PROHIVE

Orion AgriScience Ltd

Revision date : 2025-04-01

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GHS06 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

23103-98-2

Name of the chemical

Pirimicarb (ISO); 2-(Dimethylamino)-5,6-dimethylpyrimidin-4-yldimethyl-carbamat (2016/1179)

Concentration

100%

General Information

Revision date

2025-04-01

Product name

PROHIVE

CAS No.

23103-98-2

1.2.1 Relevant identified uses

Insecticide

supplier name

Orion AgriScience Ltd

Icons in SDS

GHS06 GHS07 GHS08 GHS09 M004 M008 M009 M010 M011 M013 M017

Company Information

company name

Orion AgriScience Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

orders@orionagriscience.co.nz

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H301, H317, H319, H332, H373, H400, H410, H431, H442

Hazard statements

Code

Statements

H301

Toxic if swallowed

Section 2

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

Acute Oral Toxicity (Cat. 3) Acute Inhalation Toxicity (Cat. 4) Eye Irritation (Cat. 2) Skin Sensitisation (Cat. 1) Specific Target Organ Toxicity single and repeated (Cat. 2) Hazardous to the aquatic environment Acute (Cat. 1) Hazardous to the aquatic environment chronic (Cat. 1) Hazardous to terrestrial vertebrates Hazardous to terrestrial invertebrate H301 Toxic if swallowed H332 Harmful if inhaled H319 Causes serious eye irritation H317 May cause an allergic skin reaction H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H431 Very toxic to terrestrial vertebrates H442 Toxic to terrestrial invertebrates

Prevention

P101 If medical advice is needed, have product container or label at hand P102 Keep out of reach of children P103 Read carefully and follow all instructions P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well ventilated area P273 Avoid release to the environment P280 Wear eye protection / face protection P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves P260 Do not breathe dust/fume/gas/mist/vapours/spray Avoid contact with eyes and skin. Do not breathe in the dust or spray mist. When mixing or applying, wear personal protection as described in section 8. Take all reasonable steps to ensure that this product does not cause any significant adverse effects to the environment beyond the application area. This product is toxic to bees. Do not apply this substance to plants if bees are foraging, or the plants are in flower or part flower, and are likely to be visited by non-target invertebrate pollinators (including bees). Do not apply directly into or onto water.

Response

P301+P310 IF SWALLOWED: Immediately call a POISON CENTRE/doctor P330 Rinse mouth P321 Specific treatment (Refer section 4) P304+P340 IF INHALED: Move person to fresh air and keep comfortable for breathing P312 Call a POISON CENTRE/doctor if you feel unwell P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing P337+P313 If eye irritation persists: Get medical advice/attention P302+P352 IF ON SKIN: Wash with plenty of water P333+P313 If skin irritation or rash occurs: Get medical advice/attention P362+P364 Take off contaminated clothing and wash it before reuse P391 Collect spillage First aid measures described in section 4. Contain and collect spillage for disposal. In an emergency call 111, Police or Fire Brigade. For specialist advice in an emergency only, call 0800 CHEMCALL (0800 243 6225) (24 hrs).

Storage

P405 Store locked up Keep out of reach of children.

Disposal

P501 Dispose of contents by using it in accordance with this label. Dispose of the container via AgRecovery after triple rinsing (use the rinsate for spraying).

2.1 Classification of the substance or mixture

Hazard Statements: Acute Oral Toxicity (Cat. 3) H301 Toxic if swallowed Acute Inhalation Toxicity (Cat. 4) H332 Harmful if inhaled Eye Irritation (Cat. 2) H319 Causes serious eye irritation Skin Sensitisation (Cat. 1) H317 May cause an allergic skin reaction Specific Target Organ Toxicity single and repeated (Cat. 2) H373 May cause damage to organs through prolonged or repeated exposure Hazardous to the aquatic environment Acute (Cat. 1) H400 Very toxic to aquatic life Hazardous to the aquatic environment chronic (Cat. 1) H410 Very toxic to aquatic life with long lasting effects Hazardous to terrestrial vertebrates H431 Very toxic to terrestrial vertebrates Hazardous to terrestrial invertebrate H442 Toxic to terrestrial invertebrates

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