Limestone

Principle Routes of Exposure

Eye contact, skin contact, inhalation, and ingestion. Effects Resulting from Eye Contact: Exposure to airborne dust may cause immediate or delayed irritation or inflammation. Eye contact by large amounts of dry powder or splashes of wet limestone dust may cause effects ranging from moderate eye irritation to corneal abrasions. Such exposures may require immediate first aid (see Section 4) and medical attention to prevent damage to the eye. Effects Resulting from Skin Contact: Direct contact may cause irritation by mechanical abrasion. Effects Resulting from Inhalation: Limestone may contain trace amounts of free crystalline silica. Prolonged exposure to respirable free silica can aggravate other lung conditions and cause silicosis, a disabling and potentially fatal lung disease. Exposure to limestone dust may cause irritation to the moist mucous membranes of the nose, throat, and upper respiratory system. It may also leave unpleasant deposits in the nose. Effects Resulting from Ingestion: Although small quantities of dust are not known to be harmful, ill effects are possible if larger quantities are consumed. Carcinogenic potential: Limestone is not listed as a carcinogen by NTP, OSHA, or IARC. It may however, contain trace amounts of substances listed as carcinogens by these organizations. Crystalline silica, which 1s a component of limestone, is now classified by IARC as known human carcinogen (Group I). NTP has characterized respirable silica as "reasonably anticipated to be [a] carcinogen". Medical conditions which may be aggravated by inhalation or dermal exposure: Pre-existing upper respiratory and lung diseases. - FIRST AID Eyes Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under lids, to remove all particles. Call physician if irritation persists or later develops. Skin Wash skin with cool water and pH-neutral soap or a mild detergent. Seek medical treatment if irritation persists or later develops. Inhalation of Airborne Dust Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. Ingestion Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. - FIRE AND EXPLOSION DATA Flash point ...........0ccccccccceeeseeees None Lower Explosive Limit.............00...0..4. None Upper Explosive Limit................. None Auto ignition temperature.................... Not Combustible Extinguishing media.................. Not Combustible Special fire fighting Procedures...........None Hazardous combustion products..None Unusual fire and explosion hazards.....None - ACCIDENTAL RELEASE MEASURES Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. None of the components of this product are subject to the reporting requirements of Title HI of SARA 1986, and 40 CFR 372. - HANDLING AND STORAGE Follow the personal protection and controls set forth in Section 8 of this MSDS when handling this product. Respirable crystalline silica-containing dust may be generated during processing, handling and storage. - EXPOSURE CONTROLS/PERSONAL PROTECTION Skin Protection Wash dust-exposed skin with soap and water before eating, drinking, smoking, and using the toilet facilities. Wash work clothes after each use. Respiratory Protection Avoid actions that cause dust to become airborne. Use local or general exhaust ventilation to control exposures below applicable exposure limits. Use NIOSH/MSHA approved (under 30 CFR 11) or NIOSH approved (under 42 CFR 84) respirators in poorly ventilated areas, if an applicable exposure limit is exceeded, or when dust causes discomfort or irritation. (Advisory: Respirators and filters purchased after June 10, 1998 must be certified under 42 CFR 84.) Ventilation Use local exhaust or general dilution ventilation to control exposure within applicable limits. Eye Protection Safety glasses with side shields should be worn as minimum protection. In extremely dusty environments and unpredictable environments wear unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when working with products which may generate airborne dust. - PHYSICAL AND CHEMICAL, PROPERTIES Physical state........... Solid Od Ol... cece eee esses NO distinct odor Solubility in water... Negligible Vapor pressure........................Not applicable Vapor density.......... Not applicable Boiling point..........................Not applicable (1.e., > 1000 C) Melting point........... Not applicable Specific gravity (H20 = 1.0).......2.55-2.85 Evaporation rate...... Not applicable Section 10 - STABILITY AND REACTIVITY Stability Stable. Conditions to avoid Avoid contact with incompatible materials (see below). Incompatibility Materials to avoid include; powerful oxidizing agents such as fluoride, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen defluoride. Contact of these materials may cause fire and/or explosions. Silica dissolves in hydrofluoric acid producing a corrosive gas — silicon tetrafluoride. Hazardous decomposition Will not spontaneously occur. Silica-containing respirable dust particles may be generated by handling. Hazardous Polymerization Will not occur.

