DIESEL FUEL

Hazard statements (CLP)

H226, H304, H315, H332, H336, H351, H373

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance Bright oily liquid. Colour Clear to yellow (This product may be dyed red for taxation pur- poses) Odour Mild petroleum oil like. GHS Classification Flammable liquids Category 3 Acute toxicity (Inhalation) Category 4 Skin irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity - single exposure Category 3 (Central nervous system) Specific target organ toxicity Category 2 (Liver, thymus, Bone) repeated exposure

Aspiration hazard

Category 1

Signal word

Danger

Hazard statements

Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. Harmful if inhaled. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs (Liver, thymus, Bone) through prolonged or repeated exposure.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response

IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. IF exposed or concerned: Get medical advice/ attention. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

Disposal

Dispose of contents/ container to an approved waste disposal plant.

Principle Routes of Exposure

Eye contact Ingestion Inhalation Skin contact Aggravated Medical Condi- tion : None known.

Other hazards

None known

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 Acute toxicity (Inhalation) : Category 4 Skin irritation : Category 2 Carcinogenicity : Category 2 Specific target organ toxicity : Category 3 (Central nervous system) - single exposure Specific target organ toxicity : Category 2 (Liver, thymus, Bone) - repeated exposure Aspiration hazard : Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. Harmful if inhaled. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs (Liver, thymus, Bone) through prolonged or repeated exposure. Precautionary statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER/doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. IF exposed or concerned: Get medical advice/ attention. Do NOT induce vomiting. If skin irritation occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Potential Health Effects Primary Routes of Entry : Eye contact Ingestion Inhalation Skin contact Aggravated Medical Condi- : None known. tion Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration Kerosine (petroleum), hydrodesulfurized; Kero- 64742-81-0 70 - 100 % sine — unspecified Kerosine (petroleum); Straight run kerosine 8008-20-6 Fuels, diesel; Gasoil — unspecified 68334-30-5 Alkanes, C10-20-branched and linear 928771-01-1 0 - 30 % Fatty acids, C16-18 and C18-unsatd., Me esters 67762-38-3 0 - 20 % All above concentrations are in percent by weight. SECTION 4. FIRST AID MEASURES If inhaled : Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice. In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice. In case of eye contact : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. If swallowed : Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physi- cian or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice. Most important symptoms : Harmful if inhaled. and effects, both acute and Respiratory, skin and eye irritation; nausea; cancer. delayed Notes to physician : Treat symptomatically. For specialist advice physicians should contact the Poisons Information Service. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Dry chemical Carbon dioxide (CO2) Water fog. Foam Unsuitable extinguishing : Do NOT use water jet. media Specific hazards during fire- : Cool closed containers exposed to fire with water spray. fighting Hazardous combustion prod- : Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur ucts oxides (SOx), smoke and irritating vapours as products of incomplete combustion. Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec- for firefighters essary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : For personal protection see section 8. tive equipment and emer- Ensure adequate ventilation. gency procedures Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for : Prevent further leakage or spillage if safe to do so. containment and cleaning up Remove all sources of ignition. Soak up with inert absorbent material. Non-sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid spark promoters. Ground/bond container and equip- ment. These alone may be insufficient to remove static elec- tricity. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use. Conditions for safe storage : Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well-ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sun- light. Ensure the storage containers are grounded/bonded. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type Control parame- Basis (Form of ters / Permissible exposure) concentration Kerosine (petroleum), hy- 64742-81-0 TWA 200 mg/m3 ACGIH drodesulfurized; Kerosine — (As total hydro- unspecified carbon vapour) TWA 200 mg/m3 CA AB OEL (total hydrocarbon vapor) TWA 525 mg/m3 CA ON OEL TWA 200 mg/m3 ACGIH (As total hydro- carbon vapour) TWA 200 mg/m3 ACGIH (total hydrocarbon vapor) Kerosine (petroleum); Straight 8008-20-6 TWA 200 mg/m3 CA BC OEL run kerosine (total hydrocarbon vapor) TWA 200 mg/m3 CA AB OEL (total hydrocarbon vapor) TWA 200 mg/m3 ACGIH (total hydrocarbon vapor) Fuels, diesel; Gasoil — un- 68334-30-5 TWA 100 mg/m3 CA AB OEL specified (total hydrocar- bons) TWA (Va- 100 mg/m3 CA BC OEL pour and (total hydrocar- inhalable bons) aerosols) TWA (Inhal- 100 mg/m3 ACGIH able fraction (total hydrocar- and vapor) bons) Engineering measures : Adequate ventilation to ensure that Occupational Exposure Limits are not exceeded. Use only in well-ventilated areas. Ensure that eyewash station and safety shower are proximal to the work-station location. Personal protective equipment Respiratory protection : Concentration in air determines protection needed. Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Filter type : organic vapour cartridge or canister may be permissible un- der certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is limited. Use a positive-pressure, air-supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circum- stances where air-purifying respirators may not provide ade- quate protection. Hand protection Material : neoprene, nitrile, polyvinyl alcohol (PVA), Viton(R). Consult your PPE provider for breakthrough times and the specific glove that is best for you based on your use patterns. It should be realized that eventually any material regardless of their imperviousness, will get permeated by chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of hardening and cracks, they should be changed. Remarks : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is nec- essary. Eye protection : Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Choose body protection in relation to its type, to the concen- tration and amount of dangerous substances, and to the spe- cific work-place. Protective measures : Wash contaminated clothing before re-use. Hygiene measures : Remove and wash contaminated clothing and gloves, includ- ing the inside, before re-use. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Bright oily liquid. Colour : Clear to yellow (This product may be dyed red for taxation purposes) Odour : Mild petroleum oil like. Odour Threshold : No data available pH : No data available Melting point : No data available Boiling point/boiling range : 150 - 371 °C (302 - 700 °F) Decomposition temperature No data available Flash point : > 40 °C (104 °F) Method: closed cup Auto-Ignition Temperature : 225 °C (437 °F) Evaporation rate : No data available Flammability : Flammable in presence of open flames, sparks and heat. Va- pours are heavier than air and may travel considerable dis- tance to sources of ignition and flash back. This product can accumulate static charge and ignite. Upper explosion limit : 6 %(V) Lower explosion limit : 0.7 %(V) Vapour pressure : 7.5 mmHg (20 °C / 68 °F) Relative vapour density : 4.5 Relative density : 0.8 - 0.88 Solubility(ies) Water solubility : insoluble Partition coefficient: n- : No data available octanol/water Viscosity Viscosity, kinematic : 1.3 - 4.1 cSt (40 °C / 104 °F) SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable at normal ambient temperature and pressure. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Hazardous polymerisation does not occur. tions Conditions to avoid : Extremes of temperature and direct sunlight. Incompatible materials : Reactive with oxidising agents and acids. Hazardous decomposition : May release COx, NOx, SOx, smoke and irritating vapours products when heated to decomposition. SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Eye contact Ingestion Inhalation Skin contact Acute toxicity Product: Acute oral toxicity : Remarks: Based on available data, the classification criteria are not met. Acute inhalation toxicity : Acute toxicity estimate: 1.2 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method Remarks: Harmful if inhaled. Acute dermal toxicity : Remarks: Based on available data, the classification criteria are not met. Components: Kerosine (petroleum), hydrodesulfurized; Kerosine — unspecified: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg, Acute inhalation toxicity : LC50 (Rat): > 5.2 mg/l Exposure time: 4 hrs Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg, Kerosine (petroleum); Straight run kerosine: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg, Acute inhalation toxicity : LC50 (Rat): > 5 mg/l Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg, Fuels, diesel; Gasoil — unspecified: Acute oral toxicity : LD50 (Rat): 7,500 mg/kg, Acute inhalation toxicity : LC50 (Rat): 4.1 mg/l Exposure time: 4 h Test atmosphere: vapour Acute dermal toxicity : LD50 (Mouse): 24,500 mg/kg, Skin corrosion/irritation Product: Remarks: Causes skin irritation. Serious eye damage/eye irritation Product: Remarks: Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Product: Remarks: Based on available data, the classification criteria are not met. Germ cell mutagenicity Product: Germ cell mutagenicity- : Based on available data, the classification criteria are not Assessment met. Carcinogenicity Product: Carcinogenicity - As- : Suspected of causing cancer. sessment Reproductive toxicity Product: Reproductive toxicity - : Based on available data, the classification criteria are not Assessment met. STOT - single exposure Product: Target Organs: Central nervous system Remarks: May cause drowsiness or dizziness. STOT - repeated exposure Product: Target Organs: Liver, thymus, Bone Remarks: May cause damage to organs through prolonged or repeated exposure. No data available Aspiration toxicity Product: May be fatal if swallowed and enters airways. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: No data available Toxicity to daphnia and other : aquatic invertebrates Remarks: No data available Toxicity to algae : Remarks: No data available Toxicity to bacteria : Remarks: No data available Persistence and degradability Product: Biodegradability : Remarks: No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non-recyclable solutions to a licensed dis- posal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of as hazardous waste in compliance with local and national regulations. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR UN/ID No. : UN 1202 Proper shipping name : Diesel fuel Class : 3 Packing group : III Labels : Class 3 - Flammable Liquid Packing instruction (cargo : 366 aircraft) IMDG-Code UN number : UN 1202 Proper shipping name : DIESEL FUEL Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-E Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code National Regulations TDG UN number : UN 1202 Proper shipping name : DIESEL FUEL Class : 3 Packing group : III Labels : 3 ERG Code : 128 Marine pollutant : no SECTION 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the Hazardous Products Reg- ulations (HPR) and the SDS contains all of the information required by the HPR. The components of this product are reported in the following inventories: DSL On the inventory, or in compliance with the inventory SECTION 16. OTHER INFORMATION For Copy of SDS : Internet: www.petro-canada.ca/msds Canada-wide: telephone: 1-800-668-0220; fax: 1-800-837- 1228 For Product Safety Information: 1 905-804-4752 Prepared by : Product Safety: +1 905-804-4752 Revision Date : 2020/10/06 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.