- PEC

Hazard statements (CLP)

H225, H226, H315, H317, H319, H332, H336, H351, H361f, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

at least and and other ignition Effects Avoid 10 toxic minutes. Wear information criteria Directive dispersion on consumers protective sources. for Seek to Annex II to REACH - Regulation (EU) 2020/878 and to Annex II to UK REACH 98/24/EC; this 91/322/EEC. and medical gloves/ No smoking. runoff not class Directive assistance. of protective available spilled material In clothing case of and / eye complaints contact protection Effects with or symptoms, / soil, face on waterways, workers protection. avoid drains further and exposure. sewers. Wash Inform clothing the

TOXICOLOGICAL INFORMATION

before competent Dynamic Titanium Substances - PNEC: P370+P378 Route reusing Predicted dioxide viscosity of authorities exposure subject it. Clean no to TLV-ACGIH effect if exportation your the Acute product concentration shoes In case reporting thoroughly has of Acute caused fire: ACGIH pursuant before use environmental 2023 . . 1500 using . to to Regulation extinguish. Chronic to them 6000 pollution again. mPa·s (EU) (sewers, Chronic 649/2012: waterways, Acute soil local or air). Water Acute polluting Chronic material. Chronic

UN Number

or ID number Ingestion: May Solubility CARCINOGENICITY Degradability: None - REACH: In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it P261 be harmful Rinse Regulation information to mouth the (EC)

Contains

using the criteria specified in the applicable regulation for classification. of / the ADR / RID, IMDG, IATA: Oral Regulation of 1. water Identification concerning to drink. Stop the If international UN 1993 skin if of the irritation the exposed substance/mixture transport or person rash non occurs: of feels solubile dangerous N-BUTYL sick Get in because medical acqua goods ACETATE 0,0833 and calda. vomiting advice by train attention. can be company/undertaking dangerous. Do not induce vomiting unless directed by 6.3. 12.3. medical Threshold Partition Does Substances - TLV: It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the Methods Bioaccumulative P337+P313 not Threshold coefficient: personnel. meet and Limit subject the material Limit Value classification to n-octanol/water If potential Value the vomiting for Rotterdam containment If criteria occurs, eye Convention irritation for the this and head persists hazard cleaning should not class Get available be up medical kept low advice so mg/kg that / attention the bw/d vomit does not enter the lungs. Seek medical attention if adverse health toxicological Vapour None TLV Product UN proper effects Type Inhalation CEILING effects pressure identifier shipping persist Concentration of exposure Country or are that name to the product severe TWA/8h should Never not be give exceeded 0.0013 anything during STEL/15min kPa by mouth <0.01 any time to 0,145 mm an of unconscious Hg) occupational Remarks person exposure If Observations she is unconscious, place her 0,822 in the recovery position Small Density REPRODUCTIVE TWA: spill Time-weighted and/or and stop seek relative leak medical TOXICITY if average there density attention is no exposure mg/m3 risk immediately Move limit containers ppm >1,1, from <1,14 mg/m3 spill area. Dilute ppm mg/m3 with water and dry if water soluble. Alternatively, or if mg/m3 insoluble Code Keep in Relative N-BUTYL Substances TWA water, Contains OEL Skin the STEL vapour absorb airway ACETATE subject Short-term density open with to EU dry Loosen the exposure inert Stockholm material tight 2-Hydroxyethyl 241 limit clothing Convention and place such methacrylate 50 as in a collar, REF not suitable available 2512 tie, 723 container belt or waist for 0,0833 150 waste disposal. Dispose of through a licensed waste disposal ADR Information RID on hazard 0,233 FLAMMABLE classes as LIQUID, defined N.O.S 2-Hydroxyethyl methacrylate polyurethane acrylate oligomer Identification x = Conc. %

