TOP-TIER ADHESIVE Part A ISOC YANATE

Hazard statements (CLP)

H315, H317, H320, H332, H334, H335, H372

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Acute Toxicity (Inhalation), Category 4 Target Organ Toxicity (Single exposure), Category 3 Respiratory Sensitization, Category 1 Target Organ Toxicity (Repeated exposure), Category 1 Skin Iritation, Category 2 Skin Sensitization, Category 1 Eye Irritation, Category 2

2.2 Label elements

According to Requlation 2012 HA Hazard Communications Standard 29 CER Part

Health hazards

mark

Signal word

DANGER

Hazard statements

H315: Causes skin imitation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. H372: Causes damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.

Prevention

P261: Avoid breathing dust/fume/gas/mistWvapors/spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P285: In case of inadequate ventilation wear respiratory protection. Res ponse: P314: Get medical advice/attention if you feel unwell. P302+P350 IF ON SKIN Gently wash with plenty of soap and water P332+P313: If skin irritation occurs: Get medical advice/attention. P363: Wash contaminated clothing before reuse. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye imitation persists: Get medical advice /attention. P304+P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342: If experiencing respiratory symptoms: Call a doctor or emergency medical facility (i.e. 911).

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents/container in accordance with local/regionaVnationalAnternational regulation. EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Clear straw color liquid. IMMEDIATE CONCERNS CAUTION Contains DIPHENYLMETHANE DIISOCYANATE (CAS no. 101-68-8). Inhalation of MDI mists or vapors may cause respiratory irritation, breathlessness, chest discomfort and reduced pulmonary function. Overexposure well above the PEL may result in bronchitis, bronchial spasms and pulmonary edema. Long-term exposure to isocyanates has been reported to cause lung damage, including reduced lung function which may be permanent. Acute or Chronic overexposure to isocyanates may cause sensitization in some individuals, resulting in allergic respiratory reactions including wheezing, shortness of breath and difficulty breathing.

Potential health effects

EYES: May cause significant irritation to the eyes. SKIN: Allergic reaction and significant irritation to the skin is possible. INGESTION: May cause significant irritation to the digestive tract. INHALATION: Irritating to the nose, throat and respiratory tract.

Medical Conditions Generally Aggravated by Exposure

Individuals who are sensitized to isocyanates and those with asthma, respiratory disorder, skin allergies, and eczema. SENSITIZATION: Possible sensitizer by inhalation and skin contact.