of the competent person

Hazard statements (CLP)

H226, H302, H304, H312, H314, H315, H317, H319, H330, H332, H334, H335, H336, H373, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent Flam. Liq. 3 Flammable liquid, category 3 N-BUTYL ACETATE SKIN PROTECTION 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 3.2. Mixtures The vapours may also form explosive mixtures with the air. LD50 (Oral) Solubility in water explosions. Threshold Limit Value Acute Tox. 1 Acute toxicity, category 1 > 100 mg/l 3523 mg/kg Rat

2.1 Classification of the substance or mixture

Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body LD50 (Dermal) IATA: 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament Acute Tox. 4 Class: 3 Acute toxicity, category 4 Label: 3 12126 mg/kg Rabbit with soap and water after removing protective clothing. 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament Type Country TWA/8h STEL/15min 12.3. Bioaccumulative potential 1272/2008 (CLP) Excess pressure may form in containers exposed to fire at a risk of explosion. Do not breathe combustion products. Wear airtight protective goggles (see standard EN 166). VLA ESP 724 150 965 200 subsequent amendments. LD50 (Oral) Partition coefficient: n-octanol/water subsequent amendments. Eye Irrit. 2 Eye irritation, category 2 5,54 > 2000 mg/kg ratto 14.4. Packing group RESPIRATORY PROTECTION - The Merck Index. - 10th Edition VLEP FRA 710 150 940 200 Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. POLY (HEXAMETHYLENE DIISOCYANATE) HEXAMETHYLENE-DI-ISOCYANATE LC50 (Inhalation) BCF Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet. Skin Irrit. 2 Skin irritation, category 2 367,7 4,1 mg/l/4h ratto 5.3. Advice for firefighters If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type - Handling Chemical Safety WEL GBR 724 150 966 200 CAS GENERAL INFORMATION May form explosive mixtures with alcohols,bases.May react violently with alcohols,amines,strong bases,oxidising agents,strong STOT SE 3 AK 28182-81-2 HUN 55 ≤ x < 60 Specific target organ toxicity - single exposure, category 3 950 Acute Tox. 4 H332, Resp. Sens. 1 H334, Skin Sens. 1 H317 950 Hazard classification and indication: A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases ADR / RID, IMDG, IATA: - INRS - Fiche Toxicologique (toxicological sheet) EC SKIN CORROSION / IRRITATION N-BUTYL ACETATE Hazard classification and indication: acids,water. Resp. Sens. 1 500-060-2 III Respiratory sensitization, category 1 Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. - Patty - Industrial Hygiene and Toxicology TLV-ACGIH 50 150 INDEX Does not meet the classification criteria for this hazard class Partition coefficient: n-octanol/water Flammable liquid, category 3 Skin Sens. 1 Flammable liquid, category 3 Skin sensitization, category 1 2,3 H226 Flammable liquid and vapour. health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 1272/2008 (CLP) POLY (HEXAMETHYLENE DIISOCYANATE) CAS 28182-81-2 55 ≤ x < 60 Acute Tox. 4 H332, Resp. Sens. 1 H334, Skin Sens. 1 H317 EC 500-060-2 INDEX Reg. no. 01-2119485796-17-xxxx N-BUTYL ACETATE CAS 123-86-4 25 ≤ x < 30 Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 EC 204-658-1 INDEX 607-025-00-1 Reg. no. 01-2119485493-29-xxxx XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) CAS 5 ≤ x < 10 Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, STOT RE 2 H373, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Note C EC 905-562-9 INDEX Reg. no. 01-2119555267-33 Homopolymer of Isophorondiisocyanate CAS 53880-05-0 5 ≤ x < 10 Acute Tox. 4 H332, STOT SE 3 H335, Skin Sens. 1B H317 EC 500-125-5 INDEX Reg. no. 01-2119980716-25 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM CAS 64742-95-6 1 ≤ x < 2 Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, Aquatic Chronic 2 H411, Note P EC 918-668-5 INDEX Reg. no. 01-2119455851-35 SECTION 3. Composition/information on ingredients ... / >> HEXAMETHYLENE-DI-ISOCYANATE CAS 822-06-0 0,1 ≤ x < 0,25 Acute Tox. 1 H330, Acute Tox. 4 H302, Skin Corr. 1C H314, STOT SE 3 H335, Resp. Sens. 1 H334, Skin Sens. 1 H317, Note 2 EC 212-485-8 INDEX 615-011-00-1 Reg. no. 01-2119457571-37-xxxx The full wording of hazard (H) phrases is given in section 16 of the sheet.

Contains

N-BUTYL ACETATE LC50 (Inhalation) Asp. Tox. 1 Aspiration hazard, category 1 27,124 mg/l/4h Rat 5.2. Special hazards arising from the substance or mixture Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament mg/m3 ppm mg/m3 ppm The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments Risk of explosion on contact with strong oxidising agents.May react dangerously with alkaline hydroxides,potassium tert-butoxide.Forms STOT RE 2 Specific target organ toxicity - repeated exposure, category 2 HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE EYE PROTECTION 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament MAK DEU 480 100 960 200 and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and Identification Homopolymer of Isophorondiisocyanate POLY (HEXAMETHYLENE DIISOCYANATE) and supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and explosive mixtures with: air. Skin Corr. 1C x = Conc. % Skin corrosion, category 1C HEXAMETHYLENE-DI-ISOCYANATE May produce an allergic reaction. POLY (HEXAMETHYLENE DIISOCYANATE) Homopolymer of Isophorondiisocyanate N-BUTYL ACETATE XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) Identification x = Conc. %

Environmental hazards

10.4. Conditions to avoid Reg. no. BCF Acute toxicity, category 4 Skin Sens. 1B Acute toxicity, category 4 01-2119485796-17-xxxx Skin sensitization, category 1B 15,3 H332 Harmful if inhaled. contaminated water used for extinction and the remains of the fire according to applicable regulations. threshold values considered. The protection provided by masks is in any case limited. - ECHA website N-BUTYL ACETATE SERIOUS EYE DAMAGE / IRRITATION Specific target organ toxicity - single exposure, category 3 Aquatic Chronic 2 Specific target organ toxicity - single exposure, category 3 Hazardous to the aquatic environment, chronic toxicity, category 2 H335 May cause respiratory irritation. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an ADR / RID: NO XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) CAS Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. Does not meet the classification criteria for this hazard class HEXAMETHYLENE-DI-ISOCYANATE Respiratory sensitization, category 1 H226 Respiratory sensitization, category 1 123-86-4 25 ≤ x < 30 Flammable liquid and vapour. Flam. Liq. 3 H226, STOT SE 3 H336, EUH066 H334 May cause allergy or asthma symptoms or breathing Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Threshold Limit Value emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing IMDG: NO difficulties if inhaled. EC Partition coefficient: n-octanol/water self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). H330 Type 204-658-1 Country Fatal if inhaled. TWA/8h 3,2 STEL/15min apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. IATA: Note for users: INDEX N-BUTYL ACETATE RESPIRATORY OR SKIN SENSITISATION BCF Skin sensitization, category 1 H302 Skin sensitization, category 1 607-025-00-1 NO Harmful if swallowed. 3,2 H317 May cause an allergic skin reaction. ENVIRONMENTAL EXPOSURE CONTROLS The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the Specific target organ toxicity - single exposure, category 3 mg/m3 ppm mg/m3 ppm H336 May cause drowsiness or dizziness. Reg. no. Sensitising for the skin Avoid exposure to: moisture,sources of heat,naked flames. H312 AGW 01-2119485493-29-xxxx DEU Harmful in contact with skin. 440 100 880 200 SKIN 14.6. Special precautions for user SECTION 6. Accidental release measures The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) suitability and thoroughness of provided information according to each specific use of the product. XYLENE (REACTIVE MIXTURE OF ETHYLBENZENE, m-XYLENE AND p-XYLENE) H332 Harmful if inhaled. compliance with environmental standards. This document must not be regarded as a guarantee on any specific product property. VLA ESP 221 50 442 100 SKIN

2.2 Label elements

CAS HEXAMETHYLENE-DI-ISOCYANATE GERM CELL MUTAGENICITY BCF H304 5 ≤ x < 10 May be fatal if swallowed and enters airways. Flam. Liq. 3 H226, Acute Tox. 4 H312, Acute Tox. 4 H332, Asp. Tox. 1 H304, 25,9 6.1. Personal precautions, protective equipment and emergency procedures ADR / RID: The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health VLEP FRA HIN - Kemler: 30 221 50 442 Limited Quantities: 5 L 100 SKIN Tunnel restriction code: (D/E) Does not meet the classification criteria for this hazard class Avoid exposure to: high temperatures,moisture. H373 WEL GBR May cause damage to organs through prolonged or repeated exposure. 220 50 STOT RE 2 H373, Eye Irrit. 2 H319, Skin Irrit. 2 H315, STOT SE 3 H335, Note C 441 100 12.4. Mobility in soil Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Block the leakage if there is no hazard. and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. EC H314 905-562-9

