Ecological

Hazard statements (CLP)

H315, H319, H336

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Concentration Value as a that carcinogen Wear should protective by not inhalation be gloves exceeded / applies eye during protection only any to mixtures SECTION 5. 8. 9. Firefighting In On - TWA: the P312 time Type the event / face of protection. basis Time-weighted which of of is thermal occupational in powder form Exposure Physical and available in the Country form average decomposition exposure. data, containing 1% or more of titanium dioxide of or the According controls/personal exposure Call incorporated measures TWA/8h product chemical a or POISON to Annex properties fire, limit does gases in CENTRE particles not and II to REACH

Contains

vapours protection with / doctor any STEL/15min aerodynamic - Regulation (EU) 2020/878 and to Annex II to UK REACH Value chemical class substances health powder. 1468 For are product listed 400 in the main European lists of potential or suspected endocrine evaluated loss according or leakage Information to that the has properties not caught of the fire, substances water spray it can 1.1. disruptors None be DEU Appearance Product used to using VLEP with identifier disperse environmental the criteria flammable FRA Deutschland specified effects vapours PROPAN-2-OL 734 under evaluation. in the and applicable Technischen protect those 200 Color regulation Regeln trying gel for 1468 to für stem classification. Gefahrstoffe the leak. (TRGS 900) - Liste der Arbeitsplatzgrenzwerte und 400 STOT VLEP UNSUITABLE Colour It is therefore necessary - SINGLE EXPOSURE EXTINGUISHING ITA to take into ETHYL EQUIPMENT 734 ACETATE account Kurzzeitwerte. the concentration 200 not available MAK- of und 1468 the BAT-Werte-Liste individual hazardous 400 2020, substances Ständige Senatskommission indicated in section zur 3, Prüfung to evaluate the 12.7. Code: Substances GENERAL Do Odour toxicological Other WEL adverse not use jets BIBLIOGRAPHY subject effects effects of water. of exposure to GBR exportation 734 Water is to not reporting pursuant the effective product. gesundheitsschädlicher for putting 200 15001 of acrylic to Regulation out fires but 1468 (EU) 400 Arbeitsstoffe, can be used Mitteilung 649/2012: to cool containers 56 exposed to flames to prevent explosions. Product May None 1. Regulation OEL cause name drowsiness class Parliament any care PBT products or vPvB in percentage ≥ than 0,1%. 0,024 mg/l Excess EU Upper explosive pressure limit may OEL form EU in containers exposed Directive to fire (EU) not at available 2022/431; a risk of explosion. Directive (EU) Do not 2019/1831; breathe combustion Directive (EU) products. 2019/130; Directive (EU) 13.1. Flash Substances 6. Regulation Information Waste Normal value point treatment not available subject (EU) for 618/2012 to fresh methods the water Stockholm (III Atp. sediment CLP) Convention: of the European Parliament 2019/983; > 93,3 Directive °C (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 1,15 mg/kg/d Uses The ASPIRATION None 7. Regulation Normal product Advised value does (EU) Against for not 487/2013 the contain terrestrial (IV substances Atp. compartment CLP) with of the endocrine European disrupting Parliament properties in concentration ≥ 0.1%. 0,148 5.3. Auto-ignition Advice for firefighters mg/kg/d temperature 2006/15/EC; not Directive available 2004/37/EC; Directive 2000/39/EC; Directive 98/24/EC; Directive Do Health 8. Regulation not - use Derived for (EU) purposes no-effect 944/2013 other level (V Atp. than - DNEL CLP) those / of DMEL the listed European Parliament Decomposition Information Reuse, when on possible. SPECIAL Threshold Vapour pressure Regulation on and the Country PROTECTIVE Limit Value EQUIPMENT FOR FIRE-FIGHTERS safety available (EU) 2017/776 assessment data, the (X product Atp. CLP) does not contain 36100 substances not available Vicenza listed mg/kg in bw/d the main European lists of (VI) potential or suspected endocrine disruptors 14. Inhalation Regulation with human (EU) 2018/669 health 734 effects (XI Atp. under CLP) 734 evaluation. 367 Italia 367 Normal Density Information Type fire and/or fighting not relative available 1468 clothing Country density i.e. fire TWA/8h kit (BS EN 469), gloves 1468 734 not available (BS STEL/15min 734 EN 659) and boots (HO specification SECTION PROPAN-2-OL ETHYL ACETATE Identification x = Conc. %

