Surefire Propyzamide 500 SC Herbicide

Hazard statements (CLP)

H315, H320, H351, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PROPYZAMIDE)

Signal word

WARNING Skin Irritation Category 2 Eye irritation Category 2B Carcinogenicity Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Hazard statements

H315: Causes skin irritation. H320: Causes eye irritation. H351: Suspected of causing cancer. H410: Very toxic to aquatic life with long lasting effects.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P273: Avoid release to the environment. P281: Use personal protective equipment as required.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Liquid, no data regarding colour. Odour: No data.

Health hazards

Propyzamide is practically nontoxic via ingestion. The reported oral LD50 values for Propyzamide range from 5620 mg/kg in female rats to 8350 mg/kg in male rats, respectively, and 10,000 mg/kg in dogs. Propyzamide is slightly toxic by skin exposure, with a dermal LD50 of greater than 3160 mg/kg. When applied to the skin of rabbits, it produced slight local irritation, but no systemic intoxication. The 4-hour inhalation LC50 for Propyzamide is greater than 5.0 mg/L, indicating slight toxicity by this route. Limited evidence of a carcinogenic effect, irritating to eyes and skin.