Special Provisions

640E Causes severe skin burns and eye damage. SECTION 9. Physical and chemical properties Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent IMDG: Provide appointed staff with adequate training on how to use chemical products. VLEP ITA EMS: F-E, S-E 221 50 442 Limited Quantities: 5 L 100 SKIN 10.5. Incompatible materials INDEX CARCINOGENICITY H319 OEL EU Causes serious eye irritation. 221 50 442 100 SKIN 9.1. Information on basic physical and chemical properties

Hazard pictograms

any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency IATA: Reg. no. Does not meet the classification criteria for this hazard class POLY (HEXAMETHYLENE DIISOCYANATE) H315 01-2119555267-33 Cargo: Causes skin irritation. Maximum quantity: 220 L Packaging instructions: 366 procedures. TLV-ACGIH Pass.: 434 100 651 Maximum quantity: 60 L 150 Packaging instructions: 355 Homopolymer of Isophorondiisocyanate Appearance N-BUTYL ACETATE Partition coefficient: soil/water Predicted no-effect concentration - PNEC H335 May cause respiratory irritation. liquid 7,3 CAS Colour REPRODUCTIVE TOXICITY Incompatible with: water,nitrates,strong oxidants,acids,alkalis,zinc. H334 53880-05-0 5 ≤ x < 10 Special Instructions: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Acute Tox. 4 H332, STOT SE 3 H335, Skin Sens. 1B H317 colourless A3, A72, A192 Send away individuals who are not suitably equipped. Eliminate all sources of ignition (cigarettes, flames, sparks, etc.) from the leakage site. Normal value in fresh water 0,25 mg/l EC Odour Does not meet the classification criteria for this hazard class N-BUTYL ACETATE H317 Normal value in marine water 500-125-5 May cause an allergic skin reaction. characteristic 0,25 mg/l 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code INDEX Odour threshold HEXAMETHYLENE-DI-ISOCYANATE Partition coefficient: soil/water H336 May cause drowsiness or dizziness. Not available < 3 6.2. Environmental precautions Normal value for marine water sediment 14,33 mg/kg Reg. no. pH STOT - SINGLE EXPOSURE Incompatible with: alcohols,carboxylic acids,amines,strong bases. H411 Normal value for the terrestrial compartment 01-2119980716-25 Toxic to aquatic life with long lasting effects. Not available 2,41 mg/kg The product must not penetrate into the sewer system or come into contact with surface water or ground water. Information not relevant SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM Melting point / freezing point May cause respiratory irritation SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM EUH066 Repeated exposure may cause skin dryness or cracking. Not available 10.6. Hazardous decomposition products CAS Initial boiling point Partition coefficient: soil/water EUH204 64742-95-6 1 ≤ x < 2 Contains isocyanates. May produce an allergic reaction. Flam. Liq. 3 H226, Asp. Tox. 1 H304, STOT SE 3 H335, STOT SE 3 H336, 124 1,78 °C 6.3. Methods and material for containment and cleaning up Boiling range STOT - REPEATED EXPOSURE SECTION 15. Regulatory information

Signal word

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of Aquatic Chronic 2 H411, Note P Not available Danger

Results of PBT and vPvB assessment

EC Flash point In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. Does not meet the classification criteria for this hazard class 918-668-5 23 ≤ T ≤ 60 °C the container to be used, by checking section 10. Absorb the remainder with inert absorbent material. INDEX Evaporation Rate LEGEND: Not available 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Hazard statements

Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. Reg. no. Flammability of solids and gases HEXAMETHYLENE-DI-ISOCYANATE

Aspiration hazard

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. - ADR: European Agreement concerning the carriage of Dangerous goods by Road 01-2119455851-35 Not available Lower inflammability limit Does not meet the classification criteria for this hazard class Viscosity: >20,5 mm2/sec (40°C) - CAS NUMBER: Chemical Abstract Service Number H226 May develop: nitric oxide,hydrogen cyanide. Flammable liquid and vapour. 1,1 % (V/V) Upper inflammability limit H332 Harmful if inhaled. 7,5 % (V/V) EPY 9.3.0 - SDS 1004.4 ... / >> H335 May cause respiratory irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. EUH066 Repeated exposure may cause skin dryness or cracking. EUH204 Contains isocyanates. May produce an allergic reaction. EUH208

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves / eye protection / face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P304+P340 IF INHALED: remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTRE or a doctor if you feel unwell. P370+P378 In case of fire: Use carbon dioxide (CO2), extinguishing powder or foam for extinction.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. SECTION 3. Composition/information on ingredients 3.1. Substances Information not relevant 3.2. Mixtures