Rectvavit Structan

PCL Adhesives Limited

Revision date : 2021-04-26

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GHS07 GHS08 GHS09
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

227-534-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

EC/CAS

202-966-0

Name of the chemical

4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)

Concentration

N/A

General Information

Revision date

2021-04-26

Product name

Rectvavit Structan

Icons in SDS

Company Information

company name

PCL Adhesives Limited

e-mail address of the competent person responsible for the Safety Data Sheet

sales@pcladhesives.nz

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

CLP CLASSIFICATION

Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity — Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity — Repeated exposure, Category 2 H373

Hazard statements

see section 16 : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.

Adverse physicochemical, human health and environmental effects

Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Toxic to aquatic life with long lasting effects.

2.2 Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms

GHS07 GHS08

Signal word

Danger

Hazardous Ingredients

aromatic polyisocyanate prepolymer; Diphenylmethane-2,4'-diisocyanate; 4,4'- methylenediphenyl diisocyanate

Precautionary statements

P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P261 - Avoid breathing vapours, mist. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P321 - Specific treatment (see supplemental first aid instruction on this label). P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P405 - Store locked up.

Additional information

Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. As from 24 August 2023 adequate training is required before industrial or professional use.

2.3 Other hazards

The product does not meet the PBT and vPvB classification criteria

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