POR-15 BLACK

P.O.R. Products

Revision date : 2024-01-08

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GHS08 GHS02 GHS06
Health risk rating 5
Safety risk rating 2
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

25 - < 50

EC/CAS

64742-95-6

Name of the chemical

Solvent naphtha (petroleum), light arom

Concentration

10 - < 25

EC/CAS

64742-48-9

Name of the chemical

Naphtha (petroleum), hydrotreated heavy

Concentration

N/A

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

N/A

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

98-82-8

Name of the chemical

Cumol (2022/692)

Concentration

5 - < 10

EC/CAS

75-07-0

Name of the chemical

Acetaldehyde

Concentration

0 - < 0.1

EC/CAS

75-56-9

Name of the chemical

Methyloxirane (Propylene oxide)

Concentration

0 - < 0.1

General Information

Version

GHS 3.0

Revision date

2024-01-08

Product name

POR-15 BLACK

1.2.1 Relevant identified uses

Paint

Manufacturer Name

P.O.R. Products

Icons in SDS

GHS02 GHS06 GHS08 M004 M009 M011 M017 M022

Company Information

company name

P.O.R. Products

e-mail address of the competent person responsible for the Safety Data Sheet

support@porproducts.com, sales@raj.co.nz

GHS Information

Signal word

danger

Hazard Codes

Hazard statements (CLP)

H226, H304, H315, H317, H319, H331, H334, H335, H340, H350, H373, H401, H411, H412

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture Classification acc. to GHS Section

Hazard categories

Category Hazard class and cat- Hazard state- egory ment 2.6 flammable liquid Flam. Liq. 3 H226 3.1I acute toxicity (inhal.) Acute Tox. 3 H331 3.2 skin corrosion/irritation Skin Irrit. 2 H315 3.3 serious eye damage/eye irritation Eye Irrit. 2 H319 3.4R respiratory sensitisation Resp. Sens. 1 H334 3.4S skin sensitisation Skin Sens. 1 H317 3.5 germ cell mutagenicity 1B Muta. 1B H340 3.6 carcinogenicity 1A Carc. 1A H350 3.8R specific target organ toxicity - single exposure (respiratory STOT SE 3 H335 tract irritation) 3.9 specific target organ toxicity - repeated exposure STOT RE 2 H373 Section Category Hazard class and cat- Hazard state- egory ment 3.10

Aspiration hazard

Asp. Tox. 1 H304 4.1A hazardous to the aquatic environment - acute hazard Aquatic Acute 2 H401 4.1C hazardous to the aquatic environment - chronic hazard Aquatic Chronic 3 H412 For full text of abbreviations: see SECTION 16

Most important adverse effects

Delayed or immediate effects can be expected after short or long-term exposure. The product is combustible and can be ignited by potential ignition sources. Spillage and fire water can cause pollution of watercourses

Signal word

danger

Hazard pictograms

GHS02, GHS06, GHS08

Hazard statements

H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H340 May cause genetic defects. H350 May cause cancer. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P284 In case of inadequate ventilation wear respiratory protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302+P352 IF ON SKIN: Wash with plenty of water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P331 Do NOT induce vomiting. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container to industrial combustion plant.

Hazardous Ingredients

Solvent naphtha (petroleum), light arom., 4,4'- methylenediphenyl diisocyanate, Methylenedi- phenyl diisocyanate, 1-isocyanato-2-({4-isocyanato- 3-[(4-isocyanatophenyl)methyl]phenyl}methyl)-4- [(4-isocyanatophenyl)methyl]benzene; 1-isocy- anato-2-[(4-isocyanatophenyl)methyl]benzene; 1- isocyanato-4-[(4-isocyanatophenyl)methyl]benzene, methylenediphenyl diisocyanate

Results of PBT and vPvB assessment

Does not contain a PBT-/vPvB-substance in a concentration of ≥ 0,1%. Endocrine disrupting properties Does not contain an endocrine disruptor (ED) in a concentration of ≥ 0,1%.

2.1 Classification of the substance or mixture

Classification acc. to GHS Section Hazard class Category Hazard class and cat- Hazard state- egory ment 2.6 flammable liquid 3 Flam. Liq. 3 H226 3.1I acute toxicity (inhal.) 3 Acute Tox. 3 H331 3.2 skin corrosion/irritation 2 Skin Irrit. 2 H315 3.3 serious eye damage/eye irritation 2 Eye Irrit. 2 H319 3.4R respiratory sensitisation 1 Resp. Sens. 1 H334 3.4S skin sensitisation 1 Skin Sens. 1 H317 3.5 germ cell mutagenicity 1B Muta. 1B H340 3.6 carcinogenicity 1A Carc. 1A H350 3.8R specific target organ toxicity - single exposure (respiratory 3 STOT SE 3 H335 tract irritation) 3.9 specific target organ toxicity - repeated exposure 2 STOT RE 2 H373 Section Hazard class Category Hazard class and cat- Hazard state- egory ment 3.10 aspiration hazard 1 Asp. Tox. 1 H304 4.1A hazardous to the aquatic environment - acute hazard 2 Aquatic Acute 2 H401 4.1C hazardous to the aquatic environment - chronic hazard 3 Aquatic Chronic 3 H412 For full text of abbreviations: see SECTION 16. The most important adverse physicochemical, human health and environmental effects Delayed or immediate effects can be expected after short or long-term exposure. The product is combustible and can be ignited by potential ignition sources. Spillage and fire water can cause pollution of watercourses.

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