Dainty & Heaps 80% Alcohol Hand Sanitiser

Hazard statements (CLP)

H225, H319, H336

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture

Hazard pictograms

GHS02 GHS07

Signal word

Danger

Hazard statements

H225: Highly flammable liquid and vapour. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness.

Precautionary statements

P102: Keep out of reach of children. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P264: Wash hands and exposed skin thoroughly after handling. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice/attention P370+P378 In case of fire Use water spray, dry powder or carbon dioxide to extinguish. P501: Dispose of contents in accordance with local, state or national legislation.

2.3 Other hazards

None known.

Additional information

For full text of H/P Statements see section 16.

2.1 Classification of the substance or mixture

Regulation (EC) No. 1272/2008 (CLP) Flam. Liq. 2 :Highly flammable liquid and vapour. Eye Irrit. 2 :Causes serious eye irritation. STOT SE 3 :May cause drowsiness or dizziness. 2.2 Label elements According to Regulation (EC) No. 1272/2008 (CLP) Product Name Dainty & Heaps Hand Sanitizer Hazard Pictogram(s) GHS02 GHS07 Signal Word(s) Danger Hazard Statement(s) H225: Highly flammable liquid and vapour. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. Precautionary Statement(s) P102: Keep out of reach of children. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P264: Wash hands and exposed skin thoroughly after handling. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P370+P378: In case of fire: Use water spray, dry powder or carbon dioxide to extinguish. P501: Dispose of contents in accordance with local, state or national legislation. 2.3 Other hazards None known. 2.4 Additional Information For full text of H/P Statements see section 16. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Not applicable. 3.2 Mixtures HAZARDOUS CAS No. EC No. / REACH %W/W Hazard Statement(s) Hazard INGREDIENT(S) Registration No. Pictogram(s) ethanol ethyl alcohol 64-17-5 200-578-6 80 Flam. Liq. 2 H225 GHS02 glycerol 56-81-5 200-289-5 >1% Not classified None hydrogen peroxide 7722-84-1 231-765-0 0.125 Ox. Liq. 1 H271 GHS03 solution ... % Acute Tox. 4 H302 GHS05 Skin Corr. 1A H314 GHS07 Acute Tox. 4 H332 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Skin Contact Take off immediately all contaminated clothing. Rinse skin with water. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Treat symptomatically. 4.2 Most important symptoms and effects, both acute and delayed May cause irritation. 4.3 Indication of any immediate medical attention and special treatment needed Call a POISON CENTER/doctor if you feel unwell. Treat symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable Extinguishing media Use water spray, dry powder or carbon dioxide to extinguish. Unsuitable extinguishing media Water jet spray 5.2 Special hazards arising from the substance or mixture Highly flammable liquid and vapour. 5.3 Advice for firefighters Fire fighters should wear complete protective clothing including self-contained breathing apparatus. If it is safe to do so, containers should be removed from fire area because they are likely to rupture under fire conditions. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Use non-sparking ventilation systems, approved explosion-proof equipment, and intrinsically safe electrical systems. Wear suitable protective clothing and gloves. 6.2 Environmental precautions Do not allow to enter drains, sewers or watercourses. 6.3 Methods and material for containment and cleaning up Adsorb spillages onto sand, earth or any suitable adsorbent material. Transfer to a container for disposal. Containers must not be punctured or destroyed by burning, even when empty. 6.4 Reference to other sections See Also Section 8, 13. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting/equipment. Use non-sparking tools. Take action to prevent static discharges. Wear protective gloves/protective clothing/eye protection/face protection. 7.2 Conditions for safe storage, including any incompatibilities Store in a well-ventilated place. Keep cool. Storage temperature Ambient. Storage life Stable under normal conditions. Incompatible materials None known. 7.3 Specific end use(s) Consumer use Cleaning/washing agents and additives SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Occupational Exposure Limits Occupational Exposure Limits SUBSTANCE. CAS No. LTEL (8 hr TWA ppm) LTEL (8 hr TWA mg/m³) STEL (ppm) STEL (mg/m³) Note Glycerol, mist 56-81-5 10 Ethanol 64-17-5 1000 1920 Ethanol 64-17-5 1000 1920 Comp, Hydrogen peroxide 7722-84-1 1 1.4 2 2.8 Region Source EU EU Occupational Exposure Limits United Kingdom UK Workplace Exposure Limits EH40/2005 (Fourth edition, published 2020) Remark Notes 8.2 Exposure controls 8.2.1. Appropriate engineering controls Use non-sparking ventilation systems, approved explosion-proof equipment, and intrinsically safe electrical systems. Ensure adequate ventilation. 