Exel MS

Orica UK Limited

Revision date : 2013-08-20

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GHS01 GHS08
Health risk rating 4
Safety risk rating 5
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

1314-41-6

Name of the chemical

Orange lead (lead tetroxide)

Concentration

N/A

EC/CAS

78-11-5

Name of the chemical

Pentaerithrityl tetranitrate (INN)

Concentration

N/A

EC/CAS

215-235-6

Name of the chemical

Orange lead

Concentration

N/A

EC/CAS

201-084-3

Name of the chemical

Pentaerithrityl tetranitrate (INN)

Concentration

N/A

General Information

Revision date

2013-08-20

Product name

Exel MS

1.2.2. Uses advised against

Usage of the product only according to existing laws and official permissions Function(s) of substance / Detonators will directly initiate cap sensitive boosters and packaged explosives mixture

supplier name

Orica UK Limited

Icons in SDS

Company Information

company name

Orica UK Limited

e-mail address of the competent person responsible for the Safety Data Sheet

andy.rossiter@orica.com, sds.emea@orica.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H201, H204, H361f, H373

Hazard statements

Code

Statements

H201

Explosive; mass explosion hazard

Section 2

SECTION 2: Hazards identification

67/548/EEC Unpackaged detonators are defined as: H201 - Explosive, mass explosion hazard. Risk of explosion by shock, friction, fire or other sources of ignition. Shrapnel from detonation may cause burns and wounds.

2.1 Classification of the substance or mixture

The mixture is classified as dangerous within the meaning of Regulation (EC) No 1272/2008. The preparation is classified as dangerous according to Directive 1999/45/EC. Classification in accordance with Regulation (EC) No. 1272/2008

Hazard categories

category

Hazard statements

Classification method H201 Explosive, mass explosion hazard. H204 - Fire or projection hazard.) Use of special provisions according to 1272/2008/EC art. 23e. Labelling in accordance with Directive 67/548/EEC or Directive 1999/45/EC Hazard symbol(s) Identification of danger Explosive

Additional information

Expl. 1.1 H201 UN RTDG CLP - figure 2.1.3 This classification describes UNPACKED detonators. The transport classification can differ depending on the approved packaging. Wording of Hazard statements (H, EUH): see section 16. Classification in accordance with Directive 67/548/EEC or Directive 1999/45/EC Properties or classification (EU) - - Note By using special approved packaging a reduction of a explosive hazard is possible Specific concentration limits Lead(II,IV)oxide, Index No.: 082-001-00-6 C ≥2.5 % H361f Repr. 1B R62 Repr. Cat. 3 C ≥1.0 % R20/22 Xn C ≥0.5 % H373 STOT RE 2 R33

R-phrase(s)

letter E R2 Risk of explosion by shock, friction, fire or other sources of ignition. No additional information R2 Risk of explosion by shock, friction, fire or other sources of ignition.

2.2 Label elements

Labelling in accordance with Regulation (EC) No. 1272/2008

Product definition

Exel™ MS Exel™ LP Exel™ U Det Index or C&L number Not applicable Hazardous component(s) Lead(II,IV)oxide, Index No.: 082-001-00-6 P.E.T.N., Index No.: 603-035-00-5 Hexogen, EC No.: 204-500-1 Authorization number Not applicable

Signal word

Danger Warning;

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P250 Do not subject to grinding / shock / … / friction. P280 Wear protective gloves / protective clothing / eye protection / face protection. P370+P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. P373 DO NOT fight fire when fire reaches explosives.

S-phrase(s)

S15 Keep away from heat. S16 Keep away from sources of ignition - No smoking. S20/21 When using do not eat, drink or smoke. S33 Take precautionary measures against static discharges. S36/37/39 Wear suitable protective clothing, gloves and eye / face protection. Note Use of special provisions according to 67/548/EEC art. 25(1) and 1999/45/EC art. 12(1).

Results of PBT and vPvB assessment

No assessment established up to now.

Other hazards

During use of article, a release of lead containing reaction products occurs. Stythe is heavier than air and may accumulate below ground level, in pits, channels and basements in higher concentration. All chemicals are potentially dangerous; they should only be handled by properly trained personnel with the necessary care.

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