Azoxystrobin 25% SC

SECTION 2: Hazards identification

If swallowed, it may cause nausea, vomiting and abdomen pain. If inhaled as a fine dust it may cause irritation to the bronchial and lung tissues. 4. FIRST AID MEASURES If Ingested If swallowed, induce vomiting by tickling at the back of the back of the throat with the finger. Immediately seek medical advice. Eye contact Immediately flush the contaminated eye with lukewarm water, gently flowing for 20 minutes or until the product is removed. Take care not rinse contaminated water into the unaffected eye or onto the face. Special care should be taken when the exposed person is wearing contact lenses. Skin Contact Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes or until product is removed. Under running water remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat flushing and seek medical advice. Inhalation Move affected person to fresh air. If breathing is difficult give artificial respiration. Get medical attention. Note to Physician No specific antidote. Treat symptomatically and give supportive therapy. 5. FIRE FIGHTING MEASURES Flammability Extinguishing Media Special Fire Fighting Procedures Not flammable Carbon dioxide, foam, dry powders and Water spray Firefighters should wear NIOSH/ MSHA approved self-contained breathing apparatus and full protective clothing. Persons who may have been exposed to contaminated smoke should be immediately examined by a physician and checked for symptoms of poisoning. Use dry chemical, foam or CO2 extinguishing media. All nonessential personnel should be evacuated from the affected area to prevent human exposure to fire, smoke, fumes or products of combustion. Prevent use of contaminated buildings, area, and equipment until decontaminated. Water run-off can cause environmental damage. If water is used to fight fire, dike and collect run-off. Carbon and nitrogen oxides, hydrochloric gas are expected to be produced. Decomposition Products Carbon and nitrogen oxides, hydrochloric gas are expected to be produced. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear appropriate safety clothing and eye/face protection. Environmental precautions Do not wash into sewers or into any water body. Methods for cleaning up the Wear protective equipment. Clear area of all un protective personnel. Prevent spills entry of chemical or used/ damaged containers into drains, streams or waterways. For small spill apply absorbent material such as earth, sand, clay granules or cat litter to the spill. Sweep up material when absorption is completed and contain in a refuse vessel for disposal. For large spills, place leaking container into salvage drums. Apply absorbent material such as earth, sand, clay granules to the spill. Form a barricade around spill and in front of drains or waterways in spill vicinity, using earth or other available material. Sweep up material contain in a refuse vessel for disposal. 7. HANDLING AND STORAGE Handling Use good personal hygiene. Do not consume or store food in the work area. Wash hands and exposed skin before eating, drinking or smoking and after work. Avoid breathing vapours. Avoid eye contact. Do not eat drink or smoke while using this product. Storage Store in a cool, dry, well-ventilated place in the original container. Protect from excessive heat and cold. Do not store near food, drink, and animal feeding stuffs, pharmaceuticals, cosmetics or fertilizers. Keep out of reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Ensure work areas have ventilation, containment and procedure to maintain airborne levels below the TLV. Warehouses, production area and waste holding facilities should have containment to prevent environmental contamination. Ingestion Do not eat, drink or apply cosmetics, where there is a potential for exposure to the product. Eyes protection Safety goggles, chemical splash goggles or face shield for eye protection should be used. Safety showers and eyewash should be easily accessible. Skin protection Chemical resistant gloves, coveralls, socks, apron and chemical resistant foot coverings should always be used while handling the product. Respiratory protection Always use NIOSH/MSHA approved respiratory protection equipment with a universal filter type including particle filter. General Protection Avoid contact with eyes and skin. While handling the product, wear cotton overalls buttoned to the neck and wrist and washable hat, elbow-length PVC gloves and face shield. After use and before eating drinking or smoking, wash hands, arms and face thoroughly with soap and water. After each day’s use, wash gloves, face shield and contaminated clothing.