not

Hazard statements (CLP)

H302, H314, H315, H317, H318, H335, H400, H410, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

GLYCOL 1B 603-027-00-1 arising from Skin the 0.5 substance corrosion, ≤ x < 0.6 category or mixture not available class 1B Acute Tox. 4 H302 Parliament +90 262 728 "ПРЕДЕЛЬНО 10 88 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament ВРЕДНЫХ Fax ВЕЩЕСТВ В +90 ВОЗДУХЕ 262 728 РАБОЧЕЙ 10 71 ЗОНЫ" EC Colour TUR not applicable Avoid Eye Dam. exposure 1 203-473-3 to: sources of Serious heat,naked eye damage, Kimyasal Maddelerle Çalışmalarda Sağlık ve Güvenlik Önlemleri Hakkında Yönetmelik 12.08.2013 flames. not category available ATE 1 Oral: 500 mg/kg e-mail SERIOUS 12. Regulation (EU) 2016/1179 (IX Atp. CLP) address EYE of DAMAGE the Türkiye competent / IRRITATION person 10.5. CAS Odour AMMONIA Incompatible Skin Irrit. CAUSED 2 107-21-1 materials BY EXPOSURE Skin irritation, IN THE EVENT / 28733; 20.10.2023 category characteristic OF 2 FIRE / 32345. responsible for the Safety Data Sheet 13. Regulation (EU) 2017/776 (X Atp. CLP) info@sandeco.com.tr 14.3. GBR 1,2-BENZISOTHIAZOLIN-3-ONE Do Melting Degradability: STOT not breathe point SE / 3 information freezing combustion United class(es) point not products. Kingdom available Specific target organ not EH40/2005 toxicity Workplace exposure limits (Fourth Edition 2020) available - single exposure, category 3 Does 14. Transport Regulation not meet hazard the

EU Classification

2018/669 (XI criteria Atp. CLP) for this

Hazard categories

INDEX Initial AMMONIA Skin boiling Sens. point 1 613-088-00-6 EU Skin 0 sensitization, < x < 0.05 category Directive (EU) 2022/431; Directive (EU) 2019/1831; Directive (EU) 2019/130; Directive (EU) not available 1 Acute Tox. 4 H302, Eye Dam. 1 H318, Skin Irrit. 2 H315, Skin Sens. 1 H317, 1.4. EU Emergency telephone 15. Regulation (EU) 2019/521 (XII Atp. CLP) OEL number 5.3. Flammability 1,2-BENZISOTHIAZOLIN-3-ONE not applicable Advice Incompatible Skin Sens. for firefighters 1A with: silver,silver Skin salts,lead,lead sensitization, salts,zinc,zinc 2019/983; Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive category not available 1A Aquatic salts,hydrochloric Acute 1 H400 acid,nitric M=1, Aquatic acid,oleum,halogens,acrolein,nitromethane,acrylic Chronic 2 H411 RESPIRATORY 16. Delegated Regulation EC Lower Solubility acid. Aquatic explosive in water Acute 220-120-9 OR SKIN (UE) limit 1 SENSITISATION 2018/1480 (XIII Atp. CLP) Hazardous to the aquatic not available 1288 CLP) 0.486 and subsequent goods by Road amendments and supplements First aid measures WEL GBR 52 20 104 40 SKIN BCF ATE: Acute Toxicity Estimate The Information OEL product on must likely not routes EU penetrate of exposure into 52 the sewer system 20 or come into contact 5.75 104 with surface 40 water or SKIN ground water Hazard STOT Note Safety, CAS: Information for - pictograms Chemical Abstract SINGLE users health EXPOSURE and environmental regulations/legislation specific for the substance or mixture with regard Service to physical Number hazard classes The Description ETHYLENE CE50: Effective TLV-ACGIH information of contained GLYCOL first aid measures concentration (required to induce a 50% effect) in the present sheet are 25 based on our own knowledge on 50 the date of the last version. Users must verify the Does Seveso suitability Information Partition CE: Identifier Methods TLV-ACGIH not Category ETHYLENE coefficient meet and thoroughness and material not in available the - classification ESIS Directive of 2012/18/EU GLYCOL n-octanol/water European archive of existing substances) for containment and cleaning up provided criteria for information this hazard according class 1.36 to each specific 10 None use of the product INHAL In case of WORKERS This document must not be regarded as a guarantee on any specific product property doubt or in inhalation; the presence contact of symptoms with the skin contact a doctor and show him this document

Environmental hazards

Skin mg/l Sens. acute 1 H317: toxicity, ≥ 0.05% category 1 For urgent inquiries refer to 17. Regulation (EU) 2019/1148 2006/15/EC; Tel: Directive +90 262 2004/37/EC; 728 10 88 Directive 2000/39/EC; Directive 98/24/EC; Directive 10.6. CAS 14.4. Packing group GENERAL Upper Rapidly Hazardous Aquatic explosive degradable INFORMATION Chronic decomposition 2634-33-5 limit 1 products Hazardous to the aquatic 91/322/EEC. not available ATE Oral: chronic 500 mg/kg toxicity, category 1 Sensitising 18. Delegated 2-METHYLISOTHIAZOL-3(2H)-ONE Use Flash Aquatic jets point of water for the Chronic Regulation to cool skin 2 the containers (UE) 2020/217 (XIV Atp. CLP) Hazardous to prevent to the aquatic product Ulusal Zehir Danışma Merkezi(UZEM): 114 not available decomposition chronic and the toxicity, development category of 2 substances potentially hazardous for 19. Delegated Regulation (UE) 2020/1182 (XV Atp. CLP) TLV-ACGIH ACGIH 2023 INDEX health. Auto-ignition AMMONIA 2-METHYLISOTHIAZOL-3(2H)-ONE H330 Always temperature wear 613-326-00-9 full fire prevention Fatal 0.0015 if gear. inhaled. ≤ Collect x < 0.06 extinguishing not available Acute water Tox. to 2 H330, not applicable GERM 20. Delegated prevent Acute CELL MUTAGENICITY Regulation (UE) 2021/643 (XVI Atp. CLP) it from Tox. draining 3 H301, into Acute the sewer Tox. system. 3 H311, Dispose Skin Corr. of 1B SECTION contaminated Decomposition Solubility 21. Delegated Regulation (UE) 2021/849 (XVII Atp. CLP) May H301 develop: in 2. water temperature nitric used oxide. for identification extinction Toxic if and swallowed. the remains not of available 489000 the H314, fire according mg/l Eye Dam. to 1 applicable AMMONIA H318, Skin regulations. Sens. 1A H317, Aquatic Acute 1 H400 M=10, 14.5. Threshold SPECIAL pH ETHYLENE Degradability: Environmental H311 PROTECTIVE Limit Value GLYCOL information EQUIPMENT not available Toxic in FOR contact FIRE-FIGHTERS with 8-9 skin. Aquatic Chronic 1 H410 M=1, EUH071 2.1. Does 22. Delegated EC Normal Kinematic Classification May H302 fire not meet Regulation develop viscosity fighting the classification 220-239-6 of hydroxyacetaldehyde,glyoxal,acetaldehyde,methane,carbon the clothing substance UE) 2022/692 i.e. fire Harmful criteria for (XVIII or kit mixture BS if swallowed this hazard EN 469), gloves Atp. CLP) not available class BS Skin EN Sens 659) 1A and H317 boots monoxide,hydrogen (HO 0.0015% specification A29 and A30) in combination with 23. Delegated Regulation (UE) 2023/707 Type Country TWA/8h STEL/15min Remarks / Observations CAS self-contained Dynamic ETHYLENE not applicable H314 viscosity GLYCOL open 2682-20-4 circuit positive Causes mg/m3 pressure severe compressed skin 105 ppm burns air KU and breathing ATE eye Oral SECTION damage mg/m3 The CARCINOGENICITY 24. Delegated Solubility apparatus H318 in water 100 mg/kg, product 11 is Regulation BS ATE classified ppm Toxicological EN 137) Dermal: Temperature as (UE) hazardous 300 mg/kg, 25 LC50 2023/1434 Causes pursuant information serious eye XIX Atp. CLP) C Inhalation to the not damage provisions available 1000 mists/powders 10000 set forth mg/l in (EC) 0.11 Regulation mg/l/4h individual hazardous substances indicated in section 3, to evaluate the Classification are given note in according sections Temperature to and Annex 20 12 °C of VI this to sheet the CLP Regulation Handling ETHYLENE Relative H400 vapour density Chemical GLYCOL Safety Very toxic to aquatic not life. available toxicological effects of exposure to the product INRS - Available Fiche Toxicologique studies have (toxicological shown no carcinogenic sheet) potential. In a carcinogenicity study lasting two years, carried out by the US National ETHYLENE GLYCOL Hazard EC Particle H410 classification characteristics 215-647-6 and indication Very toxic to aquatic not life applicable with STOT long lasting SE 3 H335 effects. ≥ 5% 14.7. Block Threshold Patty - Toxicology Maritime the leakage Industrial Hygiene Limit transport Value if there in is bulk Program and (NTP), no hazard Toxicology according to IMO instruments in which ethylene glycol was administered in the feed, "no evidence of carcinogenic activity" in male and Wear CAS 1,2-BENZISOTHIAZOLIN-3-ONE Information Skin H411 sensitization, Type suitable protective on hazard 1336-21-6 Country category 1A Toxic to aquatic life with long lasting effects equipment classes TWA/8h as including defined personal in Regulation protective EC) equipment STEL/15min

2.1 Classification of the substance or mixture

fighting the classification 220-239-6 of hydroxyacetaldehyde,glyoxal,acetaldehyde,methane,carbon the clothing substance (UE) 2022/692 i.e. fire Harmful criteria for (XVIII or kit mixture (BS if swallowed. this hazard EN 469), gloves Atp. CLP) not available class (BS Skin EN Sens. 659) 1A and H317: boots monoxide,hydrogen. ≥ (HO 0.0015% specification A29 and A30) in combination with 23. Delegated Regulation (UE) 2023/707 Type Country TWA/8h STEL/15min Remarks / Observations CAS self-contained Dynamic ETHYLENE not applicable H314 viscosity GLYCOL open 2682-20-4 circuit positive Causes mg/m3 pressure severe compressed skin 105 ppm burns air KU and breathing ATE eye Oral: SECTION damage. mg/m3 The CARCINOGENICITY 24. Delegated Solubility apparatus H318 in water 100 mg/kg, product 11. is Regulation (BS ATE classified ppm Toxicological EN 137). Dermal: Temperature: as (UE) hazardous 300 mg/kg, 25 LC50 2023/1434 Causes pursuant information serious eye (XIX Atp. CLP) °C Inhalation to the not damage. provisions available 1000 mists/powders: - 10000 set forth mg/l in (EC) 0.11 Regulation mg/l/4h 1272/2008 (CLP) (and subsequent 24. Delegated Regulation (UE) 2023/1435 (XX Atp. CLP) OEL EU 14 20 36 50 amendments AMMONIA Partition Rapidly H315 degradable coefficient: and supplements). n-octanol/water Causes The product skin irritation. thus requires not available a safety datasheet that complies with the provisions of (EU) Regulation 14.6. In SECTION Does 2020/878. 6. Accidental release measures INDEX Vapour the Special H335 pressure 007-001-01-2 May 0 cause not absence meet precautions the of experimental classification for user data criteria for for < x < respiratory the this product 0.05 hazard itself, not irritation. class health hazards are evaluated according to the properties of the substances it available Skin Corr. 1B H314, Eye Dam. 1 H318, STOT SE 3 H335, Aquatic Acute 1 contains, - The Merck using Index. the - criteria 10th Edition specified in the applicable regulation for classification. 12.3. Any 6.1. It not Personal Density is applicable Bioaccumulative H317 therefore precautions, additional and/or information necessary to protective relative potential density concerning take into account May cause equipment the risks an allergic the concentration for health and emergency 1.35 skin and/or reaction. H400 the M=1, of the procedures environment individual hazardous substances indicated in section 3, to evaluate the Classification are given note in according sections Temperature: 11 to and Annex 20 12 °C of VI this to sheet. the CLP Regulation: - Handling ETHYLENE Relative H400 vapour density Chemical GLYCOL Safety Very toxic to aquatic not life. available B toxicological effects of exposure to the product. - INRS - Available Fiche Toxicologique studies have (toxicological shown no carcinogenic sheet) potential. In a carcinogenicity study lasting two years, carried out by the US National ETHYLENE GLYCOL Hazard EC Particle H410 classification characteristics 215-647-6 and indication: Very toxic to aquatic not life applicable with STOT long lasting SE 3 H335: effects. ≥ 5% 14.7. Block Threshold - Patty - Toxicology Maritime the leakage Industrial Hygiene Limit transport Value if there in is bulk Program and (NTP), no hazard. Toxicology according to IMO instruments in which ethylene glycol was administered in the feed, "no evidence of carcinogenic activity" in male and 11.1. Wear CAS 1,2-BENZISOTHIAZOLIN-3-ONE Information Skin H411 sensitization, Type suitable protective on hazard 1336-21-6 Country category 1A Toxic to aquatic life with long lasting effects. equipment classes TWA/8h as (including defined personal in Regulation protective (EC) equipment STEL/15min No 1272/2008 H317 referred to under Section May cause an allergic skin reaction. Remarks 8 of / Observations the safety data sheet) to prevent - N.I. Sax female Partition EUH071 coefficient: n-octanol/water - Dangerous B6C3F1 properties mice was of observed Corrosive to the respiratory 0.7 tract. Industrial (NTP, Materials-7, 1993). 1989 Edition any Information - IFA GESTIS website contamination not relevant of skin, eyes and mg/m3 personal clothing. ppm These indications mg/m3 apply for both ppm processing staff and those involved in emergency The BCF full wording of hazard (H) phrases is given in section 16 procedures. Metabolism, TLV toxicokinetics, BGR mechanism 52 of action and 20 other information 104 6.62 of the sheet. 40 SKIN 2.2. REPRODUCTIVE - ECHA Label elements website TOXICITY - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanità) - Italy ПДК RUS

2.3 Other hazards

FOR CLASSIFICATION

Hazard statements

- LC50: Lethal Concentration 50% Rescuer Provide Interactive an protection Chemical effects emergency shower with face and eye wash station.

Precautionary statements

P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P333+P313 If skin irritation or rash occurs: Get medical advice / attention. P362+P364 Take off contaminated clothing and wash it before reuse. P280 Wear protective gloves. P321 Specific treatment (see . . . on this label). P272 Contaminated work clothing should not be allowed out of the workplace.

Contains

2-METHYLISOTHIAZOL-3(2H)-ONE 1,2-BENZISOTHIAZOLIN-3-ONE

Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.