PBT Substances

that / . . or are . if vPvB you potentially diameter feel in percentage unwell. dangerous Persistent Specific Avoid information coefficient: exposure to: on light,sources bioaccumulative n-octanol/water and toxic as REACH Regulation symptoms and of heat,naked effects caused flames. by the product are unknown. 68 ventilated Does BCF Restrictions - PEC: Predicted not statements: meet place, keep far away from sources of heat, naked flames and sparks and other sources of ignition. Keep containers away from any relating the environmental to the product Concentration criteria or contained for this hazard substances

Remarks

μm. ≥ than to / health Observations 0,1%. may be released. 5.1. 8.1. Extinguishing Substances - TWA Control parameters P403+P233 STEL: in Short-term Candidate exposure media List (Art. Store mg/m3 limit 59 in REACH) a well-ventilated ppm place. mg/m3 Keep container ppm tightly closed. 12.6. REPRODUCTIVE 9.1. Information on basic physical and chemical properties On - VOC: Endocrine P264 AGW the basis Volatile of disrupting organic available TOXICITY DEU Compounds data, properties the Wash 730 product . . . thoroughly does 200 not contain after handling. any 1460 SVHC in 400 percentage ≥ than 0,1%. / Observations A 15. chemical Identification self-contained Relative vapour open Regulation A29 and A30) in combination with safety 14. (EU) Transport density assessment 2019/521 mg/m3 circuit positive mg/m3 (XII has information Atp. not been pressure x = Conc. CLP) mg/m3 performed Tel. for mg/m3 compressed ppm % not available air breathing the preparation/for mg/m3 +39 0444-239569 apparatus mg/m3 the substances ppm (EC) (BS

TOXICOLOGICAL INFORMATION

SECTION

vPvB Substances

MAK Very 1. Persistent Identification DEU and very Bioaccumulative 750 of the substance/mixture 200 as for REACH Regulation and of the company/undertaking 1500 400 SUITABLE Regulatory EXTINGUISHING references: EQUIPMENT Does Based Substances - WGK: Extinguishing Properties In the absence substances VLA not on Water meet the subject available

2.1 Classification of the substance or mixture

Rat life. note according to Annex VI to the CLP Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the Protect hands with category III work gloves. Predicted LC50 Eye remainder There not applicable EUH066 - for are no irritation, Fish with particular no-effect inert absorbent category concentration risks of material. 2 reaction with other substances in normal conditions of use. Repeated - PNEC exposure may cause 2125 Regulation: mg/l/96h skin dryness H319 10, or V, cracking. W Causes serious eye irritation. The Note following EC Chronic Skin Normal for users: should be considered when choosing work glove material (see standard EN 374): compatibility, degradation, failure time and PROPAN-2-OL irritation, NOEC value for 236-675-5 in category Fish fresh water 2 756 mg/l H315 Causes skin irritation. 140,9 mg/l Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. permeability. The information in the sheet are based on our own knowledge on the last version. must verify the 14.5. ETHYL CAS Chronic Environmental Specific Normal LD50 ACETATE hazards NOEC value target contained (Dermal): for 13463-67-7 in organ Crustacea marine toxicity water - present single exposure, 24 12800 mg/l mg/kg H336 Rat May date cause of the drowsiness 140,9 or Users dizziness. mg/l The suitability LEGEND: category Normal work gloves' LD50 value and thoroughness 3 (Oral): for fresh water sediment resistance to of chemical provided information agents should according be checked 4710 mg/kg Rat to each before specific use, use as it of can the be product. unpredictable. The gloves' wear time depends on 552 mg/kg/d 6.4. Reference the This duration Decomposes document and must to other slowly sections type not of use. into acetic acid and ethanol under the effect of light, air and water. be regarded as a guarantee on any specific product property. 12.2. The - ADR: not Persistence Normal full European wording value and of for Agreement hazard marine degradability (H) water concerning phrases sediment is the given carriage in section of Dangerous 16 of the sheet. goods by Road 552 mg/kg/d SKIN The applicable use PROTECTION of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health 10.2. Any Health - ATE: Acute information - ETHYL Derived Toxicity stability ACETATE no-effect personal Estimate level - DNEL / DMEL protection and disposal and Wear and Chemical safety category elements laws II and on professional regulations. long-sleeved The producer 2.2. - CAS: 14.6. Special precautions for user overalls is relieved Label Chemical is and given LD50 safety from in sections (Oral): Abstract Service any footwear liability 8 (see Effects Number arising Regulation 13. from improper on consumers 2016/425 uses. and standard EN ISO 20344). Wash body 5620 mg/kg ratt Effects on workers with Provide TITANIUM - CE50: Route Effective soap appointed of DIOXIDE and water staff exposure concentration after with removing [in powder Acute (required adequate form containing protective training clothing. Acute to induce 1 a % 50% on how to use chemical products. or more Chronic effect) of particles Chronic with aerodynamic Acute diameter local ≤ 10 Acute μm] Chronic SECTION The product is stable in normal conditions of use and storage. EYE PROTECTION 4. First SECTION Hazard SKIN Solubility - CE: Identifier in ESIS (European not applicable CORROSION labelling

Principle Routes of Exposure

temperature Product residues should 91/322/EEC. be considered not available special hazardous waste. The hazard level of waste containing this product 1.3. Does Healthcare 9. Details GENERAL pH should be evaluated Regulation not of meet INFORMATION controls the (EU) the supplier

Classifications

605/2014 TLV-ACGIH according to applicable ACGIH of Effects the (VI criteria Atp. safety on CLP) consumers data for of this sheet regulations. the hazard European 2022 not available class Parliament Effects on workers Workers 10. Route Regulation exposed of exposure (EU) to 2015/1221 this chemical Acute (VII agent Atp. Acute CLP) must of not the undergo European Chronic health Parliament checks, Chronic provided that Acute available local risk-assessment Acute data Chronic prove that Chronic the risks Use Kinematic Information

Disposal

jets of must viscosity water not be available to performed cool the containers through an to authorised prevent product waste not available management decomposition firm, and in the compliance development with of national substances and local 11.2. Name 3.2. health. potentially related 11. Information Solubility CONTAMINATED regulations. Mixtures Regulation to the workers' Always TITANIUM hazardous for (EU) wear PACKAGING on other 2016/918 full fire

Health hazards

DIOXIDE local and

Prevention

(VIII safety [in powder Atp. CLP) gear. Collect systemic are modest of the European form extinguishing and PASSIONE not containing that available 1 water local the Parliament 98/24/EC BEAUTY systemic % or to more S.P.A. directive is respected. prevent of particles it from draining with aerodynamic into the sewer diameter systemic system. Dispose local ≤ 10 systemic of Full 12. Oral Regulation address (EU) 2016/1179 (IX Atp. CLP) Viale Crispi 89-93 4,5 contaminated Partition Delayed Contaminated and coefficient: immediate water packaging used n-octanol/water μm] effects for must extinction be as well recovered as and chronic the or remains disposed effects not of available from of the in short fire compliance according and long-term with to applicable national exposure waste regulations. management regulations. 15.2. District Based 13. Chemical

Precautionary statements

or ID number protective equipment and emergency procedures 12.1. CAS ACUTE Toxicity TLV-ACGIH TOXICITY 67-63-0 0,2 RESP For (C) 21. Delegated = urgent CEILING inquiries Regulation ; INHAL refer to (UE) = Inhalable 2021/849 Fraction (XVII Atp. ; RESP CLP) +39 0444-239569 = Respirable Fraction ; THORA = Thoracic Fraction. REACH Block not applicable Flam. Reg. the leakage if there is no hazard. Liq. 2 01-2119457558-25-xxxx Flammable liquid, category 2 VND 22. Delegated 2-propenoic 9.2.1. ATE Carc. (Inhalation) = hazard Regulation Information 2 acid, identified but (UE) no 2022/692 of with the 2-methyl-, regard mixture: to polymer DNEL/PNEC Carcinogenicity, physical with (XVIII available ethyl Atp. CLP) ; NEA = no exposure expected ; NPI = no hazard identified ; LOW = low hazard category classes 2-propenoate 2 Not classified and methyl (no significant 2-methyl-2-propenoate component) Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent ; MED = medium hazard ; HIGH = high hazard. 14.2. any UN contamination SECTION INDEX ATE 2-propenoic - The Merck Index. - 10th Edition Eye (Oral) proper shipping Irrit. of 2. acid, mixture: 2-methyl-, identification of skin, name eyes and personal clothing. These indications apply for both processing staff and those involved in emergency polymer Eye irritation, 23,5 with ≤ ethyl x < category 2-propenoate 25 2 Eye Not and PROPAN-2-OL classified Irrit. methyl 2 H319, 2-methyl-2-propenoate (no significant Skin Irrit. component) 2 H315, Aquatic Chronic 4 H413 EC Threshold Information ATE LC50 Skin procedures. (Dermal) - for Irrit. Fish Limit not 2 of available 607-559-5 the Value mixture: Skin irritation, category 2 > 100 Not mg/l/96h classified (no significant component) 8.2. - Handling 2.1. CAS EC50 Exposure Chemical Type STOT - for SE Crustacea controls Safety 3 25133-97-5 of the Country substance Specific TWA/8h or mixture target organ toxicity > 100 STEL/15min - single mg/l/48h exposure, category Remarks 3 / Observations not - INRS applicable - Fiche Toxicologique (toxicological sheet) 6.2. Environmental precautions ETHYL 9.2.2. EC50 Aquatic - Other for ACETATE Algae Chronic safety / Aquatic characteristics 4 Plants Hazardous mg/m3 to the ppm aquatic > environment, 100 mg/m3 mg/l/72h chronic ppm toxicity, category 4 The As - Patty INDEX the use AGW H225 product - Industrial 2-propenoic of adequate is classified 607-022-00-5 Hygiene acid, DEU as 2-methyl-, technical and Toxicology hazardous Highly equipment must always take priority over personal protective equipment, make sure that the workplace is 500 polymer 8,5 flammable pursuant ≤ x < with 10 200 to ethyl liquid the 2-propenoate provisions and vapour. Flam. 1000 set Liq. and forth 2 400 methyl H225, in (EC) Eye 2-methyl-2-propenoate Regulation Irrit. 2 H319, Possibility of first and physical for PROTECTION hazardous aid measures Product classification derives from criteria established by the CLP Regulation, Annex I, Part 2. The data for reactions Causes - DNEL: skin

Additional information

- for Reg. Crustacea 01-2119475103-46-00XX FRA concerning Causes the skin risks irritation. for health 7550 and/or 980 mg/l/48h

Environmental hazards

Daphnia 400 magna are given in sections 11 and 12 of this sheet. 6.3. Methods and material for containment and cleaning up Provide - Database an emergency of SDS models shower for with chemicals face and - Ministry eye wash of Health station. and ISS (Istituto Superiore di Sanità) - Italy TITANIUM WEL H336 TITANIUM DIOXIDE DIOXIDE GBR [in powder [in May powder form 999 cause containing form drowsiness containing 400 1 % or or 1 dizziness. % more 1250 or more 10.1. 14.4. Reactivity of particles HAND PROTECTION of 500 Packing group particles with with aerodynamic aerodynamic diameter diameter ≤ 10 μm] INDEX ETHYL TLV-ACGIH H413 classification LD50 ACETATE (Oral): 022-006-00-2 and indication: May 492 0,708 cause ≤ long x < 200 lasting 0,808 harmful Carc. > 983 10000 effects 2 H351, mg/kg to 400 aquatic Classification Rat life note according to Annex VI to the CLP Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the Protect hands with category III work gloves Predicted LC50 Eye remainder There not applicable EUH066 for are no irritation, Fish with particular no-effect inert absorbent category concentration risks of material reaction with other substances in normal conditions of use Repeated PNEC exposure may cause 2125 Regulation mg/l/96h skin dryness H319 10, or V, cracking Causes serious eye irritation The Note following EC Chronic Skin Normal for users: should be considered when choosing work glove material (see standard EN 374): compatibility, degradation, failure time and PROPAN-2-OL irritation, NOEC value for 236-675-5 in category Fish fresh water 756 mg/l H315 Causes skin irritation 140,9 mg/l Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13 permeability The information in the sheet are based on our own knowledge on the last version must verify the ETHYL CAS Chronic Environmental Specific Normal LD50 ACETATE hazards NOEC value target contained Dermal) for 13463-67-7 in organ Crustacea marine toxicity water - present single exposure, 24 12800 mg/l mg/kg H336 Rat May date cause of the drowsiness 140,9 or Users dizziness mg/l The suitability LEGEND category Normal work gloves' LD50 value and thoroughness (Oral) for fresh water sediment resistance to of chemical provided information agents should according be checked 4710 mg/kg Rat to each before specific use, use as it of can the be product unpredictable. The gloves' wear time depends on 552 mg/kg/d Reference the This duration Decomposes document and must to other slowly sections type not of use into acetic acid and ethanol under the effect of light, air and water be regarded as a guarantee on any specific product property The ADR not Persistence Normal full European wording value and of for Agreement hazard marine degradability H) water concerning phrases sediment is the given carriage in section of Dangerous of the sheet goods by Road 552 mg/kg/d SKIN The applicable use PROTECTION of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health Any Health ATE: Acute information ETHYL Derived Toxicity stability ACETATE no-effect personal Estimate level - DNEL / DMEL protection and disposal and Wear and Chemical safety category elements laws II and on professional regulations long-sleeved The producer CAS Special precautions for user overalls is relieved Label Chemical is and given LD50 safety from in sections Oral) Abstract Service any footwear liability 8 (see Effects Number arising Regulation from improper on consumers 2016/425 uses and standard EN ISO 20344). Wash body 5620 mg/kg ratt Effects on workers with Provide TITANIUM CE50 Route Effective soap appointed of DIOXIDE and water staff exposure concentration after with removing in powder Acute (required adequate form containing protective training clothing Acute to induce 1 a % 50% on how to use chemical products or more Chronic effect) of particles Chronic with aerodynamic Acute diameter local Acute μm] Chronic SECTION The product is stable in normal conditions of use and storage EYE PROTECTION First SECTION Hazard SKIN Solubility CE: Identifier in ESIS (European not applicable CORROSION

2.2 Label elements

in 7. water Handling pursuant aid / IRRITATION to measures local EC and Regulation archive

Storage

systemic

Hazard pictograms

Derived irritation No safe Effect handling Level mg/kg bw/d 14.7. Maritime transport in bulk according to IMO instruments If evaluation the threshold of chemical-physical value (e.g. TLV-TWA) properties is exceeded are reported for the in section substance 9. or one of the substances present in the product, use a mask with a type PROPAN-2-OL - EmS: Inhalation Emergency Schedule EYES: The vapours Keep A Health filter away 89 whose Remove from class may contact Product heat, also form lenses, (1, sparks or 3) and explosive must naked if present. be is chosen mixtures Wash based flames; according with the immediately on do calculation not smoke air. to the methods 500 or limit use of matches with plenty of water for at least 15 minutes, opening the eyelids fully. If problem use as per concentration. Annex or lighters. I of CLP, (see Without Part standard adequate 3, unless EN 14387). ventilation, determined In the vapours otherwise presence may in of Section gases SERIOUS Rapidly - GHS: Globally persists, Information degradable seek not medical EYE DAMAGE relevant advice. Harmonized / IRRITATION System of classification and labeling of chemicals mg/m3 accumulate or 11. vapours of at various - IATA Skin DGR: International Air Transport Association Dangerous Goods Regulation ground kinds level and, and/or if ignited, gases or catch vapours fire even containing at a distance, particulate with (aerosol 319 the danger sprays, of backfire. fumes, mists, Avoid etc.) bunching combined of electrostatic filters are charges. 888 required. SKIN: ETHYL ACETATE When Respiratory Environmental performing Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash protection transfer devices Product operations must be involving used if is large the based technical containers, on calculation measures connect methods adopted to an earthing as are per not Annex system suitable I of and for CLP, restricting wear Part antistatic 4, the unless worker's footwear. determined exposure Vigorous otherwise to stirring the in 12.3. Causes - IC50: contaminated Bioaccumulative Risk of explosion Immobilization serious eye irritation clothing on before potential Concentration 50% contact using with: it again. alkaline metals,hydrides,oleum.May react violently with: fluorine,strong oxidising agents,chlorosulphuric mg/kg bw/d mg/kg SECTION and threshold Section - IMDG: International flow 12. through values considered. 15. Regulatory the tubes and The equipment Maritime Code information protection may for dangerous goods provided cause by the masks formation is in and any case accumulation limited. of electrostatic charges. In order to avoid the risk of bw/d INHALATION: acid,potassium substance Remove considered tert-butoxide.Forms to open air. In the is odourless explosive event of mixtures breathing with: difficulties, air. is higher fires If the and RESPIRATORY - IMO: International OR Maritime get medical advice/attention immediately. explosions, SKIN SENSITISATION never use Organization compressed or its air olfactory when handling. threshold Open containers than the with corresponding caution as they TLV-TWA may be and pressurised. in the case Do of not an eat, drink or 10.4. INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious smoke emergency, Changes Conditions during to previous wear to use. open-circuit avoid Avoid review: leakage compressed of the product air breathing into the environment. apparatus (in compliance with standard EN 137) or external air-intake breathing PROPAN-2-OL - INDEX: Identifier in Annex VI of CLP person, unless authorised by a doctor. 15.1. apparatus The Safety, Does Partition - LC50: not Lethal following coefficient: meet Concentration (in health compliance sections and environmental n-octanol/water were with modified: 50% criteria for this hazard class 0,05 standard regulations/legislation EN 138). For a correct choice specific of respiratory for the substance protection or device, mixture see standard EN 529. 7.2. Signal Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. ENVIRONMENTAL 01 Conditions / 08 words: / 11 / 12. for safe EXPOSURE storage, Warning including CONTROLS any incompatibilities 4.2. Most important symptoms and effects, both acute and delayed - LD50: Lethal dose 50% The Seveso GERM ETHYL - OEL: Occupational emissions CELL ACETATE Category generated MUTAGENICITY - Directive by 2012/18/EU: Exposure Level manufacturing processes, including None those generated by ventilation equipment, should be checked to ensure ETHYL ACETATE Store compliance only in with the environmental original container. standards. Store the containers sealed, in a well ventilated place, away from direct sunlight. Store in a cool and well Partition

Hazard categories

of dangerous goods by train Precautionary Information not statements: available ... / >> P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P280 Wear protective gloves / eye protection / face protection. P312 Call a POISON CENTRE / doctor / . . . if you feel unwell. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P264 Wash . . . thoroughly after handling.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures