OEL

SECTION 2: Hazards identification

Regulation EC 1272/2008 (CLP) Vapour density Interactive effects EC50 - for Crustacea - CE NUMBER: Identifier in ESIS (European archive of existing substances) Not applicable The following sections were modified: Normal value for fresh water sediment 403 ng/l Not available 1919 mg/l/48h 49,9 µg/kg 4.3. Indication of any immediate medical attention and special treatment needed Relative density EC50 - for Algae / Aquatic Plants - CLP EC Regulation

2.1 Classification of the substance or mixture

08. Solubility Information not available - DNEL: Derived No Effect Level Normal value for marine water sediment 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 8. Exposure controls/personal protection Mixable in water 4,99 µg/kg Changed TLVs in section 8.1 for following countries: Partition coefficient: n-octanol/water 1,2-benzisothiazol-3(2H)-one - EmS: Emergency Schedule Normal value of STP microorganisms Not available 1,03 mg/l 8.1. Control parameters Information not available Health - Derived no-effect level - DNEL / DMEL DEU, ESP, GBR, ITA, POL, The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation

Principle Routes of Exposure

Acute 15000 cps > 70 µg/l 70-150 Chronic Not classified (no significant component) Chronic Acute local Acute Chronic SECTION 15. Regulatory information Explosive properties LD50 (Oral) of the mixture: Chronic NOEC for Algae / Aquatic Plants - IMDG: International Maritime Code for dangerous goods local systemic not applicable > 40,3 µg/l 40-55 local Not classified (no significant component) systemic sheet with appropriate information compliant to (EU) Regulation

Further information

SUITABLE EXTINGUISHING EQUIPMENT ESP - LC50: Lethal Concentration 50% Skin España LÍMITES DE EXPOSICIÓN PROFESIONAL PARA AGENTES QUÍMICOS EN ESPAÑA 2019 345 966

2.2 Label elements

The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. - LD50: Lethal dose 50% (2-methoxymethylethoxy)propanol (INSST) µg/kg bw/d UNSUITABLE EXTINGUISHING EQUIPMENT GBR Seveso Category - Directive 2012/18/EC: (2-methoxymethylethoxy)propanol - OEL: Occupational Exposure Level LD50 (Oral) United Kingdom EH40/2005 Workplace exposure limits (Third edition,published 2018) None > 5000 mg/kg rat Hazard labelling pursuant to EC Regulation

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation LD50 (Dermal) Italia DIRETTIVA (UE) 2017/164 DELLA COMMISSIONE del 31 gennaio 2017 1000 - 10000 mg/l 9510 mg/kg rabbit POL (C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation

Hazard pictograms

VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified. - PEL: Predicted exposure level Product -- 2018 r SECTION 10. Stability and reactivity EU 1,2-benzisothiazol-3(2H)-one - PNEC: Predicted no effect concentration Point 1,2-benzisothiazol-3(2H)-one OEL EU 40 -- Directive (EU) 2017/2398; Directive (EU) 2017/164; Directive 2009/161/EU; Directive 2006/15/EC; 8.2. Exposure controls

Signal word

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE Rapidly degradable - REACH EC Regulation LD50 (Dermal) -- 2000 mg/kg bw (rat) 12.3. Bioaccumulative potential

Hazard statements

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. - TLV: Threshold Limit Value 5.3. Advice for firefighters There are no particular risks of reaction with other substances in normal conditions of use. well aired through effective local aspiration. SKIN CORROSION / IRRITATION - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. EUH210 Safety data sheet available on request. When choosing personal protective equipment, ask your chemical substance supplier for advice. Substances subject to authorisation (Annex XIV REACH) Information not available - TWA STEL: Short-term exposure limit EUH208 EUH210

Contains

Safety data sheet available on request. 1,2-benzisothiazol-3(2H)-one (2-methoxymethylethoxy)propanol GENERAL INFORMATION Personal protective equipment must be CE marked, showing that it complies with applicable standards. None Does not meet the classification criteria for this hazard class - TWA: Time-weighted average exposure limit EUH208 May produce an allergic reaction. 1,2-benzisothiazol-3(2H)-one Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for HAND PROTECTION Forms peroxides with: air. 10.2. Chemical stability - VOC: Volatile organic Compounds May produce an allergic reaction. 12.4. Mobility in soil health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of Protect hands with category III work gloves (see standard EN 374). Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: SERIOUS EYE DAMAGE / IRRITATION On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. None 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament VOC given in g/litre of product in a ready-to-use condition : 30,00 28,00 (2-methoxymethylethoxy)propanol Wear airtight protective goggles (see standard EN 166). 1,2-benzisothiazol-3(2H)-one 4. Regulation (EU)

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.

Precautionary statements

contaminated water used for extinction and the remains of the fire according to applicable regulations. None - WGK: Water hazard classes (German). -- The product is stable in normal conditions of use and storage. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on Does not meet the classification criteria for this hazard class Information not available -- Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with the duration and type of use. Substances subject to the Rotterdam Convention: 10.3. Possibility of hazardous reactions self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). SKIN PROTECTION None VOC (Directive 2004/42/EC) : RESPIRATORY OR SKIN SENSITISATION GENERAL BIBLIOGRAPHY

Results of PBT and vPvB assessment

Matt coatings for interior walls and ceilings. Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body 1.

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.