SAC Identifier

Pemex Exploración y Producción

Revision date : 2019-01-30

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GHS02 GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

8002-05-9

Name of the chemical

Petroleum Crude Oil

Concentration

100%

Listed in

General Information

Version

1.0

Revision date

2019-01-30

Product name

SAC Identifier

CAS No.

8002-05-9

1.2.1 Relevant identified uses

of the This is the lightest of the Mexican crude oils, with a

1.2.2. Uses advised against

0.73% to 0.95% in weight, which makes it a light, bitter crude oil. These properties make it a good base material

supplier name

Data

Icons in SDS

GHS02 GHS06 GHS08 GHS09

Company Information

company name

Pemex Exploración y Producción

e-mail address of the competent person responsible for the Safety Data Sheet

ccae@pemex.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H224, H224+H302+H304+H340+H350+H361+H401+H373, H224+H319+H340+H350+H361, H302, H302+H304, H304, H304+H315, H304+H340+H350+H361, H315, H332, H332+H336, H340, H340+H350+H361, H373, H411

Hazard statements

Code

Statements

H224

Extremely flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

SAC Classification

Hazard statements

These are substances that are normally stable on their own, even in conditions such as fire. These include: Substances with an instant power density at 250ºC (482ºF) and lower than 0 0.01 W/ml. Physical • Substances that do not react with water. • Substances that do not show an exothermal reaction at temperatures lower than or equal to 500ºC (932ºF) when tested by differential scanning calorimetry. Slightly dangerous. Irritation or possible reversible injury. Light irritant, reversible within 7 days. Concentrations: 1 Orally; LD50 rat: higher than Healthcare Concerns 500 up to 5,000 mg/kg Skin; DL50 rabbit or rat: higher than 1,000 up to 5,000 mg/kg Inhaled; CL50 rat: higher than 20 up to 200 mg/l or higher than 2,000 to 10,000 ppm Liquids and solids that can burn under almost any condition at Environmental room temperature. These Concerns include the following: • Liquids with an ignition SAC Classification point lower than 22.8ºC (73ºF) and a boiling point equal or higher than 37.8ºC (100ºF), as well as those liquids with an 3 ignition point that is equal or higher than 22.8ºC (73ºF) and a boiling point lower than 37.8ºC (100ºF). • Substances that according to their physical form or surrounding environmental conditions, could form explosive mixtures with the air and that are easily dispersed into the air. • Substances that burn extremely quickly, because they usually contain oxygen. Elements of the SAC tags

Hazard pictograms

Warning Word : Danger Precautionary advice General : Not Applicable

Prevention

H224) P210 Keep away from heat, hot surfaces, sparks, open flame and other sources of ignition. No smoking. (H224/H319/H340/H350/H361) P280 Wear gloves, protective clothing and protective equipment for the eyes and face. (H304) P270 Do not eat, drink or smoke while handling this product. (H304/H315) P264 Wash carefully after handling. (H315) P280 Wear protective gloves. (H332/H336) P261 Avoid breathing in the fumes. P271 Use only outdoors or in a well ventilated place. (H340/H350/H361) P201 Read the instructions prior to use. P202 Do not handle before having read and understood all safety precautions. (H373) P260 Do not breathe in the fumes. (H411) P273 Do not release into the environment. Intervention : (H224) P370 + P378 In case of fire: Use water in the form of a spray or fog, dry chemical powder, carbon dioxide or chemical foam. (H302/H304) P301 If ingested + 312 If swallowed, call the Toxicological Assistance and Information Center of the Mexican Social Security Institute. (H302) P330 Rinse the mouth out. (H304) P331 Do not induce vomiting. (H315) P302 + P352 In the event of contact with the skin, wash with plenty of water. P332 + P313 IN the event of skin rash, consult a physician. P362 + P364 Remove any contaminated clothing and wash before wearing it again. (H332 harmful if inhaled) P304 + P340 In the event of inhalation, transfer the person outside and place them in a position that facilitates breathing. (H340 genetic defects /H350 may cause cancer /H361 may be harmful to fertility or harm the fetus) P308 +P313 In the event of assumed or proven exposure, consult a physician. (H373 may damage internal organs) P314 Consult a physician if the affected person is in a bad shape.

Storage

H224) P403 Store in a well ventilated place. (H304/H340/H350/H361) P405 Keep locked.

Disposal

H224/H302/H304/H340/H350/H361/H401/H373) P501 Dispose of the container and contents as hazardous materials. Other dangers that do not : Fumes of this product may create explosive appear in this classification mixtures with the air, they may travel to an ignition source and return in the form of open flame. Hydrogen sulfide is highly toxic and can be fatal if inhaled. H2S is an extremely flammable and toxic gas, and other hazardous vapors can evolve and accumulate in the headspace of storage tanks, transport containers and other closed containers. It can dull the sense of smell, so do not rely on odors as an indication of danger. Hydrogen sulfide has a variety of effects depending on the concentration in the air and the longitudinal exposure to this chemical compound. 0.02 ppm Olfactory threshold, smells like rotten eggs. 10 ppm irritation of the eyes and the airways, 100 ppm causes coughing, headaches, lightheadedness, ocular irritation, loss of the sense of smell within minutes. 200 ppm may cause lung edema after an exposure of over 20 to 30 minutes. 500 ppm loss of consistency after exposure, may cause respiratory arrest. Higher than 1000 ppm. Immediately there is loss of consciousness that may quickly lead to death, immediate cardiopulmonary reanimation may be necessary

Additional information

Not Applicable

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