Waterless Kalling’s Reagent

Hazard statements (CLP)

H225, H302, H312, H315, H318, H370, H400, H401, H411

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

Flammable liquids (Category 2), H225 in accordance with Acute toxicity, Oral (Category 4), H302 29 CFR 1910 Acute toxicity, Dermal (Category 4), H312 (OSHA HCS) Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 1), H370 Acute aquatic toxicity (Category 1), H400 Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 2), H411

Signal word

Danger

Hazard statements

Hazard Statement(s): H225- Highly Flammable liquid and vapor H302- Harmful if swallowed H312- Harmful in contact with skin H315- Causes skin irritation H318 - Causes serious eye damage H370- Causes damage to organs H401- Toxic to aquatic life H411- Toxic to aquatic life with long lasting effects

Precautionary statements

Precautionary Statement(s):

Prevention

P210-Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233- Keep container tightly closed. P240- Ground/bond container and receiving equipment. P241- Use explosion-proof electrical/ventilating/lighting/equipment. P242- Use only non-sparking tools. P243- Take precautionary measures against static discharge. P260- Do not breathe dust/fume/gas/mist/vapors/spray. P264- Wash skin thoroughly after handling. P270- Do not eat, drink or smoke when using this product. P273- Avoid release to the environment. P280- Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301+312- IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+352- IF ON SKIN: wash with plenty of soap and water. P303+ P361+P353- IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307+P311- IF exposed: call a POISON CENTER or doctor/physician. P310- Immediately call a POISON CENTER or doctor/physician. P312- Call a POISON CENTER or doctor/physician if you feel unwell. P321- Specific treatment (see Section 4 SDS). P322- Specific measures (see Section 4 SDS). P330- Rinse mouth. P363- Wash contaminated clothing before reuse. P370+P378- In case of fire: Use dry chemical, CO2 or appropriate foam for extinction. P391- Collect spillage. Hazardous to the aquatic environment

Storage

P403+P235- Store in a well-ventilated place. Keep cool. P405- Store locked up. Color Code Red (Flammable) , White (Corrosive) -----------------------------------------------------------------------------------------------------------

Disposal

P501- Dispose of contents/container to Federal, State and Local Regulations. Emergency Overview -------------------------- POISON! DANGER! MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. VAPOR HARMFUL. FLAMMABLE! AFFECTS CENTRAL NERVOUS SYSTEM. MAY CAUSE BLINDNESS. CANNOT BE MADE NONPOISONOUS. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY AFFECT LIVER, BLOOD, REPRODUCTIVE SYSTEM. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating: 3 - Severe (Poison) Flammability Rating: 3 - Severe (Flammable) Reactivity Rating: 1 - Slight Contact Rating: 3 - Severe (Life and Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER

Potential health effects

Inhalation: Copper Chloride - Causes irritation to respiratory tract, symptoms may include coughing, sore throat, and shortness of breath. May result in ulceration and perforation of respiratory tract. When heated, this compound may give off copper fume, which can cause symptoms similar to the common cold, including chills and stuffiness of the head. Denatured Alcohol - Exposure may cause irritation to the mucous membranes of the upper respiratory tract. Prolonged exposures to high concentrations may cause drowsiness, loss of appetite and inability to concentrate. Ingestion: Copper Chloride - May cause burning pain in the mouth, esophagus, and stomach. Hemorrhagic gastritis, nausea, vomiting, abdominal pain, metallic taste, and diarrhea may occur. If vomiting does not occur immediately systemic copper poisoning may occur. Symptoms may include capillary damage, headache, cold sweat, weak pulse, kidney and liver damage, central nervous excitation followed by depression, jaundice, convulsions, blood effects, paralysis and coma. Death may occur from shock or renal failure. Denatured Alcohol - Cause headaches, gastritis, intoxication, blindness and, in acute cases, death. Copper Chloride - Causes irritation, redness, and pain. Some individuals may develop copper allergies. Denatured Alcohol - Causes skin irritation, cracking or flaking due to dehydration and defatting action. Eye Contact: Copper Chloride - Causes severe irritation with symptoms of redness, pain, blurred vision, discoloration, and possible eye damage. Denatured Alcohol - Can cause eye irritation. Splashes may cause temporary pain and blurred vision. Chronic Exposure: Copper Chloride - Prolonged or repeated skin exposure may cause dermatitis. Prolonged or repeated exposure to dusts of copper salts may cause discoloration of the skin or hair, blood and liver damage, ulceration and perforation of the nasal septum, runny nose, metallic taste, and atrophic changes and irritation of the mucous membranes. Denatured Alcohol - Prolonged skin contact causes drying and cracking of skin. May affect the nervous system. May affect liver, blood, reproductive system. Continued ingestion of small amounts could result in blindness. Aggravation of Pre-existing Conditions: Copper Chloride - Persons with pre-existing skin disorders, impaired liver, kidney, or pulmonary function, glucose 6-phosphate-dehydrogenase deficiency, or pre-existing Wilson's disease may be more susceptible to the effects of this material. Denatured Alcohol - Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance.