Schantz’s Reagent

Hazard statements (CLP)

H290, H302, H304, H314, H318, H330, H335, H350, H370, H401

Code

Statements

H290

May be corrosive to metals

2.1 Classification of the substance or mixture

Corrosive to metals (Category 1), H290 in accordance with Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 1) H330 29 CFR 1910 (OSHA HCS) Skin corrosion (Category 1B), H314 Serious eye damage (Category 1), H318 Carcinogenicity (Category 1) H350 Specific target organ toxicity - single exposure (Category 1), Respiratory system, H370 Acute aquatic toxicity (Category 2), H401

Signal word

Danger

Hazard statements

Hazard Statement(s): H290 - May be corrosive to metals H302- Harmful if swallowed H304- Harmful if swallowed H314- Causes severe skin burns and eye damage H318 - Causes serious eye damage H330 – Fatal if inhaled H335- May cause respiratory irritation H350- May cause cancer H370- Causes damage to organs H401- Toxic to aquatic life

Precautionary statements

Precautionary Statement(s):

Prevention

P210- Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P220- Keep/Store away from clothing combustible materials. P221- Take any precaution to avoid mixing with combustibles. P234- Keep only in original container. P260- Do not breathe dust/fume/gas/mist/vapors/spray. P261-Avoid breathing dust/fume/gas/mist/vapors/spray. P264- Wash skin thoroughly after handling. P270- Do not eat, drink or smoke when using this product. P271-Use only outdoors or in a well-ventilated area. P273- Avoid release to the environment. P280- Wear protective gloves/protective clothing/eye protection/face protection.

Response

P301+312- IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P301+P330+P331- IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+P340- IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310- Immediately call a POISON CENTER or doctor/physician. P312-Call a POISON CENTER or doctor/physician if you feel unwell. P321- Specific treatment (see Section 4 SDS). P330- Rinse mouth. P370+P378- In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P390- Absorb spillage to prevent material damage. P391- Collect spillage. Hazardous to the aquatic environment.

Storage

P403+P233- Store in a well-ventilated place. Keep container tightly closed. P405- Store locked up. P406- Store in corrosive resistant container with a resistant inner liner. Color Code White (Corrosive) -----------------------------------------------------------------------------------------------------------

Disposal

P501- Dispose of contents/container to Federal, State and Local Regulations. Emergency Overview -------------------------- DANGER! CORROSIVE. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE BURNS TO SKIN AND EYES. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating: 4 - Severe (Life) Flammability Rating: 0 - None Reactivity Rating: 2 - Slight Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES

Potential health effects

Nitric acid is extremely hazardous; it is corrosive, reactive, an oxidizer, and a poison. Inhalation: Corrosive! Inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory failure, and death. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Ingestion: Corrosive! Swallowing hydrochloric acid or nitric acid can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. May cause nausea, vomiting, and diarrhea, and in severe cases, death. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma and death may follow, sometimes delayed as long as three days. Skin Contact: Corrosive! Can cause redness, pain, and severe skin burns. Concentrated solutions cause deep ulcers and discolor skin. Eye Contact: Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage. Chronic Exposure: Long-term exposure to concentrated vapors may cause erosion of teeth. Long term exposures seldom occur due to the corrosive properties of the acid. Repeated ingestion may cause liver damage. Prolonged exposure of the eyes may cause discoloration. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye disease may be more susceptible to the effects of this substance.