8.2.2. Personal protection equipment Eye Protection Wear eye protection with side protection (EN166). Skin protection Not normally required. Respiratory protection Normally no personal respiratory protection is necessary. Thermal hazards None known. 8.2.3. Environmental Exposure Controls Do not allow to enter drains, sewers or watercourses. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Liquid. Colour : translucent Colourless Odour Characteristic Solvent odour. Odour threshold Not known. pH Not known. Melting point/freezing point Not known. Initial boiling point and boiling range Not known. Flash Point 19 Deg C° Evaporation rate Not known. Flammability (solid, gas) Not known. Upper/lower flammability or explosive Not known. limits Vapour pressure Not known. Vapour density Not known. Density (g/ml) Not known. Relative density Not known. Solubility(ies) Solubility (Water) : Not known. Solubility (Other) : Not known. Partition coefficient: n-octanol/water Not known. Auto-ignition temperature Not known. Decomposition Temperature (°C) Not known. Viscosity 2.5cP "Runny" liquid Explosive properties Not known. Oxidising properties Not known. 9.2 Other information None. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity None anticipated. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known if used for its intended purpose. 10.4 Conditions to avoid Avoid friction, sparks, or other means of ignition. 10.5 Incompatible materials Not known. 10.6 Hazardous decomposition products No hazardous decomposition products known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity - Ingestion Not classified. Calculated acute toxicity estimate (ATE) Calc ATE - 400000.00000 Acute toxicity - Skin Contact Not classified. Acute toxicity - Inhalation Not classified. Calculated acute toxicity estimate (ATE) Calc ATE - 8800.00000 Skin corrosion/irritation Not classified. Serious eye damage/irritation Calculation method : Causes serious eye irritation Skin sensitization data Not classified. Respiratory sensitization data Not classified. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. Reproductive toxicity Not classified. Lactation Not classified. STOT - single exposure Calculation method : May cause drowsiness or dizziness. Calculation method : May cause drowsiness or dizziness. STOT - repeated exposure Not classified. Aspiration hazard Not classified. 11.2 Other information Not known. SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity - Aquatic invertebrates Low toxicity to invertebrates. Toxicity - Fish Low toxicity to fish. Toxicity - Algae Low toxicity to algae. Toxicity - Sediment Compartment Not classified. Toxicity - Terrestrial Compartment Not classified. 12.2 Persistence and Degradation Not known. 12.3 Bioaccumulative potential Bioaccumulation is unlikely. 12.4 Mobility in soil The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces Will likely be mobile in the environment due to its volatility. Disperses rapidly in air 12.5 Results of PBT and vPvB assessment Not known. 12.6 Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Dispose of contents in accordance with local, state or national legislation. Recycle only completely emptied packaging. Containers must not be punctured or destroyed by burning, even when empty. Do not allow to enter drains, sewers or watercourses. Do NOT landfill. Normal disposal is via incineration operated by an accredited disposal contractor. Dispose at suitable refuse site. 13.2 Additional Information Disposal should be in accordance with local, state or national legislation. RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste: D001 (Ignitable) UK Environment agency – Waste classification HP 3 – Flammable liquid class 2. H225. SECTION 14: TRANSPORT INFORMATION 14.1 UN number UN No. 1170 14.2 UN proper shipping name UN proper shipping name ETHANOL (ETHYL ALCOHOL) 14.3 Transport hazard class(es) ADR/RID ADR/RID Class 3 ADR Classification Code F1 Special Provisions 144 601 Limited Quantities 1 L Excepted Quantities E2 Emergency Action Code •2YE Mixed Packing Instructions for P001 IBC02 R001 Packages Special Packing Provisions for Packages Mixed Packing Instructions for MP19 Packages Packing Instructions for Portable Tanks T4 Special Provisions for Portable Tanks TP1 Tank Code for