Substances subject to the Stockholm Convention

Hazard statements (CLP)

H226, H304, H312, H315, H317, H319, H332, H334, H335, H336, H373, H412

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Appearance It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Degradability: information not available No chemical safety assessment has been processed for the mixture and the substances it contains. GENERAL INFORMATION VLEP ITA 221 50 Not available 442 100 SKIN 4. Regulation (EU) 2015/830 of the European Parliament Colour toxicological effects of exposure to the product. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for OEL EU 221 50 Not available 442 100 SKIN

2.1 Classification of the substance or mixture

5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Information not relevant Odour N-BUTYL ACETATE IMDG: TLV-ACGIH Class: 3 434 Label: 3 100 Not available 651 150 1272/2008 (CLP) 23 ≤ T ≤ 60 °C SECTION 6. Accidental release measures Hazard classification and indication: - The Merck Index. - 10th Edition Evaporation Rate ACUTE TOXICITY Solubility in water Hazard classification and indication: Not available > 100 mg/l - Handling Chemical Safety STOT RE 2 Flammable liquid, category 3 Specific target organ toxicity - repeated exposure, category 2 H226 POLY (HEXAMETHYLENE DIISOCYANATE) Flammability of solids and gases Not available N-BUTYL ACETATE Flammable liquid and vapour. 6.1. Personal precautions, protective equipment and emergency procedures 14.4. Packing group - INRS - Fiche Toxicologique (toxicological sheet) Eye Irrit. 2 Acute toxicity, category 4 Eye irritation, category 2 12.3. Bioaccumulative potential CAS Threshold Limit Value Lower inflammability limit LC50 (Inhalation - vapours) of the mixture: 28182-81-2 40 ≤ x < 55 Acute Tox. 4 H332, Resp. Sens. 1 H334, Skin Sens. 1 H317 1,1 % (V/V) 11,58 mg/l H332 Harmful if inhaled. Block the leakage if there is no hazard. - Patty - Industrial Hygiene and Toxicology Skin Irrit. 2 Skin irritation, category 2 EC Upper inflammability limit LC50 (Inhalation - mists / powders) of the mixture: Specific target organ toxicity - repeated exposure, Type Specific target organ toxicity - repeated exposure, 500-060-2 Country TWA/8h 7,5 STEL/15min % (V/V) Not classified (no significant component) H373 May cause damage to organs through prolonged or Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent ADR / RID, IMDG, IATA: - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition STOT SE 3 III Specific target organ toxicity - single exposure, category 3 repeated exposure. INDEX Lower explosive limit LD50 (Oral) of the mixture: POLY (HEXAMETHYLENE DIISOCYANATE) category 2 mg/m3 ppm Not available mg/m3 Not classified (no significant component) ppm any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency - ECHA website Resp. Sens. 1 Respiratory sensitization, category 1 Reg. no. Upper explosive limit LD50 (Dermal) of the mixture: Partition coefficient: n-octanol/water Eye irritation, category 2 MAK Eye irritation, category 2 01-2119485796-17-xxxx DEU 480 100 Not available 5,54 >2000 mg/kg 960 H319 200 Causes serious eye irritation.

Further information

health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 11.1. Information on toxicological effects Predicted no-effect concentration - PNEC Odour threshold Solubility in water Not available 1000 - 10000 mg/l contaminated water used for extinction and the remains of the fire according to applicable regulations. 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 3.2. Mixtures The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments pH The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments Normal value in fresh water Not available 0,25 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Text of hazard (H) indications mentioned in section 2-3 of the sheet: 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament mg/l and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and Melting point / freezing point N-BUTYL ACETATE SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and Normal value in marine water Not available 0,25 Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament mg/l subsequent amendments. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. IMDG: Reg. no. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 01-2119485493-29-xxxx mg/m3 EMS: F-E, S-E ppm mg/m3 Limited Quantities: 5 L ppm IATA: H334 Cargo: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Maximum quantity: 220 L Packaging instructions: 366 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Total solids (250°C / 482°F) XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) POLY (HEXAMETHYLENE DIISOCYANATE) OEL H317 EU May cause an allergic skin reaction. 100 20 0,17 % 6.4. Reference to other sections

Contains

Initial boiling point In humans the substance's vapours cause irritation to the eues and nose. In the event of repeated exposure, there is skin irritation, dermatosis Rapidly degradable IATA: subsequent amendments. Normal value for marine water sediment Class: 3 Label: 3 124 °C 14,33 self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament Flam. Liq. 3 mg/kg Flammable liquid, category 3 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Boiling range (with driness and flaking of the skin) and keratitis. Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Normal value for the terrestrial compartment Not available 2,41 Acute Tox. 4 mg/kg Acute toxicity, category 4 Identification Flash point XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) Asp. Tox. 1 x = Conc. % Aspiration hazard, category 1

Environmental hazards

procedures. Skin Sens. 1 Skin sensitization, category 1 XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) Vapour pressure BCF Skin irritation, category 2 VLA Skin irritation, category 2 ESP 724 150 10,7 367,7 mbar 965 H315 200 Causes skin irritation. Aquatic Chronic 2 Hazardous to the aquatic environment, chronic toxicity, category 2 CAS Vapour density N-BUTYL ACETATE Specific target organ toxicity - single exposure, category 3 VLEP Specific target organ toxicity - single exposure, category 3 FRA 35 ≤ x < 40 710 150 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, Not available 940 H335 200 May cause respiratory irritation. Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. ADR / RID: Note for users: Aquatic Chronic 3 NO Hazardous to the aquatic environment, chronic toxicity, category 3 Relative density LD50 (Oral) N-BUTYL ACETATE Respiratory sensitization, category 1 WEL Respiratory sensitization, category 1 GBR 724 150 STOT RE 2 H373, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Note C 0,97 > 6400 mg/kg Rat 966 H334 200 May cause allergy or asthma symptoms or breathing IMDG: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the H226 NO Flammable liquid and vapour. difficulties if inhaled. EC Solubility LD50 (Dermal) Partition coefficient: n-octanol/water AK H312 905-562-9 HUN Harmful in contact with skin. 950 Not available 2,3 > 5000 mg/kg Rabbit 950 6.2. Environmental precautions suitability and thoroughness of provided information according to each specific use of the product. INDEX Partition coefficient: n-octanol/water LC50 (Inhalation) BCF IATA: Skin sensitization, category 1 TLV-ACGIH NO 50 Not available 15,3 21,1 mg/l/4h Rat H317 150 May cause an allergic skin reaction. The product must not penetrate into the sewer system or come into contact with surface water or ground water. This document must not be regarded as a guarantee on any specific product property. H332 Hazardous to the aquatic environment, chronic toxicity, Harmful if inhaled. Reg. no. Auto-ignition temperature 01-2119555267-33 370 °C H412 Harmful to aquatic life with long lasting effects. 14.6. Special precautions for user The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health H304 May be fatal if swallowed and enters airways. N-BUTYL ACETATE Decomposition temperature SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) category 3 Not available 6.3. Methods and material for containment and cleaning up and safety laws and regulations. The producer is relieved from any liability arising from improper uses. H373 May cause damage to organs through prolonged or repeated exposure. CAS Viscosity LD50 (Oral) BCF H319 123-86-4 12 ≤ x < 15 Causes serious eye irritation. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 >20,5 mm2/sec (40°C) 25,9 > 8 mg/kg ratto

2.2 Label elements

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of ADR / RID: Provide appointed staff with adequate training on how to use chemical products. EC Threshold Limit Value Explosive properties LD50 (Dermal) 204-658-1 HIN - Kemler: 30 Not available > 3160 mg/kg ratto Limited Quantities: 5 L Tunnel restriction code: (D/E) the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. H315

Special Provisions

640E Causes skin irritation. 12.4. Mobility in soil INDEX Oxidising properties LC50 (Inhalation) Type H335 607-025-00-1 Country May cause respiratory irritation. TWA/8h Not available STEL/15min > 6193 mg/l/4h ratto

Hazard pictograms

CAS VOC (Directive 2010/75/EC) : LD50 (Oral) Partition coefficient: soil/water 64742-95-6 3 ≤ x < 5 Pass.: Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, 19,83 % - 192,30 7,3 3523 mg/kg Rat Maximum quantity: 60 L g/litre Packaging instructions: 355 Any information on personal protection and disposal is given in sections 8 and 13. H336 Special Instructions: May cause drowsiness or dizziness. A3, A72, A192 Legend: VOC (volatile carbon) : LD50 (Dermal) H411 Toxic to aquatic life with long lasting effects. Aquatic Chronic 2 H411, Note P 13,37 % - 129,74 12126 mg/kg Rabbit g/litre EC (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. LC50 (Inhalation) N-BUTYL ACETATE H412 918-668-5 Harmful to aquatic life with long lasting effects. 27,124 mg/l/4h Rat 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 10. Stability and reactivity Partition coefficient: soil/water INDEX VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. < 3