Winsteard’s Reagent

Hazard statements (CLP)

H225, H290, H302, H314, H317, H318, H335, H370

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flammable liquids (Category 2), H225 in accordance with Corrosive to metals (Category 1), H290 29 CFR 1910 Acute toxicity, Oral (Category 4), H302 (OSHA HCS) Skin corrosion (Category 1B), H314 Skin sensitization (Category 1), H317 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - single exposure (Category 1), H370

Signal word

Danger

Hazard statements

Hazard Statement(s): H225 - Highly Flammable liquid and vapor H290- May be corrosive to metals H302- Harmful if swallowed H314- Causes severe skin burns and eye damage H317- May cause an allergic skin reaction H318- Causes serious eye damage H335- May cause respiratory irritation H370- Causes damage to organs

Precautionary statements

Precautionary Statement(s):

Prevention

P210-Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233- Keep container tightly closed. P234- Keep only in original container. P240- Ground/bond container and receiving equipment. P241- Use explosion-proof electrical/ventilating/lighting/equipment. P242- Use only non-sparking tools. P243- Take precautionary measures against static discharge. P260- Do not breathe dust/fume/gas/mist/vapors/spray. P261-Avoid breathing dust/fume/gas/mist/vapors/spray. P264- Wash skin thoroughly after handling. P270- Do not eat, drink or smoke when using this product. P271-Use only outdoors or in a well-ventilated area. P272-Contaminated work clothing should not be allowed out of the workplace. P280- Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301+312- IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P301+P330+P331- IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352- IF ON SKIN: wash with plenty of soap and water. P303+ P361+P353- IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304+P340-IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307+P311- IF exposed: call a POISON CENTER or doctor/physician. P310- Immediately call a POISON CENTER or doctor/physician. P312-Call a POISON CENTER or doctor/physician if you feel unwell. P321- Specific treatment (see Section 4 SDS). P330- Rinse mouth. P333+P313-IF SKIN irritation or rash occurs: Get medical advice/attention. P363-Wash contaminated clothing before reuse. P370+P378- In case of fire: Use dry chemical, CO2 or appropriate foam for extinction. P390- Absorb spillage to prevent material damage.

Storage

P403+P233- Store in a well-ventilated place. Keep container tightly closed. P403+P235- Store in a well-ventilated place. Keep cool. P405- Store locked up. P406- Store in corrosive resistant container with a resistant inner liner.

Disposal

P501- Dispose of contents/container to Federal, State and Local Regulations. Hazards not Explosive when dry. otherwise classified or not covered by GHS Emergency Overview -------------------------- DANGER! KEEP WET. EXPLOSIVE IF DRY. FLAMMABLE SOLID. CAUSES SEVERE EYE IRRITATION. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY CAUSE ALLERGIC SKIN REACTION. AFFECTS LIVER, KIDNEYS AND BLOOD. POISON! DANGER! MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. VAPOR HARMFUL. FLAMMABLE! AFFECTS CENTRAL NERVOUS SYSTEM. MAY CAUSE BLINDNESS. CANNOT BE MADE NONPOISONOUS. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY AFFECT LIVER, BLOOD, REPRODUCTIVE SYSTEM. -----------------------------------------------------------------------------------------------------------

Potential health effects

Inhalation: Causes irritation mucous membranes of the upper respiratory tract. Symptoms may include coughing, shortness of breath. Systemic poisoning can cause headache, dizziness, nausea, vomiting, abdominal pain and diarrhea. Heavy exposures can cause red blood cell destruction resulting in bloody urine, liver and kidney damage, convulsions, weakness, muscle pain, coma and death. Ingestion: Causes irritation to the gastrointestinal tract, headaches, gastritis, intoxication, blindness and, in acute cases, death. Symptoms may include nausea, vomiting and diarrhea. Other symptoms may parallel those from inhalation. Ingestion of 1 to 2 grams has caused severe poisoning. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. May cause allergic skin reactions. May be absorbed through the skin with possible systemic effects. Eye Contact: Can cause eye irritation. Splashes may cause temporary pain and blurred vision. Chronic Exposure: Prolonged or repeated exposures can cause liver, kidney and blood effects. Hair and skin may become yellow (not jaundice). Conjunctiva of the eye may also become yellow with corresponding yellow vision. Prolonged skin contact causes drying and cracking of skin. Continued ingestion of small amounts could result in blindness. Aggravation of Pre-existing Conditions: Persons with pre-existing skin, blood, liver and kidney disorders may be more susceptible to the effects of this substance.