D1

PAGEL Spezial-Beton GmbH & Co. KG

Revision date : 2017-07-07

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

238-878-4/14808-60-7

Name of the chemical

Silica, crystalline

Concentration

< 75

General Information

Revision date

2017-07-07

Product name

D1

CAS No.

not

REACH No

Not

Icons in SDS

GHS05 GHS07

Company Information

company name

PAGEL Spezial-Beton GmbH & Co. KG

e-mail address of the competent person responsible for the Safety Data Sheet

info@pagel.com, schempershofe@pagel.de, labor@pagel.de

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H318, H335

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

Classifications

Section

Hazard categories

Category Hazard state ment 3.2 skin corrosion/irritation 2 Skin Irrit. 2 H315 3.3 serious eye damage/eye irritation 1 Eye Dam. 1 H318 D1 Category Hazard state ment 3.8R specific target organ toxicity - single expos- 3 STOT SE 3 H335 ure (respiratory tract irritation) For full text of abbreviations: see SECTION 16

2.1 Classification of the substance or mixture

Section

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word

danger

Hazard pictograms

GHS05, GHS07

Hazard statements

H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P261 Avoid breathing dust. P280 Wear protective gloves/protective clothing/eye protection/face protection/hear- ing protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/doctor. P501 Dispose of contents/container in accordance with local/regional/national/interna- tional regulations.

Hazardous Ingredients

portland cement flue dust, portland cement

2.3 Other hazards

The product develops an alkaline pH value with moisture and can cause irritation. The product contains chromate reducer, which results in a content of water-soluble chrome (VI) of less than 0.0002 %. In case of improper storage (moisture ingress) or storage exceeding the recommen- ded storage time, however, the contained chromate reducer may lose its effect prematurely and a sensitising effect of the cement/binder can occur upon skin contact (H317 and EUH203). The preparation is low in chromium. The content of soluble chromium (VI) compounds has been lowered with agent to below 2 ppm in the cement portion. Proper storage and compliance with the ex- D1 piration date is a prerequisite for the effectiveness of the chromate reduction.

Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

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