General Information
Revision date
2010-02-07
Product name
Black Toner Cartridge d-Copia 403MF
Icons in SDS
Company Information
company name
Olivetti S.p.A
e-mail address of the competent person responsible for the Safety Data Sheet
supplies@olivetti.com
Section 2
Further information
on hazards Ingestion: Ingestion is not applicable route of entry for intended use. Inhalation: Prolonged inhalation of excessive dusts may cause lung damage. Use of this product, as intended, does not result in inhalation of excessive dusts. Eye Contact: May cause eye irritation. Skin Contact: Unlikely to cause skin irritation.
Environmental hazards
No data are available on the adverse effects of this product on the environment. Specific Hazards: Dust explosion (like most finely divided organic powders) 3. CCooom C m mpppooosssiiitttiiiooonnn///iiinnnfffooorrrm m maaatttiiiooonnn ooonnn iiinnngggrrreeedddiiieeennntttsss Substance [ ] Preparation [ X ] Major ingredients: Chemical name Weight % CAS number EINECS number Styrene acrylate copolymer 1 50-60 +++ Magnetite 40-50 +++ Styrene acrylate copolymer 2 1-5 +++ Wax 1-5 +++ +++: Supplier’s confidential information 4. FFFiiirrrsssttt ––– aaaiiiddd m meeeaaasssuuurrreeesss m Inhalation: Remove from exposure to fresh air and gargle with plenty of water. Consult a doctor in case of such a symptoms as coughing. Skin contact: h Wash with water and mild soap. Eye contact: Flush with water immediately and see a doctor if irritating. Ingestion: Rinse out the mouth. Drink one or two glasses of water to dilute. Seek medical treatment if necessary. 5. FFFiiirrreee ––– fffiiiggghhhtttiiinnnggg m m meeeaaasssuuurrreeesss Extinguishing Media: CO2, Water spray, Foam and Dry Chemical Fire-Fighting Procedure: Pay attention not to blow away toner powder. Drain water off around and decrease the atmosphere temperature to extinguish the fire.. 6. AAcccccciiidddeeennntttaaalll A rrreeellleeeaaassseee m meeeaaasssuuurrreeesss m Personal precautions: Avoid inhalation, ingestion, eye and skin contact in case of accidental toner release. Environmental precautions: No special precaution. Methods for Cleaning-up: Gather the released tone not to blow away and wipe a wet cloth. 7. HHaaannndddllliiinnnggg H aaannnddd ssstttooorrraaagggeee Handling: Never open the toner container
Storage
Keep the toner container tightly closed and store in a cool, dry and dark place keeping away from fire. Keep away from children. 8. EExxxpppooosssuuurrreee E cccooonnntttrrrooolllsss///pppeeerrrsssooonnnaaalll ppprrrooottteeeccctttiiiooonnn Engineer Measures Ventilation: Ventilator is not required under normal use.. Control Parameters h ACGIH-TLV (2008)-TWA: Inhalable fraction 10 mg/m3, Respirable fraction 3 mg/m3 OSHA-PEL (2006)-TWA: Total Dust 15 mg/m3, Respirable fraction 5 mg/m3 Protective Equipment: Respiratory protection, eye protection, hand protection, skin and body protection are not required under normal use. Hygiene measures: Wash hands after handling. 9. PPhhhyyysssiiicccaaalll P aaannnddd ccchhheeem m miiicccaaalll ppprrrooopppeeerrrtttiiieeesss Physical state: Solid Form: Fine Powder Color: Black Odour: Odorless pH Not applicable Melting Point: 140°C Explosion Properties: Dust explosion is improbable under normal use. Experimental explosiveness of toner is classified into the same rank such kind of powder as flour, dry milk and resin powder according to the pressure rising speed. Density: 1.5-2.0 g/cm3 Solubility: Almost insoluble in water 10. SStttaaabbbiiillliiitttyyy S aaannnddd rrreeeaaaccctttiiivvviiitttyyy Stability/Reactivity: Stable under normal use. Hazardous Decomposition Products: None. 11. TTToooxxxiiicccooolllooogggiiicccaaalll iiinnnfffooorrrm m maaatttiiiooonnn Acute oral toxicity: (rat) LD50>2,500 mg/kg (Estimated from other products containing same materials) Acute dermall toxicity: (rat) LD50>2,000 mg/kg (Estimated from other products containing same materials) Acute inhalation toxicity: (rat) LC50 (4hr)>5.13 mg/l (Estimated from other products containing same materials) Acute eye irritation: (rabbit) Mild irritant (Estimated from other products containing same materials) Acute skin irritation: (rabbit) Non-irritant (Estimated from other products containing same materials) Skin sensitization: (mouse) Non-Sensitiser (Estimated from other products containing same materials) Mutagenicity: Ames test is Negative Reproductive Toxicity: No reproductive toxicant, according to MAK, California Carcinogenicity: No carcinogen or potential carcinogen, according to IARC, Japan Association on Industrial Health, ACGIH, EPA, OSHA, NTP, ILO, MAK, California Proposition 65, TRGS 905 and EU Directive (67/548/EEC) Chronic effects: In a study in rats by chronic inhalation exposure to a typical toner, a mild to moderate degree of lung fibrosis was observed in 92% of the rats in the high concentration (16 mg/m3) exposure group, and a minimal to mild degree of fibrosis was noted in 22% of the animal in the middle (4 mg/m3) exposure group. But no pulmonary change was reported in the lowest (1 mg/m3) exposure group, the most relevant level to potential human exposures.