Environmental hazards

CAS approved ETHYL Skin ACETATE Sens alternative, made of a Skin compatible sensitization, material category and kept 1 tightly closed when not in use Wear Firefighting measures disruptors Based TLV-ACGIH 2-Hydroxyethyl Empty Information Classification Decomposes Skin containers Delegated Regulation (UE) 2018/1480 (XIII Atp. CLP) category on the Sens with available not available human II professional 1A methacrylate of slowly retain the into health data, effects substance product acetic Skin the long-sleeved residue product 0,2 under does acid or sensitization, mixture and and ethanol evaluation overalls can be category not contain under and safety dangerous the 1A effect substances footwear listed Do not of light, reuse air the and container see in Regulation the main RESP water European 2016/425 lists and of standard potential EN or ISO suspected 20344). endocrine Wash body with disruptors Regulation INDEX General STOT occupational soap and SE 3 607-124-00-X with water environmental EU) 2019/1148 after removing hygiene advice effects protective Specific under evaluation 22,5 Eating, target x < drinking clothing organ 24 toxicity and smoking Eye single Irrit. are exposure, prohibited H319, Skin category in Irrit areas 3 2 where SECTION ADR / RID: 12. Ecological information Consider Delegated H315, the Skin material the appropriateness Sens. 1 is H317, Regulation NO (UE) of 2020/217 handled, Classification stored or providing (XIV antistatic note Atp. CLP) clothing in the case of working environments in which there is a risk of explosion 10.2. The processed ACUTE IMDG Extinguishing Chemical Aquatic product TOXICITY Workers Chronic is stability classified media must as wash hazardous their Hazardous hands pursuant to and the faces to aquatic the before provisions according eating, set drinking forth chronic to Annex in (EC) and toxicity, smoking VI Regulation to category the Remove provisions beverage product to thus the areas and aquatic the See Regulation aquatic also Section organisms chronic for In further the that toxicity, long information term, category it with have on 3 the hygiene negative measures effects of (EU) on aquatic environment. 2020/878 Threshold Wear 20. Delegated CAS Suitable The ATE H225 product Inhalation airtight Limit extinguishing is stable protective Regulation 868-77-9 gas) of media Value goggles the mixture UE) 2021/643 Use see standard Highly dry flammable chemicals, liquid XVI Atp EN ISO CLP) 16321) CO₂, water and vapour spray 20000 or mg/l foam 12.1. Any RESPIRATORY Information 21. Delegated Regulation (UE) 2021/849 (XVII Atp. CLP) Titanium Unsuitable ATE Conditions Toxicity Type H226 additional Oral) dioxide extinguishing of the not available for information PROTECTION mixture safe storage, Country media concerning Flammable Do including TWA/8h not the use risks any water liquid incompatibilities for jets and health vapour and/or STEL/15min Not the classified no significant are given component) Remarks / Observations in sections 11 and 12 of this sheet Special precautions for user Respiratory 22. Delegated protection Regulation devices UE) must 2022/692 mg/m3 be used XVIII if ppm the Atp. technical CLP) measures mg/m3 adopted ppm are not suitable for restricting the worker's exposure to the INDEX ATE Possibility H351 Dermal) of of 022-006-00-2 the hazardous mixture: reactions Suspected ≤ x < of 2,5 causing cancer. Carc Not classified H351, (no Aquatic significant Chronic component) H411 Hazard threshold 23. Delegated Regulation (UE) 2023/707 EC Shield N-BUTYL Special OEL values considered H361f UV classification hazards ACETATE light sources 236-675-5 arising EU and Store indication from Use a 734 mask with a 200 in Suspected accordance the substance of with damaging type A filter whose or local mixture regulations fertility 1468 class 400 SECTION Store in a separate, approved area. Keep ADR / RID: 13. Disposal considerations Predicted concentration 1, 2 or 3) must be chosen according to the limit of use no-effect see standard concentration EN 14387) HIN - Kemler: 30 PNEC Limited Quantities: 5 L Tunnel restriction code: (D/E) CAS in Hazardous Acute the Flammable H332 original LC50 polymerization 32 container liquid, mg/l 13463-67-7 Marine category away may water from occur Harmful Crustaceans direct under if sunlight, inhaled certain Artemia in storage a dry, salina cool or use 48 and conditions hours If - The well-ventilated the Normal H226 substance value considered place, Flammable in fresh water away from liquid is odourless or its olfactory threshold is higher than the corresponding TLV-TWA incompatible Special provision: 274, 601 and vapour materials (see Section 10) 0,24 and in the mg/l case of an ETHYL Hazards and These IMDG Waste Eye Merck Index. - 10th Edition H319 food could irritation, N-BUTYL ACETATE arising and treatment cause drink from category ACETATE the Eliminate methods the product substance all to Causes sources EMS: F-E, S-E polymerize or mixture serious of ignition exothermically Flammable eye Separate irritation liquid Inadvertent from and Limited Quantities: 5 L oxidizing vapour H319 contact materials Runoff with into them Causes sewers should serious may be avoided create eye irritation a fire or explosion hazard emergency, Handling INDEX In Keep Titanium the Skin Normal value H315 the event LD50 irritation, dioxide container Chemical Safety wear in open-circuit of (Dermal) a 607-022-00-5 fire category marine water tightly or overheating, closed compressed air breathing apparatus (in compliance with standard EN 137) 0,024 Causes and a 2 sealed pressure x skin < 2,5 until irritation increase ready for will use Flam occur 17600 Containers and Liq. mg/kg the H315 H225, container that rabbit have Eye may Irrit been Causes burst opened H319, with skin STOT must the irritation risk be SE of carefully or external air-intake a H336, subsequent mg/l resealed EUH066 explosion breathing and kept This IATA apparatus INRS Normal (in value compliance for fresh with water standard sediment EN 138). For a correct choice of respiratory protection device, see 1,15 standard EN mg/kg Cargo Maximum quantity: 220 L Packaging instructions: 366 529 EC material upright N-BUTYL Acute Reuse, Skin - Fiche Toxicologique (toxicological sheet) H317 LC50 to LD50 when sensitization, is avoid ACETATE harmful possible Oral) mg/l 205-500-4 leaks to Fresh aquatic category Do Product water not life store 1A Crustaceans residues May with in cause Passengers long unlabeled should lasting an Ceriodaphnia allergic be containers effects considered skin Fire reaction dubia Use 10768 water special Maximum quantity: 60 L appropriate Newborn mg/kg contaminated hazardous H317 rat containment 48 hours waste with this May The to material avoid cause hazard contamination an must level allergic Packaging instructions: 355 be of contained waste skin of reaction the containing and environment. prevented this product Consult from ENVIRONMENTAL Patty CAS being Section Acute should Normal value for EXPOSURE Hazardous Risk H336 discharged LC50 Industrial Hygiene and Toxicology be LC50 10 of evaluated explosion for 6.5 (Inhalation incompatible to 141-78-6 mg/l the into Fresh the terrestrial CONTROLS according aquatic on waterways, contact gas) water materials to May with Daphnia applicable sewers compartment cause before strong or - chronic Daphnia drowsiness drains regulations handling oxidising pulex or agents.May or use. dizziness Newborn 4000 react ppm/4h 48 H412 dangerously hours rat with: Harmful alkaline to hydroxides,potassium aquatic life with long lasting 0,148 mg/kg tert-butoxide.Forms effects Health The N.I. emissions Sax - Dangerous properties of Industrial Materials-7, 1989 Edition Derived generated no-effect by level manufacturing Special provision DNEL / DMEL processes, including those generated by ventilation equipment, should be checked to ensure A3 N-BUTYL Hazardous Disposal toxicity, explosive H411 must ACETATE category Combustion mixtures be performed with Products air. through Toxic Decomposition an to authorised aquatic life products waste with long management may lasting include effects the firm, following in compliance materials with national and local regulations compliance IFA GESTIS with website INDEX carbon Seveso ETHYL Waste H412 transportation dioxide ACETATE ETHYL Directive ACETATE 607-025-00-1 environmental Reporting may be thresholds Effects subject standards Harmful on consumers to ≤ ADR x to < aquatic restrictions 2,5 life with long Flam lasting Liq. effects H226, Acute Tox. 4 H332, Eye Irrit. 2 H319, STOT SE 3 H336, Effects on workers 14.7. Product ECHA carbon Hazard LC50 CONTAMINATED Maritime Route website Risk EUH066 Pimephales monoxide criteria LD50 residues of explosion of exposure transport Dermal) must not PACKAGING promelas on contact in bulk be Acute cyprinid indiscriminately according Acute Repeated with: alkaline fish) exposure to IMO 220.00 disposed metals,hydrides,oleum.May instruments may 250.00 of Chronic cause with waste water Aquatic 18000 mg skin l - mg/kg 96 dryness Chronic h react Chronic ratto or 3 o violently or by dumping cracking H412, coniglio EUH066 Acute with: fluorine,strong oxidising agents,chlorosulphuric in waterways local Acute Chronic 2.2 Database of SDS models Label local for chemicals systemic Ministry of Health local and ISS (Istituto EC metal Category Toxicity Contaminated Information not relevant acid,potassium systemic oxide/oxides LD50 to elements Superiore di Sanità) - Italy systemic P5c daphnia Oral) packaging 204-658-1 tert-butoxide.Forms and other must aquatic be recovered invertebrates explosive or disposed mixtures of with local in STA 5620 systemic compliance air. Inhalation mg/kg ratt with gas national 4500 waste ppm management regulations CAS N-BUTYL Notification EC50 Conditions Oral ACETATE Daphnia LC50 and (Inhalation to 123-86-4 MAPP magna avoid threshold Water mists/powders) flea) 5000 2,300.00 tonnes - 3,090.00 mg 56 l mg/l/4h 24 h ratto 4,5 Hazard DO NOT dispose of in the sewer. DO NOT allow this chemical to contaminate TPO Safety LC50 Product LEGEND Advice ratio Daphnia SECTION Note Inhalation INDEX Avoid Toxicity

2.2 Label elements

for threshold: firefighters magna pursuant 50000 (Water to EC tonnes flea) Regulation

Disposal

ADR: all European for users: 2-Hydroxyethyl to possible methods: algae 15. 015-203-00-X EC50 Regulatory Agreement sources The - methacrylate generation No of information concerning ignition information of 1 (sparks waste ≤ available. 734 x the < should carriage 1,5 or flames). - 4,300.00 be of avoided Dangerous Do not mg Repr. 367 or / pressurize, l minimized - goods 2 24 H361f h by cut, wherever Road weld, braze, possible. 1468 drill, grind, or expose containers to heat or 1468 734 The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the EC Special sources EC50 - ATE: Specific - Acute Selenastrum Effective (mg/l) ACETATE spray estimates = contractor. to 1 concentration keep containers Waste (required must exposed not to be induce to disposed fire a cool. 50% of effect) untreated into sewers unless it fully complies with the requirements of all relevant The use of this product is not subject to our direct control; 2-Hydroxyethyl The Special SP23 authorities. - CE: Avoid full Identifier Dreamer: wording protective exposure in Inhalation of ESIS equipment to: moisture,sources (European (gas) (H) for phrases 10214.3 firefighters: archive is of ppm given of heat,naked existing Firefighters in section substances) flames. must 16 of wear therefore, users methacrylate the sheet. appropriate protective equipment and self-contained breathing apparatus must, under their own responsibility, comply with the current health 9.1. (SCBA) Health Seveso and safety ETHYL Hazardous - CLP: Information Regulation - Category ACETATE with waste: Derived laws and no-effect a on face basic - Directive (EC) The shield regulations. - EmS: Incompatible

Hazard pictograms

LD50 protective of of end ignition. this Toxicity (Oral): use(s) 278-355-8 product, actions Estimate - 1,800.00 solutions for firefighters: - 3,200.00 and any Promptly mg/m3 mg by-products / l - 72 isolate h must mg/m3 the 5050 always area mg/kg by comply removing rat with all the people requirements from the of area environmental mg/m3 of the accident protection mg/m3 in case and of fire. waste No suitability and thoroughness of provided information according to each specific use of the product. CAS action M disposal - CAS: factor shall Chemical = legislation 1 be taken 75980-60-8 Abstract and involving the Service requirements personal Number risk of or regional without local adequate authorities. training. Dispose Move of containers surplus and 15.1. This Safety, SECTION 9. Physical and chemical properties from non-recyclable document fire area if this products health must and not environmental can be done be regarded as regulations/legislation through without a licensed a guarantee on any specific risk. specific product for property. the substance or mixture Use Not N-BUTYL Acute C(E)L50 waste - CE50: available. water toxicity

Principle Routes of Exposure

- for Emergency methods: Fish relating to the product materials The Schedule generation of waste should be Value Acute or contained Acute substances avoided Chronic 18000 or μg/l minimized pursuant to Chronic Fish - Pimephales Annex XVII to Acute wherever possible. EC Regulation promelas Information local Waste packaging should be recycled.

Precautionary statements

or dioxide incompatible International Accidental This with Air material 3 - 40 release Transport the following P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P370+P378 In case of fire: use . . . to extinguish. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P333+P313 If skin irritation or rash occurs: Get medical advice / attention. P337+P313 If eye irritation persists: Get medical advice / attention.

