SA54-1; SA54-4: SA54-10; SA54-20

SECTION 2: Hazards identification

Signal word

Warning

Hazard statements

Causes skin irritation Causes serious eye irritation May cause respiratory irritation

Prevention

Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep only in original container

Response

Get medical attention/advice if you feel unwell Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Skin IF ON SKIN: Wash with plenty of soap and water if skin irritation occurs: Get medical advice/attention Take off contaminated clathing and wash before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Spills Absorb spillage to prevent material damage

Storage

Store in a well-ventilated place. Keep container tightly closed Store locked up Store in corrosive resistant polypropylene container with a resistant inliner Store in a dry place Keep containers tightly closed in a dry, cool and well-ventilated place. Exposure control SURES Artoteindl) rols\ipersona jaliprote Ra pan tection: Expo osure Guidelines Component ACGIH TLV

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

None identified Component CAS-No Weight % Water 7732-18-5 > 98 Hydrochloric acid 7647-01-0 <2.0 Hae roe Eee General Advice If symptoms persist, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Skin Contact Wash off immediately with plenty of water for at least 16 minutes. Get medical attention if symptoms occur. Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention if symptoms occur. Ingestion Do not induce vorniting. Obtain medical attention. Most important symptoms/effects None reasonably foreseeable. Notes to Physician Treat symptomatically Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Unsuitable Extinguishing Media No information available Flash Point Not applicable Method - No information available Autoignition Temperature No information available Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge —_No information available Specific Hazards Arising from the Chemical Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (COz) Hydrogen chloride gas Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Flammability Instability

Physical hazards

2 0 NIA Ed eee 36. Accidental releaseimeasines Bae aide TEA Ree ae a oP OC i G7 Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Environmental Precautions Should not be released into the environment. See Section 12 for additional ecological information. Methods for Containment and Clean Soak up with inert absorbent material. Keep tn suitable, closed containers for disposal. Up — eS aia agit cee or iandlingiand:storage, Se eres distorage. aye te ie 2 egret Rey Rianne Parente i SEE Handling Wear personal protective equipment. ae adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Appearance/Odor

Clear No information available Odor Threshold No information available pH 0.10 (1N) Meiting PointiRange No data available Boiling PointfRange No information available Flash Point Not applicable Evaporation Rate No information available Flammability (solid,gas) No information available Flammability or explosive limits Upper No data available Lower No data available Vapor Pressure No information available Vapor Density No information available Relative Density No information available Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature No information available Decomposition Temperature No information available Viscosity No information available Molecular Formula HCI Molecular Weight 36.46 Reactive Hazard None known, based on information available Stability Stable under normal conditions. Conditions to Avoid “Incompatible products. Excess heat. Incompatible Materials Metals, Oxidizing agents, Reducing agents, Aldehydes Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Hydrogen chloride gas Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. ene BT RETR rade to} jexicolol jicaltinformatia OS RAT (Mga Acute Toxicity Component Information Component LD50 Oral LDS50 Dermal LC50 Inhalation Hydrochloric acid 238 - 277 ma/kg (Rat) 5010 mg/kg_( Rabbit ) 1.68 ma/L (Rat) ih Toxicologically Synergistic No information available Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Irritating to eyes and skin Sensitization No information available Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No [ARG NTP ACGIH OSHA Mexico Water 7732-18-5 Not listed Hydrochloric acid 7647-01-0 Not listed Not fisted IARC: (international Agency for Research on Cancer) Group 7 - Carcinogenic to Humans Group 2A - Probably Carcinagenic to Humans Group 2B - Possibly Carcinogenic to Humans Mutagenic Effects Mutagenic effects have occured in microorganisms. Reproductive Effects Experiments have shown reproductive toxicity effects on laboratory animals. Developmental Effects Developmental effects have occurred in experimental animals. Teratogenicity Teratogenic effects have occurred in experimental animals. STOT - single exposure Respiratory system STOT - repeated exposure None known Aspiration hazard No information available Symptoms / effects,both acute and No information available delayed Endocrine Disruptor Information No information available Other Adverse Effects See actual entry in RTECS for complete information. Ecol Toes TRE ee Ecologicaliintormation: fue ey Ecotoxicity Do not empty inte drains. Component Freshwater Algae Freshwater Fish Microtox Water Flea Hydrochloric acid - 282 mg/l LC50 96 h - Persistence and Degradability No information available Bioaccumutation/ Accumulation No information available. Mobility No information available. Disposal-considerations tae waste generators must determine whether a discarded chemical is classifi ed ¢ as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. iransport: ortintorm DOT UN-No UN1789 Proper Shipping Name HYDROCHLORIC ACID Hazard Class Packing Group TDG UN-No UN1789 Proper Shipping Name HYDROCHLORIC ACID Hazard Class 8 Packing Group Wi IATA UN-No UN1789 Proper Shipping Name HYDROCHLORIC ACID Hazard Class 8 Packing Group tl IMDG/IMO UN-No UN1789 Proper Shipping Name HYDROCHLORIC ACID Hazard Class 8 Pee Pte tS pyran ae Pcie International inventories Component TSCA | DSL | NDSL | EINECS | ELINCS| NLP | PICCS| ENCS | AICS | IECSC| KECL Water Xx ~ |234-791-2/ —- x - x Hydrochloric acid Xx X - 231-595-7 - xX X Xx Legend: X - Listed E - Indicates a substance that Is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that Is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical inittator in its inventory name but is considered to cover the designated polymer made with any free-radical Initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that Is the subject of a Section 6 risk management rule under TSCA. & - Indicates a substance that Is Identified in a proposed or final Significant New Use Rule T - Indicates a substance that Is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, l.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2- Indicates an exempt polymer that is a polyester and is made only from reactants included In a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S, Federal Requlations TSCA 12{b) Not applicable SARA 313 Component CAS-No Weight % SARA 3143 - Threshold Values % Hydrochtoric acid 7647-01-0 <2.0 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act Component |__CWA-Hazardous | CWA-Reportable | CWA - Toxic Pollutants [CWA - Priority Pollutants] Substances Quantities Hydrochloric acid - x 5000 Ib - Clean Air Act Component HAPS Data Class 1 Ozone Depletors Class 2 Ozone Depletors Hydrochloric acid Xx - OSHA Occupational Safety and Health Administration Not applicable Component Specifically Regulated Chemicals Highly Hazardous Chemicals Hydrochloric acid - TQ: 5000 tb CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Component Hazardous Substances RQs CERCLA EHS RQs Hydrochloric acid 5000 tb §000 Ib California Proposition 65 This product does not contain any Proposition 65 chemicals State Right-to-Know Component Massachusetts New Jersey Pennsyivania lilinois Rhode Island Water - Xx - Hydrochloric acid X x X U.S. Department of Transportation Reportable Quantity (RQ): Y DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product contains the following DHS chemicals: Component DHS Chemical Facility Anti-Terrorism Standard Hydrochloric acid 0 Ib STQ (anhydrous); 11250 Ib STQ (37% concentration or greater) Other International Regulations Mexico - Grade No information available Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class D2B Toxic materials Prepared By Regulatory Affairs Thermo Fisher Scientific Email: EMSDS.RA@thermofisher.com Creation Date 15-Feb-2010 Revision Date 20-Feb-2014 Print Date 20-Feb-2014 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS