Most

Hazard statements (CLP)

H225, H226, H302, H315, H319, H332, H336, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

EXPOSURE and DEU GBR competent

vPvB Substances

and controls/personal assessment Toxicology Toxic criteria CONTROLS person EMS: to and 734 23 for this hazard F-E, aquatic protect S-D life those 200 5 class protection with long trying lasting to Limited stem 1468 46 effects. the Quantities: leak. 1 lt 400 10 responsible The - N.I. MAK OEL emissions Sax - Dangerous for generated the Safety DEU EU properties by Data manufacturing Sheet of 734 23 Industrial processes, Materials-7, 200 5 SDS@forestali.it including 1989 Edition those 1468 46 generated by 400 10 ventilation equipment, should be checked to ensure 8.1. Control parameters - for Very Fish ATE None Methods (Inhalation) and Do material persistent and very bioaccumulative of not the induce mixture: for vomiting containment unless and grenseverdier), explicitly cleaning authorised 7,72 mg/l/96h Pimephales promelas up 21. Not august by classified a doctor. 2018 (no nr. Do 1255 significant not give component) anything by mouth to an unconscious person. Get 9.2. - vPvM

Contains

UNSUITABLE Avoid IATA: EUH066 overheating. EXTINGUISHING Avoid bunching Repeated EQUIPMENT Cargo: of electrostatic exposure charges. may cause Avoid skin Maximum all sources dryness quantity: of or ignition. cracking. 60 L Packaging instructions: 364 compliance CARCINOGENICITY On - IFA TLV Do EUH204 TLV-ACGIH the GESTIS not use jets of water. Water is Contains basis with of website available environmental DNK data, the standards. 1441 Passengers: not effective 23 product does not 400 5 contain any PBT 70 or vPvB in percentage isocyanates. for putting May out produce fires Maximum but an can allergic be quantity: used reaction. to 5 cool 15 L containers exposed ≥ than 0,1%. E Packaging to flames instructions: to prevent 353 explosions. 1.4. Predicted For - ECHA Identification ETHYL ACETATE Emergency VLA information website no-effect telephone on controlling ESP concentration number environmental Special 23 - PNEC exposure, x = Conc. provision: % 5 see the exposure ETHYL ACETATE Identification x = Conc. %

2.1 Classification of the substance or mixture

- SINGLE and value 15. thoroughness EXPOSURE for Regulatory acid-tris the (European the ITA terrestrial substance (p-isocyanatophenylester) of provided archive compartment information 23 or mixture information 5 according to each 70 specific use of 15 the product. of existing substances) se stanoví podmínky ochrany zdraví při práci 0,148 mg/kg/d DEU Health Information This RD document - Derived not available must no-effect Deutschland LTU not be regarded level - 23 DNEL as a / guarantee DMEL 5 on any specific 70 Forschungsgemeinschaft MAK- und BAT-Werte-Liste 2022 Ständige Senatskommission zur product property. 15 INDEX GENERAL Properties In - CLP: the event Regulation INFORMATION of thermal (EC) decomposition 1272/2008 24 or ≤ fire, x < gases Prüfung gesundheitsschädlicher Arbeitsstoffe Mitteilung 58 25,5 and Value vapours Acute that Tox. are 4 potentially H302 dangerous to Information health may be released. The May The RV use EC Use Appearance - DNEL: cause of drowsiness product jets Derived of water this product LVA is classified 223-981-9 No to cool Effect the or is dizziness as Level not Effects hazardous containers pursuant subject on 23 consumers to our direct control; to prevent to product the 5 liquid provisions therefore, 70 decomposition ATE Oral: set forth users must, under 15 Effects 500 and in mg/kg (EC) the development Regulation 1272/2008 their own on workers of substances responsibility, comply with the current health (CLP) potentially 15.1. DNK Safety, health and Danmark (and subsequent and TLV Route safety of laws hazardous for exposure and regulations. NOR Acute The 23 producer environmental regulations/legislation Acute is relieved Bekendtgørelse om grænseværdier 5 from Chronic any liability Chronic specific for the for substance arising from Acute stoffer og materialer improper or mixture - BEK nr 1458 af 13/12/2019 local uses. Acute amendments CAS health. Colour - EmS: Always Chronic Emergency and wear 4151-51-3 Chronic supplements). Schedule full fire prevention The product gear. Collect SECTION ESP STOT Provide thus requires TGG - REPEATED extinguishing yellow a safety water appointed 13. Disposal 11. Toxicological staff EXPOSURE España considerations NLD with local datasheet to prevent adequate 23 information that it complies training from draining systemic Límites de exposición profesional para agentes químicos en España 2023 on how to use with the into provisions local chemical 70 products. the sewer of system. (EU) Regulation systemic Dispose of systemic local systemic 2020/878. REACH contaminated Odour - GHS: Globally Reg. water 01-2119948848-16 Harmonized used for System extinction of and classification the remains characteristic and of labeling the fire of according of chemicals solvent to applicable regulations. EST Seveso Category - Directive Oral Eesti PRT 2012/18/EU: 23 Ohtlike kemikaalide ja neid sisaldavate 5 13.1. CHLOROBENZENE Any VLE SPECIAL Melting - IATA 70 4,5 Waste None additional DGR: point PROTECTIVE treatment International / information materjalide kasutamise töötervishoiu ja tööohutuse nõuded freezing methods 15 point EQUIPMENT Air concerning Transport the FOR Association risks FIRE-FIGHTERS for Dangerous health -84 and/or °C Goods the environment Regulation are given in sections Substance:ETHYL 11 and 12 of ACETATE this sheet. 11.1. Information on hazard classes as defined Does CALCULATION NDS/NDSCh not meet the METHODS classification POL FOR criteria CLASSIFICATION 23 for this hazard class ning in töökeskkonna Regulation keemiliste (EC) No 1272/2008 70 mg/kg bw/d ohutegurite piirnormid [RT I, 21.12.2022, 14] INDEX Normal Initial - IC50: boiling FRA Restrictions relating to France Immobilization fire fighting point 602-033-00-1 clothing Concentration the product or contained i.e. fire kit 0,809 50% (BS EN ≤ x < 469), Valeurs substances 0,909 limites d'exposition gloves 77 (BS pursuant to professionnelle Flam. °C EN Liq. 659) 3 and Annex XVII to aux H226, boots Acute (HO Tox. EC agents specification Regulation 4 H332, Substance:ETHYL chimiques A29 Skin and 1907/2006 Irrit. A30) en FranceDécret n° 2021-1849 2 H315, ACETATE in combination Aquatic Chronic with 2 Hazard Chemical self-contained Flammability Reuse, - IMDG: classification TLV Inhalation when International and physical ROU possible. open circuit and Maritime hazards: Product indication: positive 734 Product Code residues 23 pressure for dangerous 734 classification 5 derives should compressed be goods considered flammable air breathing 367 from criteria H411 special liquid apparatus 70 367 established 15 1468 hazardous (BS waste. EN 137). by the CLP Regulation, The hazard level of waste containing this product 1468 Annex 734 I, Part 2. The 734 data for Metabolism, ASPIRATION evaluation Product NGV/KGV of chemical-physical toxicokinetics, mechanism of action HAZARD SWE mg/m3 properties 23 mg/m3 are reported du 28 and décembre 5 in section other information mg/m3 9. 70 mg/m3 2021 15 mg/m3 mg/m3 EC Lower should - IMO: FIN Flammable explosive International be evaluated liquid, 203-628-5 limit Maritime according Suomi category Organization 2 to applicable regulations. HTP-VÄRDEN 2 ATE % (v/v) Inhalation Koncentrationer H225 vapours: 11 Highly mg/l flammable skadliga. Substance:ETHYL SOCIAL liquid and ACETATE vapour. Health NPEL Skin Point hazards: Product irritation, category SVK classification 3 - 40 23 is based on calculation 5 2020. methods CAS Upper Disposal - INDEX: Information 70 as 37 per Annex Eye explosive must Identifier not som 15 be 108-90-7 available limit I befunnits performed in Annex 2 VI through of CLP, Part serious eye of CLP an authorised waste 3, unless determined HÄLSOVÅRDSMINISTERIETS PUBLIKATIONER 2020:25 - OCH otherwise 63 in Section 11,5 management % (v/v) firm, H319 in compliance Causes with Substance:ETHYL national and irritation. local regulations. ACETATE SECTION Does 11. Contained substance MV not meet Specific 6. the Accidental classification SVN release criteria - single 23 for this measures exposure, hazard 5 class REACH Flash Waste - LC50: GRC Point 69 mg/kg bw/d 15 H336 point transportation Lethal Reg. target Concentration 01-2119432722-45 organ may toxicity May cause Ελλάδα 75 be subject 50% drowsiness or dizziness. to ADR Π.Δ. 26/2020 (ΦΕΚ 50/Α` 6.3.2020) Εναρμόνιση της ελληνικής νομοθεσίας προς τις διατάξεις των restrictions. -4 °C mg/kg Substance:ETHYL ACETATE Environmental Auto-ignition CONTAMINATED - LD50: Lethal temperature category ESD 3 hazards: TUR Product classification dose PACKAGING 50% 23 is based 5 on calculation 70 methods as per 15 Annex I of CLP, Part 4, unless determined otherwise not available bw/d in 6.1. Information 11.2. Section Personal precautions, Information WEL 12. on likely routes protective on other GBR hazards 4,7 of exposure equipment οδηγιών and 2017/2398/EΕ, 1 emergency procedures 2019/130/ΕΕ και 2019/983/ΕΕ «για την τροποποίηση της οδηγίας 14 3 SKIN The Decomposition Contaminated - OEL: Regulation (EU) 2019/1148 - on the marketing full Occupational wording packaging temperature of hazard Exposure must (H) phrases Level be recovered is given or in disposed 2004/37/ΕΚ and use ’’σχετικά section not available of explosives of 16 in of compliance the sheet. with national waste management regulations. με την precursors προστασία των εργαζομένων από τους κινδύνους που συνδέονται με pH - PBT: Persistent, bioaccumulative and toxic OEL EU 23 5 not available 70 15 Reason for missing data:reacts with water Block Information not applicable Changes TLV-ACGIH the leakage to the previous not available available review: if there is no hazard. data, the product 46 does Thiophosphoric την έκθεση σε καρκινογόνους ή μεταλλαξιγόνους παράγοντες κατά την εργασία’’» not contain 10 substances acid-tris listed 2.2. Based Kinematic - PEC: Predicted Label (p-isocyanatophenylester) on elements in the main European lists of potential or suspected endocrine viscosity environmental Concentration not available SECTION

Environmental hazards

Regulation are given in sections Substance:ETHYL and 12 of ACETATE this sheet Information on hazard classes as defined Does CALCULATION NDS/NDSCh not meet the METHODS classification POL FOR criteria CLASSIFICATION 23 for this hazard class ning in töökeskkonna Regulation keemiliste

Hazard pictograms

Regulation value for fresh water sediment according

Principle Routes of Exposure

Acute Chronic Acute local Acute Chronic further IATA: Substances contact subject with contaminated to ETHYL the Rotterdam local ACETATE, clothing. Convention: systemic SOLUTIONS arbeidsmiljøet samt smitterisikogrupper for biologiske faktorer (forskrift om tiltaks- og local systemic local systemic 6.3. INGESTION: LC50

Further information

Inhalation Very persistent and very mobile 70 23 0,047 medical NLD ATE (Oral)

Signal word

advice/attention. of the mixture: Nederland Danger Arbeidsomstandighedenregeling. >2000 mg/kg Lijst van wettelijke grenswaarden op grond van de artikelen 4.3, mg/m3 ETHYL - WGK: ACETATE Water hazard classes (German). INHALATION: Collect ATE Substances Skin (Dermal) the leaked subject of Remove the product to mixture: the victim into Stockholm to a fresh suitable Convention: air, container. away eerste from lid, Evaluate the en 4.16, accident Not the eerste classified compatibility scene. lid, van In (no the het of significant event Arbeidsomstandighedenbesluit the container of respiratory component) to be symptoms used, by checking 15 (coughing, section wheezing, 10. Absorb the 5 LC50 - for Fish breathing remainder PRT None difficulty, with inert asthma) absorbent Portugal keep material. the victim Decreto-Lei in a comfortable n.º 1/2021 230 mg/l/96h Pimephales promelas position de for 6 de breathing. janeiro, valores-limite If necessary administer de exposição oxygen. profissional If the subject indicativos stops para os Legend: 9.2.1. EC50 GENERAL - Information for Crustacea BIBLIOGRAPHY with regard to physical hazard classes 165 mg/l/48h Daphnia magna mg/cm2 mg/kg/d breathing, Make sure administer (C) = CEILING the leakage artificial ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. site is respiration. well aired. Contaminated Get agentes medical químicos. advice/attention. material Decreto-Lei should be n.º disposed 35/2020 of de in compliance 13 de julho, with proteção the provisions dos trabalhadores EC50 1. Regulation - for Algae set forth in contra

Hazard statements

(EC) / Aquatic point os 13.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing / eye protection / face protection. P370+P378 In case of fire: use CO2 to extinguish. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P233 Keep container tightly closed. P312 If you feel unwell, call a POISON CENTER / doctor

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.2. Mixtures