TONER Copied d 25-35

Further information

on hazards Ingestion: Ingestion is not applicable route of entry for intended use. Inhalation: Prolonged inhalation of excessive dusts may cause lung damage. Use of this product, as intended, does not result in inhalation of excessive dusts. Eye Contact: May cause eye irritation. Skin Contact: Unlikely to cause skin irritation.

Environmental hazards

No data are available on the adverse effects of this product on the environment. Specific Hazards: Dust explosion (like most finely divided organic powders) 3. CCooom C m mpppooosssiiitttiiiooonnn///iiinnnfffooorrrm m maaatttiiiooonnn ooonnn iiinnngggrrreeedddiiieeennntttsss Substance [ ] Preparation [ X ] Major ingredients: Chemical name Weight % CAS number EINECS number Styrene acrylate copolymer 1 40-50 +++ Styrene acrylate copolymer 2 1-5 +++ Magnetite 40-50 +++ Titanium dioxide <1 13463-67-7 +++ Wax 1-5 +++ +++: Supplier’s confidential information 4. FFFiiirrrsssttt ––– aaaiiiddd m meeeaaasssuuurrreeesss m Inhalation: Remove from exposure to fresh air and gargle with plenty of water. Consult a doctor in case of such a symptoms as coughing. Skin contact: h Wash with water and mild soap. Eye contact: Flush with water immediately and see a doctor if irritating. Ingestion: Rinse out the mouth. Drink one or two glasses of water to dilute. Seek medical treatment if necessary. 5. FFFiiirrreee ––– fffiiiggghhhtttiiinnnggg m meeeaaasssuuurrreeesss m Extinguishing Media: CO2, Water (Sprinkle with water), Foam, Powder or Dry Chemical Extinguisher Fire-Fighting Procedure: Pay attention not to blow away toner powder. Drain water off around and decrease the atmosphere temperature to extinguish the fire. 6. AAcccccciiidddeeennntttaaalll A rrreeellleeeaaassseee m meeeaaasssuuurrreeesss m Personal precautions: Avoid inhalation, ingestion, eye and skin contact in case of accidental toner release. Environmental precautions: No special precaution. Methods for Cleaning-up: Gather the released toner not to blowing away and wipe up with up with a wet cloth. 7. HHaaannndddllliiinnnggg H aaannnddd ssstttooorrraaagggeee Handling: Never open the toner container

Storage

Keep the toner container tightly closed and store in a cool, dry and dark place keeping away from fire. Keep away from children. 8. EExxxpppooosssuuurrreee E cccooonnntttrrrooolllsss///pppeeerrrsssooonnnaaalll ppprrrooottteeeccctttiiiooonnn Engineer Measures Ventilation: Ventilator is not required under normal use. Control Parameters ACGIH-TLV (2008)-TWA: Inhalable fraction 10 mg/m3, Respirable fraction 3 mg/m3 Titanium dioxide 10mg/m3 OSHA-PEL (2006)-TWA: Total Dust 15 mg/m3, Respirable fraction 5 mg/m3 h Titanium dioxide 15 mg/ m3 Protective Equipment: Respiratory protection, eye protection, hand protection, skin and body protection are not required under normal use. Hygiene measures: Wash hands after handling. 9. PPhhhyyysssiiicccaaalll P aaannnddd ccchhheeem m miiicccaaalll ppprrrooopppeeerrrtttiiieeesss Physical state: Solid Form: Fine Powder Color: Black Odour: Odorless pH Not applicable Melting Point: 130°C Explosion Properties: Dust explosion is improbable under normal use. Experimental explosiveness of toner is classified into the same rank such kind of powder as flour, dry milk and resin powder according to the pressure rising speed. Density: 1.5-2 g/cm3 Solubility: Almost insoluble in water 10. SStttaaabbbiiillliiitttyyy S aaannnddd rrreeeaaaccctttiiivvviiitttyyy Stability/Reactivity: Stable under normal use. Hazardous Decomposition Products: None. 11. TTToooxxxiiicccooolllooogggiiicccaaalll iiinnnfffooorrrm m maaatttiiiooonnn Acute oral toxicity: No data available. Acute dermal toxicity: No data available. Acute inhalation toxicity: No data available. Acute eye irritation: No data available. Acute skin irritation: No data available. Skin sensitization: No data available. Mutagenicity: Ames test is Negative (Estimated from other products containing same materials) Reproductive Toxicity: No reproductive toxicant, according to MAK, California Proposition 65, TRGS905 and EC n. 1272/2008 Carcinogenicity: No carcinogen or potential carcinogen (except titanium dioxide), according to IARC, Japan Association on Industrial Health, ACGIH, EPA, OSHA, NTP, ILO, MAK, California Proposition 65, TRGS905 and EC n. 1272/2008 Chronic effects: In a study in rats by chronic inhalation exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92% of the rats in the high concentration (16 mg/m3) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animal in the middle (4 mg/m3) exposure group. But no pulmonary change was reported in the lowest (1 mg/m3) exposure group, the most relevant level to potential human exposures. Other information: None 12. EEcccooolllooogggiiicccaaalll E iiinnnfffooorrrm m maaatttiiiooonnn No data available. 13. DDiiissspppooosssaaalll D cccooonnnsssiiidddeeerrraaatttiiiooonnnsss Do not incinerate toner and toner containers. Dangerous sparks may cause burn. Any disposal practice should be done under conditions which meet local, state and federal laws and regulations relating to waste (contact local or state environmental agency for specific rules). 14. TTTrrraaannnssspppooorrrttt iiinnnfffooorrrm m maaatttiiiooonnn UN Shipping name, UN Classification, UN Packing Group, Special Precautions : None 15. RReeeggguuulllaaatttooorrryyy R iiinnnfffooorrrm m maaatttiiiooonnn EU Information Information on the label (1999/45/EC and 67/548/EEC): Not required US Information All components in this product comply with order under TSCA 16. OOttthhheeerrr O iiinnnfffooorrrm m maaatttiiiooonnn This Material Safety Data Sheet was prepared in according to the Regulation (CE) n. 1907/2006 REACh and Regulation 1272/2008. This information adds to those contained in the “Instructions of use” for same product, but does not substitute them. The information contained herein relates only to the referred product as manufactured and put into the market, and is not valid for other combinations of same materials. It is the user’s responsibility to determine the suitability of such information for his intended use. <Abbreviation> ACGIH: American Conference of Governamental Industrial Hygienists PEL: Permissible Exposure Limit OSHA: Occupational Safety and Health Administration TLV: Threshold Limit Value TWA: Time Weighted Average MAK: MAK (Maximale Arbeitsplatzkonzentrationen) under Deutsche Forschungsgemeinschaft TRGS: Technische Regeln fur Gefahrstoffe (Deutsche) IARC: International Agency for Reserch on Cancer EPA: