ORP Thermobond 65

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) - CE50: Effective concentration (required to induce a 50% effect) As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail The following sections were modified: - CE NUMBER: Identifier in ESIS (European archive of existing substances) HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE well aired through effective local aspiration. (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

HMIS® ratings

CARCINOGENICITY 01 / 03 / 04 / 06 / 07 / 08 / 10 / 11. The product is stable in normal conditions of use and storage. - CLP: EC Regulation 1272/2008 Do not breathe combustion products. The product is combustible and, when the powder is released into the air in sufficient concentrations HAND PROTECTION Health: 1 - DNEL: Derived No Effect Level Health: 1 Fire:1 Reactivity 0 PPE E

UN Number

and in the presence of a source of ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage of the solid In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). Does not meet the classification criteria for this hazard class 10.3. Possibility of hazardous reactions - EmS: Emergency Schedule product from the container, when it reaches high temperatures or through contact with sources of ignition. Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity - GHS: Globally Harmonized System of classification and labeling of chemicals reactions. Not applicable

2.1 Classification of the substance or mixture

REPRODUCTIVE TOXICITY No hazardous reactions are foreseeable in normal conditions of use and storage. - IATA DGR: International Air Transport Association Dangerous Goods Regulation 5.3. Advice for firefighters SKIN PROTECTION 14.2. UN proper shipping name - IC50: Immobilization Concentration 50% None required. The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent Does not meet the classification criteria for this hazard class - IMDG: International Maritime Code for dangerous goods The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent GENERAL INFORMATION amendments and supplements). Accumulation of fine dust may entail the risk of a dust explosion in the presence of air. Reactions with oxiziding agents. - IMO: International Maritime Organization amendments and supplements). Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for EYE PROTECTION Not applicable STOT - SINGLE EXPOSURE - INDEX NUMBER: Identifier in Annex VI of CLP health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of None required. 10.4. Conditions to avoid Hazard classification and indication: - LC50: Lethal Concentration 50% Hazard classification and indication: -- 14.3. Transport hazard class(es) contaminated water used for extinction and the remains of the fire according to applicable regulations. RESPIRATORY PROTECTION Does not meet the classification criteria for this hazard class - LD50: Lethal dose 50% SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Use a type P filtering facemask, whose class (1, 2 or 3) and effective need, must be defined according to the outcome of risk assessment None in particular. However the usual precautions used for chemical products should be respected. - OEL: Occupational Exposure Level Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with (see standard EN 149). Not applicable

2.2 Label elements

STOT - REPEATED EXPOSURE

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). ENVIRONMENTAL EXPOSURE CONTROLS 10.5. Incompatible materials 14.4. Packing group - PEC: Predicted environmental Concentration The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure Does not meet the classification criteria for this hazard class

Hazard pictograms

PEL: Predicted exposure level compliance with environmental standards. SECTION 6. Accidental release measures Information not available - PNEC: Predicted no effect concentration Not applicable

Aspiration hazard

REACH: EC Regulation 1907/2006

Signal word

6.1. Personal precautions, protective equipment and emergency procedures 10.6. Hazardous decomposition products - RID: Regulation concerning the international transport of dangerous goods by train

Environmental hazards

GLOVES TYPE: Nitrile rubber, breakthrough time > 480 minutes, glove thickness 0.1 - 0.4 mm. Does not meet the classification criteria for this hazard class

Hazard statements

TLV: Threshold Limit Value -- Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Not applicable emergency procedures.

Precautionary statements

For thermal decomposition to high temperature are formed toxic, irritating and inflammable smoke. - TWA STEL: Short-term exposure limit --

ECOLOGICAL INFORMATION

14.6. Special precautions for user SECTION 9. Physical and chemical properties - TWA: Time-weighted average exposure limit Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or - VOC: Volatile organic Compounds

TOXICOLOGICAL INFORMATION

contaminate soil or vegetation.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation 6.2. Environmental precautions 9.1. Information on basic physical and chemical properties Not applicable

2.3 Other hazards

WGK: Water hazard classes (German). 12.1. Toxicity 11.1. Information on toxicological effects 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. The product must not penetrate into the sewer system or come into contact with surface water or ground water. Appearance On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. powder Colour GENERAL BIBLIOGRAPHY white Information not relevant Odour characteristic Risk of dust explosion. No expected damaging effects to aquatic organisms. 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament Risk of dust explosion. LD 50 (Oral,rat)> 2000 mg/kg (conclusion by analogy) Odour threshold Not available 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament . 6.3. Methods and material for containment and cleaning up SECTION 15. Regulatory information pH 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 5,0-8,0 (1:1 aqueous soln.) 12.2. Persistence and degradability