PetraFlex 900 - PART A

Petra Polymers

Revision date : 2015-05-06

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GHS07
Health risk rating 4
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

4098-71-9

Name of the chemical

3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate

Concentration

N/A

General Information

Revision date

2015-05-06

Product name

PetraFlex 900 - PART A

CAS No.

4098-71-9

1.2.1 Relevant identified uses

Chemical intermediate for polyurethane

Emergency telephone

CHEM-TEL 1-800-255-3924

Icons in SDS

Company Information

company name

Petra Polymers

GHS Information

Signal word

Warning

Section 2

2.1 Classification of the substance or mixture

Acute Oral Toxicity Category 4 Acute Dermal Toxicity Category 4 Acute Vapors Toxicity Category 5 Skin Irritation Category 2 Eye Irritation Category 2 Skin Sensitizer Category 1 Respiratory Sensitizer Category 1 TOST: Single Exposure Category 2 Aspiration Toxicity Category 2 NFPA ratings (scale 0 – 4): HEALTH 3 FIRE 1 REACTIVITY 1 SPECIAL - NFPA HAZARD RATING: 4= EXTREME 2= MODERATE 0= INSIGNIFICANT 3= HIGH 1= SLIGHT

Signal word

Warning PHYSICAL APPEARANCE: Clear to slight yellow liquid

Hazard statements

IMMEDIATE CONCERNS: Toxic gases/fumes may be given off during burning or thermal decomposition. Closed container may forcibly rupture under extreme heat or when contents have been contaminated with water. Use cold water to spray to cool fire-exposed containers to minimize the risk of rupture. Causes respiratory tract irritation. May cause allergic respiratory reaction. Harmful if inhaled. Respiratory sensitizer. Lung damage and respiratory sensitization may be permanent. Causes skin irritation. May cause allergic skin reaction. Skin sensitizer. Animal tests indicate that skin contact alone may lead to allergic respiratory reaction. Causes eye irritation. May cause lung damage.

Potential health effects

EYES: Causes irritation with symptoms of reddening, tearing, stinging, and swelling. May cause temporary corneal injury. Vapor or aerosol may cause irritation with symptoms of burning and tearing. Prolonged vapor contact may cause conjunctivitis. SKIN: Causes irritation with symptoms of reddening, itching, and swelling. Persons previously sensitized can experience allergic skin reaction with symptoms of reddening, itching, swelling, and rash. Cured material is difficult to remove. Potent skin sensitizer. Once sensitized, an individual may react to direct skin contact or even to airborne levels below the TLV with reddening, swelling, rash and in severe cases blistering and hives. These symptoms may be immediate or delayed several hours. INGESTION: May cause irritation; Symptoms may include abdominal pain, nausea, vomiting, and diarrhea. INHALATION: Dissocynate or polyisocyanate vapors or mist at concentrations above the exposure limits or guidelines can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, lungs) with symptoms of running nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing difficulty). Persons with a preexisting, onspecific bronchial hyperreactivity can respond to concentrations below the exposure limits or guidelines with similar symptoms as well as asthma attack or asthma-like symptoms. Exposure well above the exposure limits or guidelines may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in lungs). Chemicals or hypersensitivity pneumonitis, with flu-like symptoms (e.g. fever, chills), has also been reported. These symptoms can be delayed up to several hours after exposure. These effects are usually reversible. SIGNS AND SYMPTOMS OF OVEREXPOSURE CARCINOGENICITY: This product does not contain any ingredients designated by NTP, LARC, ACGIH, or OSHA as probable or suspected human carcinogens. COMMENTS The criteria for listing components in the composition section are as follows Carcinogens are listed when present at 0.1% or greater; components which are otherwise hazardous according to OSHA are listed when present at 1.0% or greater; nonhazardous components are not listed. This is not intended to be complete compositional disclosure. Refer to section 15 for applicable states right to know and other regulatory information.

Precautionary statements

Do not breathe dust/fume/gas/mist/vapors/spray. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. IF SWALLOWED: Get immediate medical advice/attention. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention.

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