TOXICOLOGICAL INFORMATION

For a description of available, more detailed toxicological information contact the supplier or manufacturer.

ECOLOGICAL INFORMATION

Ecotoxicity No recognized unusual toxicity to plants or animals Relevant physical and chemical properties (See Sections 9 and 10.)

Disposal

Pickup and reuse clean materials. Dispose of waste materials in accordance with applicable federal, state, and local laws and regulations. Where applicable, dispose of bags in an approved landfill or incinerator. Section 14 - TRANSPORTATION DATA Hazardous materials description/proper shipping name Not hazardous under U.S. Department of Transportation (DOT) regulations.

Hazard categories

Identification number Not applicable. Not applicable Required label text Hazardous substances/reportable quantities (RQ) Not applicable. Section 15 - OTHER REGULATORY INFORMATION Status under USDOL-OSHA Hazard Communication Rule, 29 CFR 1910.1200 Limestone is considered a "hazardous chemical" under this regulation, and should be part of any hazard communication program. Status under CERCLA/SUPERFUND 40 CFR 117 and 302 Not listed. Hazard Category under SARA(Title IT), Sections 311 and 312 Limestone qualifies as a "hazardous substance" with delayed health effects. Status under SARA (Title IJ), Section 313 Not subject to reporting requirements under Section 313. Status under TSCA (as of May 1997) Some substances in limestone are on the TSCA inventory List. Status under the Federal Hazardous Substances Act Limestone 1s a "hazardous substance" subject to statutes promulgated under the subject act. Status under California Proposition 65 This product contains up to 0.05 percent of chemicals (trace elements) known to the State of California to cause cancer, birth defects or other reproductive harm. California law requires the manufacturer to give the above warning in the absence of definitive testing to prove that the defined risks do not exist.

Further information

Prepared by Bob Segal Plant Manager Oldcastle® Stone Products 550 S. Biesecker Road Thomasville, PA. 17364 (717) 792 - 2631 Approval date or Revision date Approved: February, 1999 Revised: Nov. 2005 Other important information This product should only be used by knowledgeable persons. While the information provided in this material safety data sheet 1s believed to provide a useful summary of the hazards this product as it is commonly used, the sheet cannot anticipate and provide the all of the information that might be needed in every situation. Inexperienced product users should obtain proper training before using this product. SELLER MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY Oldcastle® Stone Products except that the product shall conform to contracted specifications. The information provided herein was believed by Oldcastle® Stone Products to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information to comply with all laws and procedures applicable to the safe handling and use of product and to determine the suitability of the product for its intended use. Buyer's exclusive remedy shall be for damages and no claim of any kind, whether as to product delivered or for non-delivery of product, and whether based on contract, breach of warranty, negligence, or otherwise shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise. Material Safety Data Sheet GUM ARABIC Revised: 03/06/2010 Replaces: 11/23/2009 Printed: 03/06/2010 Carolina Biological Supply Company CAROLINA 2700 York Rd | Burlington, NC 27215 « to order: 800.334.5551 « for support: 800.227.1150 www.carolina.com Section

Product definition

Product Name: Gum Arabic Product Code(s): 86-6108, 86-6110 Size: 100 g, 500 g Chemical Name: Acacia Powder CAS Number: See section 2 Formula: Composition varies Synonyms: Gum Arabic Distributor: Carolina Biological Supply Company, 2700 York Road, Burlington, NC 27215 Chemical Information: 800-227-1150 (8am-5pm (ET) M-F) Chemtrec 800-424-9300 (Transportation Spill Response 24 hours)