DPD No.3 Tablets

SECTION 2: Hazards identification

Hazard statements

Not applicable · Canadian Hazard Symbols Not controlled under

Classification system

The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. · NFPA ratings (scale 0 - 4) Health = 0 0 Fire = 0 0 0 Reactivity = 0 3 Composition / Data on components · Description: Preparation contains inorganic compounds. · Composition and Information on Ingredients: CAS: 9999-99-9

Non Hazardous Components

80-90% Any ingredient(s) of this product listed as "Nonhazardous component(s)" is not considered a health hazard

Additional information

Ambient fire may liberate hazardous vapours. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures · Person-related safety precautions: Avoid formation of dust. Wear protective equipment. Keep unprotected persons away. · Measures for environmental protection: Do not allow product to reach sewage system or any water course. · Measures for cleaning/collecting: Pick up mechanically. Ensure adequate ventilation. Dispose contaminated material as waste according to item 13. No dangerous substances are released 7 Handling and storage · Handling: · Information for safe handling: No special measures required. · Information about protection against explosions and fires: The product is not flammable. The lists that were valid during the creation were used as basis · Personal protective equipment: · General protective and hygienic measures: Do not eat, drink, smoke or sniff while working. Wash hands before breaks and at the end of work. · Breathing equipment: Use respiratory protective device against the effects of fumes/dust/aerosol. · Recommended filter device for short term use: Filter P2 · Protection of hands: Preventive skin protection by use of skin-protecting agents is recommended. · Material of gloves Nitrile Recommended thickness of the material: ≥ 0.11 mm · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Value for the permeation: Level ≥ 6 (480 min) · Eye protection: Not required. · Body protection: Protective work clothing 9 Physical and chemical properties · Odor Threshold: Not applicable. · Form: Tablets · Color: White · Odor: Odorless · Melting point/Melting range: Undetermined. · Boiling point/Boiling range: 1330°C (2426°F) · Freezing Point: Not applicable. · Flash point: Not applicable. · Flammability (solid, gaseous): Upper Flammable Limit: Not applicable. Lower Flammable Limit: Not applicable. · Ignition temperature: Undetermined. · Sensitivity to Mechanical Impact: None · Sensitivity to Static Discharge: None · Auto igniting: Product is not selfigniting. · Danger of explosion: Product does not present an explosion hazard. · Vapor Density: Not applicable. · Specific Gravity: Not applicable. · Density at 20°C (68°F): 2.160 g/cm³ · Solubility in / Miscibility with Water: Soluble. · Coefficient of Water / Oil Distribution: Not applicable. · pH-value (13 g/l) at 20°C (68°F): 6.3 · Solvent content: Organic solvents: 0.0 % (Contd. on page 4) USA · Solids content: 100.0 % 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat. · Materials to be avoided: alkali metals acids oxidizing agents --> Forms heat. · Dangerous products of decomposition: see chapter 5

Storage

· Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store in dry conditions. Protect from humidity and water. Protect from exposure to the light. Protect from heat and direct sunlight. USA (Contd. on page 3) 8 Exposure controls and personal protection · Additional information about design of technical systems: No further data; see item 7. · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

TOXICOLOGICAL INFORMATION

· Acute toxicity: Quantitative data on the toxicity of the preparation are not available. · LD/LC50 values that are relevant for classification: 7681-11-0 potassium iodide Oral LD50 2779 mg/kg (rat) · Primary irritant effect: · on the skin: No irritant effect. · on the eye: Irritating effect. · Sensitization: Sensitizing effect by skin contact is possible with prolonged exposure. · Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations. When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. The usual precautionary measures for handling chemicals should be followed. · Carcinogenicity NTP? IARC Monographs?

Teratogenic Effects

Not found · Mutagenicity: Not found. · Reproductive Toxicity: Not found. · Synergistic Products: None

ECOLOGICAL INFORMATION

· Information about elimination (persistence and degradability)

Further information

Methods for the determination of biodegradability are not applicable to inorganic substances. Quantitative data on the ecological effect of this preparation are not available. · Behavior in environmental systems: 7681-11-0 potassium iodide log P(o/w) 0.04 (.) · Ecotoxical effects: · Aquatic toxicity: 7681-11-0 potassium iodide Daphnia EC50 2.7 mg/l/24h (Daphnia magna) · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 5) USA Must not reach bodies of water or drainage ditch undiluted or unneutralized. 13 Disposal considerations · Product: · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information · DOT regulations: This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Contact Orbeco-Hellige, Inc., Quality Assurance Dept., Phone 941-756-6410 · Sources Data arise from manufacturers' data sheets, reference works and literature. USA 1 Identification of the substance/mixture and of the company/undertaking

Hazard categories

None · Land transport ADR/RID (cross-border): · ADR/RID class: None · Maritime transport IMDG: · IMDG Class: None · Marine pollutant: No · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: None · Propper shipping name: None · Canadian TDG Class: None · Transport/Additional information: Not dangerous according to the above specifications. 15 Regulations · Sara · Section 355 (Extremely hazardous substances): None of the ingredients is listed. · Section 313 (Specific toxic chemical listings): None of the ingredients is listed. · TSCA (Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemicals known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Canadian Ingredient Disclosure List · Limit 0,1% None of the ingredients is listed. (Contd. on page 6) USA · Limit 1% 7681-11-0 potassium iodide · Canadian Domestic Substances List (DSL) All ingredients are listed. · EPA (Environmental Protection Agency) None of the ingredients is listed. · IARC (International Agency for Research on Cancer) None of the ingredients is listed. · NTP (National Toxicology Program) None of the ingredients is listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. · Product related hazard informations: The product is not subject to identification regulations according to directives on hazardous materials. · Information about limitation of use: Not required. Water hazard class Water hazard class 1 (Self-assessment) slightly hazardous for water

CLP CLASSIFICATION

None · MSDS discloses information elements required by the CPR .

Product definition

Reagent for water analysis · Trade name: DPD No.1 Tablets · Catalogue number: RT105-0BT · Manufacturer/Supplier: Orbeco-Hellige, Inc. 6456 Parkland Drive Sarasota, FL 34243 USA phone: (941) 756-6410 fax: (941) 727-9654 www.orbeco.com Made in Germany Emergency telephone number Chemtrec 800-424-9300

2.1 Classification of the substance or mixture

The product is not classified according to the Globally Harmonized System (GHS).

EU Classification

Directive 67/548/EEC or Directive 1999/45/EC none

2.2 Label elements

· GHS label elements none · Hazard pictograms none · Signal word none

Hazardous Ingredients

none · Hazard statements none · Canadian Hazard Symbols Not controlled under