Route of exposure

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) SECTION 10. Stability and reactivity - CE NUMBER: Identifier in ESIS (European archive of existing substances) SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.

Environmental hazards

Product classification is based on calculation methods as per Annex I of CLP, Part 4, unless determined otherwise in Point 75 2-AMINO-2-METHYLPROPANOL - CLP: EC Regulation 1272/2008 INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly Reg. no.: 01-2119475110-51 8.2. Exposure controls

2.1 Classification of the substance or mixture

10.1. Reactivity 12.4. Mobility in soil SERIOUS EYE DAMAGE / IRRITATION - DNEL: Derived No Effect Level Point 75 GROUND NATURAL CALCIUM CARBONATE authorised by a doctor. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away - EmS: Emergency Schedule INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops from any incompatible materials, see section 10 for details. Point 75 Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one[EC no. 247-500-7] and The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is Does not meet the classification criteria for this hazard class There are no particular risks of reaction with other substances in normal conditions of use. Information not available - GHS: Globally Harmonized System of classification and labeling of chemicals The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) breathing, administer artificial respiration. Take suitable precautions for rescue workers. well aired through effective local aspiration. Changes to previous review: However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data - IATA DGR: International Air Transport Association Dangerous Goods Regulation However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data Reg. no.: 01-2120764691-48 7.3. Specific end use(s) When choosing personal protective equipment, ask your chemical substance supplier for advice. RESPIRATORY OR SKIN SENSITISATION The following sections were modified: 10.2. Chemical stability sheet with appropriate information, compliant to (EU) Regulation 2015/830. - IC50: Immobilization Concentration 50% sheet with appropriate information, compliant to (EU) Regulation 2015/830. Point 75 2-octyl-2H-isothiazol-3-one 4.2. Most important symptoms and effects, both acute and delayed Personal protective equipment must be CE marked, showing that it complies with applicable standards. 02 / 03 / 11 / 12 / 15.

Results of PBT and vPvB assessment

IMDG: International Maritime Code for dangerous goods Information not available Point 75 1,2-benzisothiazol-3(2H)-one Hazard classification and indication: HAND PROTECTION May produce an allergic reaction. The product is stable in normal conditions of use and storage. - IMO: International Maritime Organization Hazard classification and indication: Reg. no.: 01-2120761540-60 -- Specific information on symptoms and effects caused by the product are unknown. Protect hands with category III work gloves (see standard EN 374).

Contains

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. - INDEX NUMBER: Identifier in Annex VI of CLP 10.3. Possibility of hazardous reactions SECTION 8. Exposure controls/personal protection The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one[EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Regulation (EC) No. 2019/1148 - on the marketing and use of explosives precursors - LC50: Lethal Concentration 50% 4.3. Indication of any immediate medical attention and special treatment needed The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on 2-octyl-2H-isothiazol-3-one Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one[EC no. 247-500-7] and CONTAMINATED PACKAGING None in particular. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the 10.6. Hazardous decomposition products Substances subject to the Rotterdam Convention: - TWA: Time-weighted average exposure limit 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. threshold values considered. The protection provided by masks is in any case limited. Does not meet the classification criteria for this hazard class None - VOC: Volatile organic Compounds 2-octyl-2H-isothiazol-3-one 5.2. Special hazards arising from the substance or mixture If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an Information not available

2.2 Label elements

Not applicable - LD50: Lethal dose 50% 8.1. Control parameters the duration and type of use. No hazardous reactions are foreseeable in normal conditions of use and storage. - OEL: Occupational Exposure Level Information not available SKIN PROTECTION GERM CELL MUTAGENICITY Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Information not available Substances in Candidate List (Art. 59 REACH)

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 10.4. Conditions to avoid Regulatory References: Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body On the basis of available data, the product does not contain any SVHC in percentage ≥ than 0,1%. - PEC: Predicted environmental Concentration SECTION 5. Firefighting measures with soap and water after removing protective clothing.

Hazard pictograms

Does not meet the classification criteria for this hazard class - PEL: Predicted exposure level -- SECTION 13. Disposal considerations DEU EYE PROTECTION None in particular. However the usual precautions used for chemical products should be respected. Substances subject to authorisation (Annex XIV REACH) - PNEC: Predicted no effect concentration Deutschland Technischen Regeln für Gefahrstoffe (TRGS 900) - Liste der Arbeitsplatzgrenzwerte und 5.1. Extinguishing media

Signal word

Wear airtight protective goggles (see standard EN 166). CARCINOGENICITY None - REACH: EC Regulation 1907/2006 -- Kurzzeitwerte. MAK- und BAT-Werte-Liste 2020, Ständige Senatskommission zur Prüfung 13.1. Waste treatment methods RESPIRATORY PROTECTION gesundheitsschädlicher Arbeitsstoffe, Mitteilung 56 10.5. Incompatible materials - RID: Regulation concerning the international transport of dangerous goods by train

Hazard statements

SUITABLE EXTINGUISHING EQUIPMENT If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type Does not meet the classification criteria for this hazard class Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: - TLV: Threshold Limit Value Reuse, when possible. Neat product residues should be considered special non-hazardous waste. The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. Reaction mass of 5-chloro-2-methyl-2H-isothiazol-3-one[EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases Information not available None - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. EUH210 Safety data sheet available on request. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. UNSUITABLE EXTINGUISHING EQUIPMENT or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. REPRODUCTIVE TOXICITY - TWA STEL: Short-term exposure limit EUH208

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation May produce an allergic reaction. SECTION 14. Transport information emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing STOT - SINGLE EXPOSURE Substances subject to the Stockholm Convention: - WGK: Water hazard classes (German). HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. None

TOXICOLOGICAL INFORMATION

ENVIRONMENTAL EXPOSURE CONTROLS

Precautionary statements

Do not breathe combustion products. Does not meet the classification criteria for this hazard class The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail -- The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Healthcare controls GENERAL BIBLIOGRAPHY In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it 5.3. Advice for firefighters compliance with environmental standards. STOT - REPEATED EXPOSURE Information not available 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament

UN Number

contains, using the criteria specified in the applicable regulation for classification. VOC (Directive 2004/42/EC) : 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament VOC (Directive 2004/42/EC) : It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the GENERAL INFORMATION Does not meet the classification criteria for this hazard class Decorative effect coatings. VOC (Directive 2004/42/EC) : 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament Decorative effect coatings. toxicological effects of exposure to the product. Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for Not applicable VOC given in g/litre of product in a ready-to-use condition : Decorative effect coatings. 4. Regulation (EU) 2015/830 of the European Parliament VOC given in g/litre of product in a ready-to-use condition : SECTION 9. Physical and chemical properties health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of

Aspiration hazard

93,00 Limit value: 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament Limit value: 200,00 11.1. Information on toxicological effects 14.2. UN proper shipping name contaminated water used for extinction and the remains of the fire according to applicable regulations. 15.2. Chemical safety assessment 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 9.1. Information on basic physical and chemical properties SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Does not meet the classification criteria for this hazard class 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament Metabolism, toxicokinetics, mechanism of action and other information Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with Not applicable

2.3 Other hazards

A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3. 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). EPY 10.5.2 - SDS 1004.13 On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%.