Note: Ingredients listed on restricted chemical lists
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
227-534-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
EC/CAS
202-966-0
Name of the chemical
4,4'-Methylendiphenyldiisocyanat 2,2'-Methylendiphenyldiisocyanat 2,4'-Methylendiphenyldiisocyanat Methylendiphenyldiisocyanat (790/2009)
Concentration
N/A
General Information
Revision date
2021-04-26
Product name
Rectvavit Structan
Icons in SDS
Company Information
company name
PCL Adhesives Limited
e-mail address of the competent person responsible for the Safety Data Sheet
sales@pcladhesives.nz
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
CLP CLASSIFICATION
Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Respiratory sensitisation, Category 1 H334 Skin sensitisation, Category 1 H317 Carcinogenicity, Category 2 H351 Specific target organ toxicity — Single exposure, Category 3, H335 Respiratory tract irritation Specific target organ toxicity — Repeated exposure, Category 2 H373
Hazard statements
see section 16 : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Adverse physicochemical, human health and environmental effects
Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Hazardous Ingredients
aromatic polyisocyanate prepolymer; Diphenylmethane-2,4'-diisocyanate; 4,4'- methylenediphenyl diisocyanate
Precautionary statements
P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P261 - Avoid breathing vapours, mist. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P321 - Specific treatment (see supplemental first aid instruction on this label). P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P405 - Store locked up.
Additional information
Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. As from 24 August 2023 adequate training is required before industrial or professional use.
2.3 Other hazards
The product does not meet the PBT and vPvB classification criteria