s s Con rol A d. ): A ngr di nts ar s 25068-­‐38-­‐6 Ch m als known o h r ac on produc : bisphenol-­‐A-­‐( pi hlorhydr n) pox S at of Cal forn a (Prop. 65) o aus an r s n (number av rage mol r: ular w ght = 700) · Ch m als known o aus r produ oxi for f mal s: None of he ngr di nts s s d. · Ch m als known o aus r produ oxi for mal s: None of he ngr di nts s s d. · EPA (En ronm n al Prot None on Agen ) None of he ngr di nts s s d. of he ngr di nts s s d. IARC (In 14807-­‐96-­‐6 rnat onal Agen Tal (Mg3H2(SiO3)4) 3 for R s ar h on Can r) · NTP (Nat onal Toxi ology Program) None of he ngr di nts s s d. · TLV (Thr shold L m Valu s abl sh d by ACGIH) 14807-­‐96-­‐6 Tal (Mg3H2(SiO3)4) A4 · MAK (G rman Maximum Workplac Con n rat on) None of he ngr di nts s s d. · d. · NIOSH-­‐Ca (Nat onal Ins u for O upat onal Saf and H al h) None of he ngr di nts s s This n orma on s bas d on our pr s nt now dg . How Date: Page 6/6 3/21/14 nam : RS 600 – A Component None Trade of he ngr di nts s s d. OSHA-­‐Ca (O upat onal Saf & H al h Adm n s rat on) · Produ r at d hazard nformat ons: The produc has be n ass d and mar d n ac ordanc w h dir s on hazardous mat r als. · Hazard s mbols: X Irr ant N Dangerous or he nv ronm nt · Hazard-­‐de rm n ng ompon n s of abe ng: r ac on produc : bisphenol-­‐A-­‐( pi hlorhydr n) pox r s n (number av ragemol ular w ght = 700) · R sk phras s: 36/38 Irr at ng o s and s n. 43 May aus s ns sat on by s n ontac . 51/53 Tox o aquat organisms, may aus ong-­‐ rm adv rs s n he aquat nv ronm nt. · Saf phras s: 23 Do not br athe gas um s apour spray (appropr at wording o be spe d by he manufac ur r). 24/25 A oid ontac w h s n and s. 26 In as of ontac w h s, r ns mm diat w h pl nt of wat r and s m di al adv . 28 A r ontac w h s n, wash mm diat w h pl nt of … ( o be spe d 29 Do not mpt nto drains. 37/39 W ar sui abl glov s and ac prot on. 46 I swal ow d, s m di al adv mm diat and show his ontainer or abe . I swal ow d, r ns mouth w h wat r (onl he person s ons ous). · 64

Further information

r, his shal no ons ut a guaran or any spe produc 16 · D par m n ssu ng MSDS: Env ronm ntal, H al h & Saf atur s and shal not s abl sh a gal al d ontrac ual r at onship. D par m nt · Con ac : Env ronm ntal, H al h & Saf Manager 3. 3/21/14 Page 1/7 Identification of substance Ÿ Product details Ÿ Trade name: RS 600 -­‐B Component Ÿ Manufacturer /Supplier: Pilgrim Permocoat, Inc. 402 S. 22nd Street Tampa, FL 33605 Tel: (800) 637 3328 Fax: (813) 248 1076 2. Ÿ Composition/Data on components Ÿ Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. HEALTH=3 Fire = HEALTH=3 471-­‐34-­‐1 Calcium carbonate 25-­‐50% Components: 140-­‐31-­‐8 2-­‐piperazin-­‐1-­‐ylethylamine 10-­‐25% 111-­‐41-­‐1 2-­‐(2-­‐aminoethylamino) ethanol 10-­‐25% 694-­‐83-­‐7 Cyclohex-­‐1,2-­‐ylenediamine 10-­‐25% 90-­‐72-­‐2 2,4,6-­‐tris(dimethylaminomethyl)phenol ≤ 5% Date: 1317-­‐65-­‐3 Ÿ Limestone ≤ 5%

Additional information

For the wording of the listed risk phrases refer to section 16. Ÿ Information pertaining to particular dangers for man and environment:

Hazard statements

Not applicable. The product has to be labeled due to internationally acknowledged calculation procedures using the latest valid versions. Ÿ

Classification system

The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Ÿ NFPA ratings (scale 0-­‐4) Dangerous 3 1 2 FIRE=1 REACTIVITY=2 HMIS-­‐ratings (scale 0-­‐4) Ÿ -­‐ Health = FIRE=1 REACTIVITY=2 HAZARD 1. PHYSICAL 3/21/14 Page Material Safety Data Sheet 2/7 Trade name: RS 600 – B Component 4.