2.1 Classification of the substance or mixture

to n-octanol/water If potential Value the vomiting for Rotterdam containment If criteria occurs, eye Convention: irritation for the this and head persists: hazard cleaning should not class Get available be up medical kept low advice so mg/kg that / attention. the bw/d vomit does not enter the lungs. Seek medical attention if adverse 1.1. health 14.2. toxicological Vapour None - TLV Product UN proper effects Type Inhalation CEILING: effects pressure identifier shipping persist Concentration of exposure Country or are that name to the product. severe. TWA/8h should Never not be give exceeded <0.0013 anything during STEL/15min kPa by mouth (<0.01 any time to 0,145 mm an of unconscious Hg) occupational Remarks person. exposure. / If Observations she is unconscious, place her 0,822 in the recovery position Small Density REPRODUCTIVE - TWA: spill: Time-weighted and/or and stop seek relative leak medical TOXICITY if average there density attention is no exposure mg/m3 risk. immediately. Move limit containers ppm >1,1, from <1,14 mg/m3 spill area. Dilute ppm mg/m3 with water and dry if water soluble. Alternatively, or if mg/m3 insoluble Code: Keep in Relative N-BUTYL Substances - TWA water, Contains: OEL Skin the STEL: vapour absorb airway ACETATE subject Short-term density open. with to EU dry Loosen the exposure inert Stockholm material tight 2-Hydroxyethyl 241 limit clothing Convention: and place such methacrylate 50 as in a collar, REF not suitable available 2512 tie, 723 container belt or waist. for 0,0833 150 waste disposal. Dispose of through a licensed waste disposal 11.1. ADR Information / RID: on hazard 0,233 FLAMMABLE classes as LIQUID, defined N.O.S. in Regulation (EC) No 1272/2008 Product Protection contractor. Health Particle Does Partition None - VOC: not - Volatile characteristics name Derived coefficient: meet of first the organic aid no-effect classification n-octanol/water workers: Compounds level No polyurethane criteria - action DNEL for should / this DMEL acrylate hazard be taken SP23 not oligomer class applicable which 2,3 Dreamer potential: involves low mg/kg personal bw/d risk or without adequate training. If the presence mg/kg IMDG: of fumes is FLAMMABLE LIQUID, N.O.S. suspected, Large - vPvB: spill: IATA: N-BUTYL ACETATE Very the stop persistent rescuer the leak and FLAMMABLE LIQUID, N.O.S. should if there Effects very wear bioaccumulative is on no an consumers risk. appropriate Move containers mask or self-contained from spill area. breathing Approaching apparatus. Effects release on from workers windward. Prevent entry into bw/d sewers, 1.2. It waterways, STOT ETHYL Healthcare - vPvM: Relevant can Route be - SINGLE ACETATE Result: Eyes - Moderately irritating. Species: Rabbit. Exposure: 100 mg Very dangerous of controls identified basements exposure persistent EXPOSURE for uses or the and confined Acute person very of the mobile substance providing areas. Acute aid or to mixture perform Chronic and mouth-to-mouth uses advised Chronic resuscitation. against Acute local Acute Chronic 9.2. Wash 14.3. Transport Legend: Partition Workers - WGK: Other contaminated spills Specific hazard information Water coefficient: exposed at hazard an effluent target class(es) to n-octanol/water clothing this classes organ toxicity (single exposure): category 3. Target organs: Narcotic effects. chemical treatment local thoroughly (German). agent plant with systemic must or water do not the undergo before following. removing, local 0,68 health Contain potential: checks, or and wear systemic low provided collect gloves. spillage that available with non-combustible risk-assessment systemic absorbent data local prove material, that systemic the e.g. risks sand, 2.3. Intended earth, (C) Does related Other Oral = CEILING not vermiculite to hazards use meet the workers' the ; or classification INHAL diatomaceous health = Inhalable and criteria safety earth Fraction for 2 are and this modest place hazard ; RESP them and UV class gel that in = Respirable a the container 98/24/EC Fraction for 2 disposal directive ; THORA according is respected. = Thoracic to local regulations. Fraction. Dispose of through a licensed VND 2-Hydroxyethyl ADR / RID: = hazard Titanium dioxide Class: 3 waste identified disposal methacrylate contractor. but no DNEL/PNEC mg/kg available Label: 3

PBT Substances

clothing and EU unsuitable H317 Persistent, such as materials. temperature collar, OEL bioaccumulative May and cause tie, See EU belt. also what is reported toxic an allergic not skin Directive in (EU) "For 2022/431; available non-emergency reaction. Directive personnel". (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU) Decomposition H412 temperature Harmful to aquatic life with long lasting effects. ... / >>

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures