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Hazard statements (CLP)

H225, H302, H314, H315, H317, H318, H319, H320, H332, H334, H335, H336, H351, H370, H372, H373, H402, H413

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA In Case of Emergency Contact INFOTRAC 800-535-1035 Classification of the HAZARD Substance IDENTIFICATION or Mixture HAZARD IDENTIFICATION Acute Toxicity: Inhalation, Category 4 GHS Classification GHS Section Classification HAZARD IDENTIFICATION Skin Corrosion/Irritation, Category 2 GHS Classification Category 2A SIGNAL Serious Eye Damage/Eye Irritation, SIGNAL CATEGORY HAZARD STATEMENT(S) CATEGORY WORD HAZARD STATEMENT(S) Respiratory Sensitization, Category WORD CATEGORY SIGNAL HAZARD STATEMENT(S) Skin Sensitization, Category 1 WORD Physical Label Flammable Flammable Liquids, Category 2 Elements Physical Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor Flammable Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor Health Acute Oral Toxicity, Category 4 Acute Acute Oral Oral Toxicity, Toxicity, Category Category 4 4 WARNING H302 – Harmful if swallowed WARNING WARNING H302 H302 Harmful if swallowed Skin GHS Skin Skin Corrosion,

Signal word

Corrosion, Corrosion, Category Category 1 Danger WARNING H314 – Causes severe skin burns and eye damage WARNING WARNING H314 H314 Causes severe severe skin burns skin and burns eye damage and eye damage Serious Eye Damage, Category 1 Serious Serious Eye Eye Damage, Damage, Category Category 1 1 WARNING WARNING H318 – Causes serious eye damage WARNING H318 H318 Causes serious serious eye damage Hazard-determining Skin Sensitization, Category 1 Skin Sensitization, components Category 1 of labelling WARNING H317 – May cause an allergic skin reaction WARNING H317 – May cause an allergic skin reaction Skin Sensitization, Castor STOT SE, Category Category 3 1 diisocyanate WARNING WARNING H317 H335 – – May May cause cause a respiratory an allergic irritation skin reaction STOT SE, Category 3 STOT oil, SE, 4,4-diphenylmethane Category 3 WARNING H335 – May cause a respiratory irritation WARNING polymer H335 – May cause a respiratory irritation Methylenebis(phenylisocyanate) Environmental GHS Environmental Hazard Acute, Category Phrases H402 – Harmful to aquatic life Acute, H315 Category Acute, Chronic, Causes 3 skin irritation Category Category 3 4 H402 – Harmful to aquatic life H413 H402 May – cause Harmful long to lasting aquatic harmful life effects to aquatic Chronic, H317 Category Chronic, Category 4 May cause 4 an allergic skin reaction H413 – May cause long lasting harmful effects to aquatic life H413 – May cause long lasting harmful effects to aquatic life H319 - Causes serious eye irritation H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled GHS Precautionary Phrases P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 GHS Wash Precaution hands Statements thoroughly after handling P271 Prevention Use only outdoors or in a well-ventilated area GHS Precaution Statements P272 P210 Contaminated Keep away work from clothing heat/sparks/open should not flames/hot be allowed surfaces out of No the smoking workplace GHS Precaution P280 - Wear protective gloves/protective clothing/eye protection/face protection P261 – Avoid Statements breathing dust/fume/mist/vapors/spray Prevention P264 – Wash hands (or other affected skin surfaces) thoroughly after handling P284 - Wear respiratory protection P210 – Keep away from heat/sparks/open flames/hot surfaces. No smoking GHS Response Phrases P261 – Avoid breathing dust/fume/mist/vapors/spray P302+352 - IF ON SKIN: Wash with plenty of soap and water P264 – Wash hands (or other affected skin surfaces) thoroughly after handling P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Section P312 1 - Call IDENTIFICATION a POISON CENTER or doctor/physician if you feel unwell P332+313 - If skin irritation occurs, get medical advice/attention P333+313 - If skin irritation or rash occurs, seek medical advice/attention Product Name: UL8110, UL8120 Acrylic Structural Bonding Adhesive Cartridges P337+313 - If eye irritation persists, get medical advice/attention Manufacturer P342+311 - If Chemical experiencing Concepts, respiratory Inc. symptoms call a POISON CENTER or doctor/physician P362+364 - Take 410 off Pike contaminated Road clothing and wash it before reuse GHS Storage Huntingdon and Disposal Valley, Phrases PA. 19006 P501 - Dispose Phone of contents/container 800.220.1966 to local state and federal regulations Email: sales@chemical-concepts.com Website: www.chemical-concepts.com UFI Information department: Environment protection department Adverse Human Health Hazards not otherwise classified (HNOC) or not covered by GHS -none Effects and Symptoms Materials Uses: Bonding Section and 3. Adhering Composition/Information various plastic surfaces, fiberglass on Ingredients surfaces, gel coat, and various metals, including aluminum, steel, and stainless steel CAS # Hazardous Components (Chemical Name)/ Concentration EC No./ GHS Classification In Case of Emergency Contact: INFOTRAC: 800-535-1035 REACH Registration No EC Index No 68424-09-9 Castor oil, 4,4-diphenylmethane diisocyanate 60.0 -80.0 % NA Skin Corr. 2: H315 polymer NA Eye Damage 2A: H319 HAZARD IDENTIFICATION Acute Tox.(I) 4: H332 GHS Classification Resp. Sens. 1: H334 STOT (SE) 3: H335 H336 14807-96-6 Talcum SIGNAL 238-877-9 STOT (SE) 1: H370 CATEGORY HAZARD 10.0 -30.0 STATEMENT(S) 01-2120140278-58 WORD NA STOT (RE) 1: H372 101-68-8 Methylenebis(phenylisocyanate) 5.0 % Physical 202-966-0 Skin Corr. 2: H315 01-2119457014-47 Flammable Liquids, Category 2 615-005-00-9 Skin Sens. 1: H317 DANGER H225 – Highly flammable liquid and vapor Eye Damage 2A: H319 Acute Tox.(I) 4: H332 Health Resp. Sens. 1: H334 Acute Oral Toxicity, Category 4 STOT (SE) 3: H335 WARNING H302 – Harmful if swallowed Skin Corrosion, Category 1 Carcinogen 2: H351 WARNING H314 – Causes severe skin burns and eye damage Serious Eye Damage, Category 1 STOT (RE) 2: H373 WARNING H318 – Causes serious eye damage Skin Sensitization, Category 1 First Aid Measures WARNING H317 – May cause an allergic skin reaction STOT SE, Category 3 WARNING H335 – May cause a respiratory irritation Description of First Aid Move out of dangerous area Environmental Measures Acute, In Case Category of Inhalation Remove victim to fresh air H402 and provide Harmful oxygen to aquatic if breathing life is difficult. Give artificial Chronic, Category 4 respiration if not breathing H413 and seek May medical cause help long immediately lasting harmful Asthmatic-type effects to aquatic symptoms may develop and life may be immediate or delayed up to several houts In Case of Skin Remove contaminated clothing or shoes, wipe excess from skin. Wash with soap and Contact plenty of water (warm water is preferable if readily available) In Case of Eye Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids Contact open and seek medical attention In Case of Ingestion: Do not give any liquids (do not induce vomiting). Get medical help immediately Important Symptoms The most important known symptoms and effects are described in the labelling (see and Effects, Both 2) and/or in section 11 GHS Precaution Statements Acute and Delayed Prevention Indication of any P210 – Keep away from heat/sparks/open flames/hot surfaces. No smoking No data available P261 – Avoid breathing dust/fume/mist/vapors/spray immediate medical P264 – Wash hands (or other affected skin surfaces) thoroughly after handling attention and special treatment needed IDENTIFICATION Fire Fighting Measures Suitable Extinguishing Use Dry Chemical, Carbon Dioxide, Foam, or Water Fog. For large fires, alcohol Product Name: UL8110, UL8120 Acrylic Structural Bonding Adhesive Cartridges Media resistant foams (including AFFF) or protein foams may function but much less effectively Manufacturer Chemical Concepts, Inc Water is not recommended but may be applied in very large quantities as a fine spray 410 Pike Road when other extinguishing media are not available Flammable Properties Huntingdon No Valley, data available PA. 19006 and Hazards: Phone: 800.220.1966 Email: sales@chemical-concepts.com Website: www.chemical-concepts.com No data available Information department: Environment protection department Flash Pt 204.4 C (> 400.00 F) Method Used: Estimate Explosive Limits LEL: No data UEL: No data Autoignition Pt No data Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and Fire Fighting Full emergency equipment with self-contained breathing apparatus and full protective various metals, including aluminum, steel, and stainless steel Instructions clothing should be worn by fire fighters In Case of Emergency Contact: INFOTRAC: 800-535-1035 Do not enter a confined space without full bunkjer gear, including a positive pressure NIOSH approved self-contained breathing apparatus. During fire, irritating and toxic HAZARD IDENTIFICATION gases may be generated by thermal decompostion or combustion. Product reacts with water. Reaction may produce heat and/or gases GHS Classification Accidental Release Measures SIGNAL CATEGORY Protective Precautions, Remove all sources of ignition WORD HAZARD and STATEMENT(S) ventilate the area Protective Equipment Physical and Emergency Flammable Procedures Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor Environmental Dike and contain spilled material and control further spillage if feasible. Cover spill with Precautions clay, sand, saw dust, vermiculite, Fuller's earth or other suitable absorbent Health Methods and Material Acute Oral Toxicity, Category 4 Collect material in non-leaking containers and seal tightly for disposal. Attempt to WARNING H302 – Harmful if swallowed Skin Corrosion, Category 1 For Containment and neutralize by adding a mixture of: water(80%) with non-ionic surfactant Tergitol WARNING H314 – Causes severe skin burns and eye damage Serious Cleaning Eye Damage, Up Category TMN-10(20%), WARNING or water(90%), H318 concentrated Causes serious ammonia(3-8%) eye damage and detergent(2%). Add Skin Sensitization, Category about parts WARNING of neutralizer H317 per – part May of cause isocyanate an allergic while skin mixing reaction Allow to stand STOT SE, Category 3 uncovered WARNING for 48hours to H335 let CO2 – May escape cause If ammonia a respiratory is used, irritation use good ventilation to prevent vapor exposure. Large quantities may be pumped into closed, but not sealed Environmental containers. Refer to section 13 for disposal information Acute, Category 3 H402 – Harmful to aquatic life Chronic, Category 4 Handling H413 – May and cause Storage long lasting harmful effects to aquatic life Precautions To Be Handle in accordance with good industrial hygiene and safety practices. These practices Taken in Handling include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Employee education and training in the safe use and handling of this material Warning

UN Number

Packing Group III

Hazard categories

Materials MARINE Uses: TRANSPORT Bonding and IMDG/IMO) Adhering various plastic surfaces, fiberglass surfaces, gel coat, and various IMDG/IMO metals, Shipping including Name: aluminum, Not a dangerous steel, and good stainless in sense steel of this transport regulation In UN Case Number of Emergency Contact: INFOTRAC: 800-535-1035 Packing Group III AIR TRANSPORT (ICAO/IATA) HAZARD IDENTIFICATION ICAO/IATA Shipping Name Not a dangerous good in sense of this transport regulation GHS UN Classification Number Packing Group III SIGNAL CATEGORY HAZARD STATEMENT(S) Section WORD Regulatory Information EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists Physical CAS # Flammable Liquids, Category 2 Hazardous Components (Chemical Name) DANGER H225 – Highly flammable liquid and vapor S. 302 (EHS) S. 304 RQ S. 313 (TRI) 68424-09-9 Castor oil, 4,4-diphenylmethane diisocyanate No polymer 14807-96-6 Health Talcum No Acute Oral Toxicity, Category 4 WARNING H302 – Harmful if swallowed 101-68-8 Methylenebis(phenylisocyanate) No Skin Corrosion, Category 1 Yes NA Yes-Cat. N120 (5%) WARNING H314 – Causes severe skin burns and eye damage This Serious material Eye meets Damage, the EPA Category 'Hazard 1 Categories' WARNING defined H318 for – SARA Causes Title serious III Sections eye damage 311/312 as indicated ] Yes [X] No Explosive Skin Sensitization, Category 1 WARNING H317 – May cause an allergic skin reaction X] Yes [ ] No Acute toxicity (any route of exposure) ] Yes [X] No Flammable (gases, aerosols, liquid, or solid) STOT SE, Category 3 X] Yes [ ] No Skin Corrosion or Irritation WARNING H335 – May cause a respiratory irritation ] Yes [X] No Oxidizer (liquid, solid or gas) X] Yes [ ] No Serious eye damage or eye irritation ] Yes [X] No Self-reactive Environmental X] Yes [ ] No Respiratory or Skin Sensitization ] Yes [X] No Pyrophoric (liquid or solid) ] Yes [X] No Germ cell mutagenicity Acute, Category 3 H402 – Harmful to aquatic life ] Yes [X] No Pyrophoric gas ] Yes [X] No Carcinogenicity ] Yes Chronic, X] No Category Self-heating 4 H413 ] Yes – May X] No cause Reproductive long lasting toxicity harmful effects to aquatic ] Yes [X] No Organic peroxide life [ ] Yes [X] No Specific target organ toxicity (single or repeated exposure) ] Yes [X] No Corrosive to metal ] Yes [X] No Aspiration Hazard ] Yes [X] No Gas under pressure (compressed gas) ] Yes [X] No Simple Asphyxiant ] Yes [X] No In contact with water emits flammable gas ] Yes [X] No (Health) Hazard Not Otherwise Classified (HNOC) ] Yes [X] No Combustible Dust ] Yes [X] No (Physical) Hazard Not Otherwise Classified (HNOC) CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 68424-09-9 Castor oil, 4,4-diphenylmethane diisocyanate TSCA: Yes - Inventory: Active; CA PROP.65: No polymer GHS Precaution Statements 14807-96-6 Talcum TSCA: Yes - Inventory: Active/Exempt; CA PROP.65: No Prevention 101-68-8 P210 – Keep away from heat/sparks/open flames/hot surfaces. No smoking Methylenebis(phenylisocyanate) TSCA: Yes - Inventory: Active/Exempt, 8C; CA PROP.65: No CAS P261 # – Avoid Hazardous breathing Components dust/fume/mist/vapors/spray Chemical Name) International Regulatory Lists 68424-09-9 P264 – Wash Castor hands oil, (or 4,4-diphenylmethane other affected skin diisocyanate surfaces) thoroughly REACH: after Yes - handling P) polymer 14807-96-6 Talcum IDENTIFICATION REACH: Yes - 01-2120140278-58: Full, (P) 101-68-8 Methylenebis(phenylisocyanate) REACH: Yes - 01-2119457014-47: Full, (P) Regulatory Information Product Name: UL8110, UL8120 Acrylic Structural Bonding Adhesive Cartridges Under applicable definitions, the product is considered to be an immediate health hazzard, a delyed health hazzard, and a reactive hazard Manufacturer Chemical Concepts, Inc 410 Pike Road

2.2 Label elements

WORD Physical Flammable Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor

Hazardous Ingredients

Acute Oral Toxicity, Category 4 WARNING H302 – Harmful if swallowed Skin Corrosion, Category 1

Hazard statements

WARNING H314 – Causes severe skin burns and eye damage Serious H315 Eye - Causes Damage, skin Category irritation. 1 WARNING H318 – Causes serious eye damage Skin H320 Sensitization, - Causes Category eye irritation. 1 WARNING H317 – May cause an allergic skin reaction STOT H335 SE, - Category May cause 3 respiratory irritation. WARNING H335 – May cause a respiratory irritation

Precautionary statements

Environmental P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. Acute, Category 3 H402 – Harmful to aquatic life P264 - Wash hands thoroughly after handling. Chronic, Category 4 H413 – May cause long lasting harmful effects to aquatic P280 - Wear protective gloves/protective clothing/eye protection/face protection. life P232 - Protect from moisture. P233 - Keep container tightly closed. Statements P332+313 - If skin irritation occurs, get medical advice/attention. P337+313 - If eye irritation persists, get medical advice/attention.

Response

P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+352 - IF ON SKIN: Wash with plenty of soap and water. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Prevention

P342+311 - If experiencing respiratory symptoms call a POISON CENTER or doctor/physician. P210 – Keep away from heat/sparks/open flames/hot surfaces. No smoking. P261 – Avoid breathing dust/fume/mist/vapors/spray.

Storage

P264 – Wash hands (or other affected skin surfaces) thoroughly after handling. P403+235 - Store in cool/well-ventilated place. P404 - Store in a closed container. P501 - Dispose of contents/container to Federal State/Provincal and local governmental regulations.. Section

2.1 Classification of the substance or mixture

GHS Classification: GHS Section Classification: 2 HAZARD IDENTIFICATION Skin Corrosion/Irritation, Category 2 GHS Classification: Category 2A SIGNAL Serious Eye Damage/Eye Irritation, SIGNAL CATEGORY HAZARD STATEMENT(S) CATEGORY WORD HAZARD STATEMENT(S) Respiratory Sensitization, Category WORD CATEGORY 1 SIGNAL HAZARD STATEMENT(S) Skin Sensitization, Category 1 WORD Physical 2.2 Label Flammable Flammable Liquids, Category 2 Elements: Physical Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor Flammable Liquids, Category 2 DANGER H225 – Highly flammable liquid and vapor