Patterson Non-Latex Super Dam

SECTION 2: Hazards identification

1272/2008 Classification of the substance or mixture Classification according to regulation (EC) No

Hazard pictograms

Not Applicable

Signal word

Not Applicable

Hazard statements

Not Applicable

Supplemental label elements

Not Applicable

Prevention

Not Applicable

Response

Not Applicable

Storage

Not Applicable

Disposal

Not Applicable

2.3 Other hazards

May produce discomfort of the respiratory system*. REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

2.1 Classification of the substance or mixture

regulation (EC) No 1272/2008 [CLP] and Not Applicable amendments [1] Page 1 continued... 2.2. Label elements Hazard pictogram(s) Not Applicable Signal word Not Applicable Hazard statement(s) Not Applicable Supplementary statement(s) Not Applicable Precautionary statement(s) Prevention Not Applicable Precautionary statement(s) Response Not Applicable Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal Not Applicable 2.3. Other hazards May produce discomfort of the respiratory system*. REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 Composition / information on ingredients 3.1.Substances See 'Composition on ingredients' in Section 3.2 3.2.Mixtures 1. CAS No 2.EC No Classification according to regulation (EC) No SCL / Nanoform Particle %[weight] Name 3.Index No 1272/2008 [CLP] and amendments M-Factor Characteristics 4.REACH No Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties SECTION 4 First aid measures 4.1. Description of first aid measures If this product comes in contact with eyes: Wash out immediately with water. Eye Contact If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. Immediately give a glass of water. Ingestion First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 4.2 Most important symptoms and effects, both acute and delayed See Section 11 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Continued... SECTION 5 Firefighting measures 5.1. Extinguishing media There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area. 5.2. Special hazards arising from the substrate or mixture Fire Incompatibility None known. 5.3. Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. Fire Fighting DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use. Non combustible. Fire/Explosion Hazard Not considered a significant fire risk, however containers may burn. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures See section 8 6.2. Environmental precautions See section 12 6.3. Methods and material for containment and cleaning up Clean up all spills immediately. Avoid contact with skin and eyes. Wear impervious gloves and safety glasses. Use dry clean up procedures and avoid generating dust. Vacuum up (consider explosion-proof machines designed to be grounded during storage and use). Minor Spills Do NOT use air hoses for cleaning Place spilled material in clean, dry, sealable, labelled container. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Control personal contact with the substance, by using protective equipment and dust respirator. Prevent spillage from entering drains, sewers or water courses. Major Spills Avoid generating dust. Sweep, shovel up. Recover product wherever possible. Put residues in labelled plastic bags or other containers for disposal. If contamination of drains or waterways occurs, advise emergency services. 6.4. Reference to other sections Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 Handling and storage 7.1. Precautions for safe handling Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with incompatible materials. Safe handling When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Continued... Work clothes should be laundered separately. Use good occupational work practice. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are maintained. Fire and explosion See section 5 protection Store in original containers. Keep containers securely sealed. Other information Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. 7.2. Conditions for safe storage, including any incompatibilities Lined metal can, lined metal pail/ can. Plastic pail. Suitable container Polyliner drum. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks. Storage incompatibility None known Hazard categories in accordance with Not Available Regulation (EC) No 1272/2008 Qualifying quantity (tonnes) of dangerous substances as referred to Not Available in Article 3(10) for the application of 7.3. Specific end use(s) See section 1.2 SECTION 8 Exposure controls / personal protection 8.1. Control parameters DNELs PNECs Ingredient Exposure Pattern Worker Compartment Not Available * Values for General Population Occupational Exposure Limits (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes I Not Available Not Applicable Emergency Limits Ingredient TEEL-1 TEEL-2 TEEL-3 HySolate Non-Latex Dental Not Available Dam Ingredient Original IDLH Revised IDLH HySolate Non-Latex Dental Not Available Dam MATERIAL DATA 8.2. Exposure controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed 8.2.1. Appropriate engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to engineering controls provide this high level of protection. Continued... The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use. Employers may need to use multiple types of controls to prevent employee overexposure. Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively large, a certain proportion will be powdered by mutual friction. If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be considered. Such protection might consist of: (a): particle dust respirators, if necessary, combined with an absorption cartridge; (b): filter respirators with absorption cartridge or canister of the right type; (c): fresh-air hoods or masks. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant. Type of Contaminant: Air Speed: direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s (200-500 discharge (active generation into zone of rapid air motion) f/min.) grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial 2.5-10 m/s velocity into zone of very high rapid air motion). (500-2000 f/min.) Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favourable to capture 1: Disturbing room air currents 2: Contaminants of low toxicity or of nuisance value only. 2: Contaminants of high toxicity 3: Intermittent, low production. 3: High production, heavy use 4: Large hood or large air mass in motion 4: Small hood-local control only Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 4-10 m/s (800-2000 f/min) for extraction of crusher dusts generated 2 metres distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are 8•ct@ ' Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent] Safety glasses with side shields installed or used. 8.2.2. Individual protection measures, such as personal protective equipment ' Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy ' document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59]. Skin protection See Hand protection below Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not present. polychloroprene. nitrile rubber. Hands/feet protection butyl rubber. fluorocaoutchouc. polyvinyl chloride. Gloves should be examined for wear and/ or degradation constantly. Body protection See Other protection below No special equipment needed when handling small quantities. OTHERWISE: Other protection Overalls. Barrier cream. Eyewash unit. Continued... I Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator P1 - PAPR-P1 up to 10 x ES Air-line* - up to 50 x ES Air-line** P2 PAPR-P2 up to 100 x ES - P3 - Air-line* - 100+ x ES - Air-line** PAPR-P3 * - Negative pressure demand ** - Continuous flow A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC) 8.2.3. Environmental exposure controls See section 12 SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Not Available Relative density (Water = Physical state Solid Not Available 1) Partition coefficient Odour Not Available n-octanol / water Auto-ignition temperature Odour threshold Not Available (°C) Decomposition pH (as supplied) Not Available temperature (°C) Melting point / freezing Not Available Viscosity (cSt) Not Available point (°C) Initial boiling point and Not Available Molecular weight (g/mol) Not Available boiling range (°C) Flash point (°C) Not Available Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Surface Tension (dyn/cm Upper Explosive Limit (%) Not Available Not Applicable or mN/m) Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available Solubility in water Immiscible