Tanks LGBF Special Provisions for Tanks Vehicle for Tank Carriage FL ADR Transport Category 2 Tunnel Restriction Code D/E Special Provisions for Carriage - Packages Special Provisions for Carriage - Bulk Special Provisions for Carriage - Loading, Unloading and Handling Special Provisions for Carriage - S2 S20 Operation ADR HIN 33 IMDG IMDG Class 3 Special Provisions 144 601 Limited Quantities 1 L Excepted Quantities E2 Mixed Packing Instructions for P001 IBC02 R001 Packages Special Packing Provisions for Packages Packing Instructions for Portable Tanks T4 Special Provisions for Portable Tanks TP1 IMDG EMS F-E, S-D Stowage and Handling Category A Segregation Marine Pollutant ICAO/IATA IATA Proper Shipping Name ETHANOL Excepted Quantities E2 Passenger and Cargo Aircraft Limited Y341 Quantities Packing Instructions Passenger and Cargo Aircraft Limited 1L Quantities Max net Qty Passenger and Cargo Aircraft Packing 353 Instructions Passenger and Cargo Aircraft Max net 5L Qty Cargo Aircraft Packing Instructions 364 Cargo Aircraft Max net Qty 60L Special Provisions A3, A58, A180 Emergency Response Guidebook (ERG) 3L Code Labels 3 14.4 Packing group Packing group II 14.5 Environmental hazards Environmental hazards Not classified as a Marine Pollutant. 14.6 Special precautions for user Special precautions for user Not known. 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code No information available SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture European Regulations - Authorisations and/or Restrictions On Use Candidate List of Substances of Very Not listed High Concern for Authorisation REACH: ANNEX XIV list of substances Not listed subject to authorisation REACH: Annex XVII Restrictions on the ethanol ethyl alcohol (64-17-5), hydrogen peroxide solution ... % (7722-84-1) manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Community Rolling Action Plan Not listed (CoRAP) Regulation (EC) N° 850/2004 of the Not listed European Parliament and of the Council on persistent organic pollutants Regulation (EC) N° 1005/2009 on Not listed substances that deplete the ozone layer Regulation (EU) N° 649/2012 of the Not listed European Parliament and of the Council concerning the export and import of hazardous chemicals National regulations Other Germany water classification: WGK1 France INRS Tables of occupational diseases – RG84 UK – Control of substances Hazardous to health regulations. 15.2 Chemical Safety Assessment A REACH chemical safety assessment has not been carried out. CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: LEGEND Hazard Pictogram(s) GHS02 GHS03: GHS: Flame over circle GHS05: GHS: Corrosion GHS07: GHS: Exclamation mark Hazard classification Flam. Liq. 2 : Flammable liquid, Category 2 Ox. Liq. 1 : Oxidising liquid, Category 1 Acute Tox. 4 : Acute toxicity, Category 4 Skin Corr. 1A : Skin corrosion/irritation, Category 1A Acute Tox. 4 : Acute toxicity, Category 4 Hazard Statement(s) H225: Highly flammable liquid and vapour. H271: May cause fire or explosion; strong oxidiser. H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H332: Harmful if inhaled. Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P280: Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P370+P378: In case of fire: Use water spray, dry powder or carbon dioxide to extinguish. P403+P235: Store in a well-ventilated place. Keep cool. P501: Dispose of contents in accordance with local, state or national legislation. Acronyms ADN : European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR : European Agreement concerning the International Carriage of Dangerous Goods by Road CAS : Chemical Abstracts Service CLP : Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures DNEL : Derived No Effect Level EC : European Community EINECS : European Inventory of Existing Commercial Chemical Substances IATA : International Air Transport Association IBC : Intermediate Bulk Container ICAO : International Civil Aviation Organization IMDG : International Maritime Dangerous Goods LTEL : Long term exposure limit PBT : Persistent, Bioaccumulative and Toxic PNEC : Predicted No Effect Concentration REACH : Registration, Evaluation, Authorisation and Restriction of Chemicals RID : Regulations concerning the International Carriage of Dangerous Goods by Rail STEL : Short term exposure limit STOT : Specific Target Organ Toxicity UN : United Nations vPvB : very Persistent and very Bioaccumulative Disclaimers Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. PERFUME ADDICT (UK) LTD gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. PERFUME ADDICT (UK) LTD accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed.