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Hazard statements (CLP)

H225, H226, H302, H314, H317, H319, H332, H335, H336, H370, H372, H400, H410, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008 SECTION 8. Exposure controls/personal protection Total solids (250°C / 482°F)

Contains

using the criteria specified in the applicable regulation for classification IMDG: SUITABLE EXTINGUISHING EQUIPMENT H370 EMS: F-E, S-E Causes damage to organs. 0,77 % Limited Quantities: 5 L 12.4. Mobility in soil (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. dibutyltin diluated VOC (Directive 2004/42/EC) : It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the IATA: Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can H302 Cargo: Harmful if swallowed. 58,23 % - 570,62 Maximum quantity: 60 L g/litre Packaging instructions: 364 VOC (volatile carbon) : toxicological effects of exposure to the product. H332 Pass.: Harmful if inhaled. 37,12 % - 363,74 Maximum quantity: 5 L g/litre Packaging instructions: 353 8.1. Control parameters 8.2. Exposure controls be used to disperse flammable vapours and protect those trying to stem the leak. Benzotriazol derivatives The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the UNSUITABLE EXTINGUISHING EQUIPMENT H372 Special Instructions: Causes damage to organs through prolonged or repeated exposure. A3, A72, A192 11.1. Information on toxicological effects The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments 4-METHYLPENTAN-2-ONE suitability and thoroughness of provided information according to each specific use of the product. Identification The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments H314 x = Conc. % Causes severe skin burns and eye damage. dibutyltin diluated Sebacate Bis (1,2,2,6,6-pentamethyl-4-piperidyl) Benzotriazol derivatives May produce an allergic reaction. N-BUTYL ACETATE METHYL ETHYL KETONE VOC (Directive 2004/42/EC) : Special finishes. VOC given in g/litre of product in a ready-to-use condition : 570,00 Limit value: 840,00

2.1 Classification of the substance or mixture

Sebacate Bis (1,2,2,6,6-pentamethyl-4-piperidyl) Note for users: 1272/2008 (CLP) SECTION 10. Stability and reactivity Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent Regulatory References: As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is GERM CELL MUTAGENICITY Partition coefficient: soil/water This document must not be regarded as a guarantee on any specific product property. 2,008 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and H319 Causes serious eye irritation. explosions. well aired through effective local aspiration. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health subsequent amendments. N-BUTYL ACETATE Metabolism, toxicokinetics, mechanism of action and other information subsequent amendments. H335 May cause respiratory irritation. 10.1. Reactivity DEU When choosing personal protective equipment, ask your chemical substance supplier for advice. Does not meet the classification criteria for this hazard class N-BUTYL ACETATE and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Deutschland MAK-und BAT-Werte-Liste 2012 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. CAS Information not relevant Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. H317 123-86-4 40 ≤ x < 60 May cause an allergic skin reaction. Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 5.2. Special hazards arising from the substance or mixture ESP Personal protective equipment must be CE marked, showing that it complies with applicable standards. Partition coefficient: soil/water Provide appointed staff with adequate training on how to use chemical products. España INSHT - Límites de exposición profesional para agentes químicos en España 2015 < 3 EC Information not available FRA There are no particular risks of reaction with other substances in normal conditions of use. H336 204-658-1 France May cause drowsiness or dizziness. JORF n°0109 du 10 mai 2012 page 8773 texte n° 102 Hazard classification and indication: Provide an emergency shower with face and eye wash station. CARCINOGENICITY INDEX Hazard classification and indication: H400 607-025-00-1 Very toxic to aquatic life.

Results of PBT and vPvB assessment

SECTION 15. Regulatory information HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE GBR HAND PROTECTION United Kingdom EH40/2005 Workplace exposure limits Reg. no. Information on likely routes of exposure Flammable liquid, category 2 H410 Flammable liquid, category 2 01-2119485493-29-xxxx Very toxic to aquatic life with long lasting effects. H225 Highly flammable liquid and vapour. Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. HUN N-BUTYL ACETATE Protect hands with category III work gloves (see standard EN 374). Does not meet the classification criteria for this hazard class Magyarország 50/2011. (XII. 22.) NGM rendelet a munkahelyek kémiai biztonságáról METHYL ETHYL KETONE Eye irritation, category 2 H411 Eye irritation, category 2 Toxic to aquatic life with long lasting effects. H319 Causes serious eye irritation. ITA The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. Decomposes on contact with: water. Italia Decreto Legislativo 9 Aprile 2008, n.81 CAS Specific target organ toxicity - single exposure, category 3 H412 Specific target organ toxicity - single exposure, category 3 N-BUTYL ACETATE 78-93-3 7,5 ≤ x < 10 Harmful to aquatic life with long lasting effects. Flam. Liq. 2 H225, Eye Irrit. 2 H319, STOT SE 3 H336, EUH066 H336 May cause drowsiness or dizziness. 5.3. Advice for firefighters 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture NLD The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on REPRODUCTIVE TOXICITY Nederland Databank of the social and Economic Concil of Netherlands (SER) Values, AF 2011:18 EC Hazardous to the aquatic environment, chronic toxicity, EUH066 Hazardous to the aquatic environment, chronic toxicity, WORKERS: inhalation; contact with the skin. 201-159-0 Repeated exposure may cause skin dryness or cracking. H412 Harmful to aquatic life with long lasting effects.

Other hazards

POL the duration and type of use. METHYL ETHYL KETONE Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 16 grudnia 2011r INDEX category 3 606-002-00-3 GENERAL INFORMATION PRT Seveso Category - Directive 2012/18/EC: SKIN PROTECTION Does not meet the classification criteria for this hazard class Reacts with: light metals,strong oxidants.Attacks various types of plastic materials.Decomposes under the effect of heat. Portugal Ministério da Economia e do Emprego Consolida as prescrições mínimas em matéria de protecção P5c Reg. no. Delayed and immediate effects as well as chronic effects from short and long-term exposure Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for 01-2119457290-43 dos trabalhadores contra os riscos para a segurança e a saúde devido à exposição a agentes

2.2 Label elements

Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Information not available 4-METHYLPENTAN-2-ONE LEGEND: health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of 4-METHYLPENTAN-2-ONE Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 with soap and water after removing protective clothing. STOT - SINGLE EXPOSURE químicos no trabalho - Diaro da Republica I 26; 2012-02-06 CAS - ADR: European Agreement concerning the carriage of Dangerous goods by Road N-BUTYL ACETATE 108-10-1 5 ≤ x < 7,5 Flam. Liq. 2 H225, Acute Tox. 4 H332, Eye Irrit. 2 H319, STOT SE 3 H335, EUH066 contaminated water used for extinction and the remains of the fire according to applicable regulations. EU Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. Product Reacts violently with: light metals.Attacks various types of plastic materials. OEL EU Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. EC - CAS NUMBER: Chemical Abstract Service Number Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. In humans, the substance's vapours cause irritation of the eyes and nose. In the event of repeated exposure, skin irritation, dermatitis 203-550-1 SECTION 13. Disposal considerations SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS EYE PROTECTION May cause drowsiness or dizziness Point 3 - 40 Directive 2000/39/EC; Directive 91/322/EEC. 10.2. Chemical stability INDEX - CE50: Effective concentration (required to induce a 50% effect) Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with (dryness and cracking of the skin) and keratitis appear. 606-004-00-4 TLV-ACGIH ACGIH 2016 13.1. Waste treatment methods

Hazard pictograms

Wear airtight protective goggles (see standard EN 166). Reg. no. - CE NUMBER: Identifier in ESIS (European archive of existing substances) 01-2119473980-30 self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). Substances in Candidate List (Art. 59 REACH) RESPIRATORY PROTECTION STOT - REPEATED EXPOSURE Benzotriazol derivatives Interactive effects - CLP: EC Regulation 1272/2008 The product is stable in normal conditions of use and storage. On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. N-BUTYL ACETATE If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a type CAS Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product - DNEL: Derived No Effect Level 0 ≤ x < 1 Skin Sens. 1 H317, Aquatic Chronic 2 H411 Threshold Limit Value AX filter, whose limit of use will be defined by the manufacturer (see standard EN 14387). In the presence of gases or vapours of various Does not meet the classification criteria for this hazard class 10.3. Possibility of hazardous reactions SECTION 6. Accidental release measures EC should be evaluated according to applicable regulations. - EmS: Emergency Schedule Substances subject to authorisarion (Annex XIV REACH) Type N-BUTYL ACETATE 400-830-7 Country TWA/8h STEL/15min kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. INDEX Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. - GHS: Globally Harmonized System of classification and labeling of chemicals A case of acute intoxication been reported involving a 33 year old worker while cleaning a tank with a preparation containing xylenes, 607-176-00-3 6.1. Personal precautions, protective equipment and emergency procedures Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the

Aspiration hazard

None mg/m3 ppm mg/m3 ppm Reg. no. Waste transportation may be subject to ADR restrictions. - IATA DGR: International Air Transport Association Dangerous Goods Regulation The vapours may also form explosive mixtures with the air. MAK butyl acetate and ethylene glycol acetate. The person had irritation of the conjunctiva and upper respiratory tract, drowsiness and 01-0000015075-76 DEU 480 100 960 200 threshold values considered. The protection provided by masks is in any case limited. Sebacate Bis (1,2,2,6,6-pentamethyl-4-piperidyl) CONTAMINATED PACKAGING - IC50: Immobilization Concentration 50% Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: VLA motor coordination disorders, which disappeared within 5 hours. The symptoms are attributed to poisoning by mixed xylenes and butyl ESP 724 150 965 200 Block the leakage if there is no hazard. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Does not meet the classification criteria for this hazard class Viscosity: >20,5 mm2/sec (40°C) CAS Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. - IMDG: International Maritime Code for dangerous goods acetate, with a possible synergistic effect responsible for the neurological effects. Cases of vacuolar keratitis are reported in workers 41556-26-7 0,1 ≤ x < 0,25 Skin Sens. 1 H317, Aquatic Acute 1 H400 M=1, Aquatic Chronic 1 H410 M=1 N-BUTYL ACETATE None Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing VLEP FRA 710 150 940 200 EC - IMO: International Maritime Organization WEL Risk of explosion on contact with strong oxidising agents.May react dangerously with alkaline hydroxides,potassium tert-butoxide.Forms exposed to a mixture of butyl acetate and isobutanol vapours, but with uncertainty concerning the responsibility of a particular solvent 255-437-1 GBR 724 150 966 200

Signal word

any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. INDEX (INRC, 2011). - INDEX NUMBER: Identifier in Annex VI of CLP Danger

ECOLOGICAL INFORMATION

SECTION 14. Transport information Substances subject to the Rotterdam Convention: procedures. ENVIRONMENTAL EXPOSURE CONTROLS AK explosive mixtures with: air. HUN 950 Reg. no. - LC50: Lethal Concentration 50% None OEL 01-2119491304-40 NLD 150

Hazard statements

The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure ACUTE TOXICITY This product is dangerous for the environment and the aquatic organisms. In the long term, it have negative effects on aquatic environment. - LD50: Lethal dose 50%

UN Number

METHYL ETHYL KETONE Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. compliance with environmental standards. NDS POL Highly flammable liquid and vapour. 200 950 - OEL: Occupational Exposure Level H225 Substances subject to the Stockholm Convention: Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways. TLV-ACGIH May form peroxides with air,light,strong oxidising agents.Risk of explosion on contact with hydrogen peroxide,nitric acid,sulphuric 50 150 12.1. Toxicity LC50 (Inhalation) of the mixture:

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation H319 Causes serious eye irritation. > 20 mg/l 6.2. Environmental precautions ADR / RID, IMDG, IATA: None acid.May react dangerously with oxidising agents,trichloromethane,alkalis.Forms explosive mixtures with air 1263 LD50 (Oral) of the mixture: - PEC: Predicted environmental Concentration H336 May cause drowsiness or dizziness. Not classified (no significant component) LD50 (Dermal) of the mixture: H412 Harmful to aquatic life with long lasting effects. Not classified (no significant component) EPY 9.4.5 - SDS 1004.4 ... / >> EUH066 Repeated exposure may cause skin dryness or cracking. EUH208

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P261 Avoid breathing fumes / vapours. P280 Wear protective gloves / eye protection / face protection. P312 Call a POISON CENTRE or a doctor if you feel unwell. P370+P378 In case of fire: Use carbon dioxide (CO2), extinguishing powder or foam for extinction.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.