Iron-base Alloy and Castings

Hazard statements (CLP)

H302, H317, H335, H351, H372, H373, H413

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

OSHA HCS 2012 EU/EEC

2.2 Label elements

CLP DANGER Hazard • H302 - Harmful if swallowed

Hazard statements

H317 - May cause an allergic skin reaction H335 - May cause respiratory irritation H351 - Suspected of causing cancer. H372 - Causes damage to organs through prolonged or repeated exposure. H373 - May cause damage to organs through prolonged or repeated exposure. H413 - May cause long lasting harmful effects to aquatic life R22 - Harmful if swallowed R37 - Irritating to respiratory system. R40 - Limited evidence of a carcinogenic effect. R43 - May cause sensitisation by skin contact. R48/23 - Toxic: danger of serious damage to health by prolonged exposure through inhalation. R53 - May cause long-term adverse effects in the aquatic environment. Harmful if swallowed May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Suspected of causing cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure.

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust. P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P281 - Use personal protective equipment as required. Obtain special instructions before use Do not handle until all safety precautions have been read and understood. Do not breathe dust. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, clothing , and eye/face protection , . In case of inadequate ventilation wear respiratory protection.

Response

P304+P340 - IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P363 - Wash contaminated clothing before reuse. P321 - Specific treatment, see supplemental first aid information. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P301+P312 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. P330 - Rinse mouth. P308+P313 - IF exposed or concerned: Get medical advice/attention. Storage/Disposal • P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Supplemental • 34-48 percent of this product consists of an ingredient of unknown toxicity. information DSD/DPD IF INHALED If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. If on skin: Wash with plenty of water . Wash contaminated clothing before reuse. Specific treatment, see supplemental first aid information. If skin irritation or rash occurs: Get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. IF exposed or concerned: Get medical advice/attention. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Supplemental • 34-48 percent of this product consists of an ingredient of unknown toxicity. information

Precautionary statements

S24 - Avoid contact with skin S36 - Wear suitable protective clothing. S37 - Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use.

2.3 Other hazards

CLP

2.1 Classification of the substance or mixture

CLP • Products do not present an inhalation, ingestion or skin contact health hazard under normal handling and use as it is in a metallic form. However, processes such as welding, grinding, burning, melting, or otherwise generating dust, fumes and gases may present a health hazard. Acute Toxicity Oral 4 - H302 Skin Sensitization 1 - H317 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Carcinogenicity 2 - H351 Specific Target Organ Toxicity Repeated Exposure 1 - H372 Specific Target Organ Toxicity Repeated Exposure 2 - H373 Hazardous to the aquatic environment Chronic 4 - H413 DSD/DPD • Toxic (T) Irritant (Xi) Harmful (Xn) Carcinogenic Substances - Category 3 R22, R37, R40, R43, R48/23, R53